Silver ions enhanced AuNCs fluorescence as a turn-off nanoprobe for ultrasensitive detection of iodide.

Title Silver ions enhanced AuNCs fluorescence as a turn-off nanoprobe for ultrasensitive detection of iodide.
Authors W. Hou; Y. Chen; Q. Lu; M. Liu; Y. Zhang; S. Yao
Journal Talanta
DOI 10.1016/j.talanta.2017.12.047
Abstract

Fluorescence nanoprobes are frequently employed to construct sensitive biosensors via turn-on and turn-off strategy. In this paper, a novel strategy for ultrasensitive detection of iodide was firstly constructed based on Agregulated photoluminescence enhancement of gold nanoclusters (AuNCs) as a turn-off nanoplatform. In the presence of Ag, the fluorescence (FL) intensity of AuNCs can be enhanced obviously. When adding iodide ions (I) in the Ag-AuNCs, Agcan be pulled down from AuNCs and results in quenching of the fluorescent effectively owing to the combination between Agand I. Compared with that of Idirectly reaction with AuNCs, the introducing of Agshows improved quenching efficiency from 32% to 66% since Ican react with Agas well as AuNCs. Therefore, the platform could be applied to assay Agand I, on the basis of the FL enhancement and the further FL quenching. The detection ranges and detection limits were 0.2-12?M and 0.06?M for Ag, 0.001-6?M and 0.3nM for I, respectively. The new sensing method based on ion regulation to enhance the detection sensitivity can extend to the appliance of other fluorescent materials in biosensing and biomedical field.

Citation W. Hou; Y. Chen; Q. Lu; M. Liu; Y. Zhang; S. Yao.Silver ions enhanced AuNCs fluorescence as a turn-off nanoprobe for ultrasensitive detection of iodide.. Talanta. 2018;180:144149. doi:10.1016/j.talanta.2017.12.047

Related Elements

Silver

See more Silver products. Silver (atomic symbol: Ag, atomic number: 47) is a Block D, Group 11, Period 5 element with an atomic weight of 107.8682. Silver Bohr ModelThe number of electrons in each of Silver's shells is 2, 8, 18, 18, 1 and its electron configuration is [Kr]4d10 5s1. The silver atom has a radius of 144 pm and a Van der Waals radius of 203 pm. Silver was first discovered by Early Man prior to 5000 BC. In its elemental form, silver has a brilliant white metallic luster. Elemental SilverIt is a little harder than gold and is very ductile and malleable, being exceeded only by gold and perhaps palladium. Pure silver has the highest electrical and thermal conductivity of all metals and possesses the lowest contact resistance. It is stable in pure air and water, but tarnishes when exposed to ozone, hydrogen sulfide, or air containing sulfur. It is found in copper, copper-nickel, lead, and lead-zinc ores, among others. Silver was named after the Anglo-Saxon word "seolfor" or "siolfur," meaning 'silver'.

Iodine

See more Iodine products. Iodine (atomic symbol: I, atomic number: 53) is a Block P, Group 17, Period 5 element with an atomic radius of 126.90447. The number of electrons in each of Iodine's shells is 2, 8, 18, 18, 7 and its electron configuration is [Kr] 4d10 5s2 5p5. The iodine atom has a radius of 140 pm and a Van der Waals radius of 198 pm. In its elemental form, iodine has a lustrous metallic gray appearance as a solid and a violet appearance as a gas or liquid solution. Elemental IodineIodine forms compounds with many elements, but is less active than the other halogens. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Iodine compounds are important in organic chemistry and very useful in the field of medicine. Iodine was discovered and first isolated by Bernard Courtois in 1811. The name Iodine is derived from the Greek word "iodes" meaning violet.

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