Tin Sulfate Solution

CAS 7488-55-3
Linear Formula: SnSO4
MDL Number: MFCD00011246
EC No.: N/A

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PRODUCT PRODUCT CODE REQUEST A QUOTE SAFETY DATA TECHNICAL DATA
(2N) 99% Tin Sulfate Solution
SN-SAT-02-SOL Pricing
(3N) 99.9% Tin Sulfate Solution
SN-SAT-03-SOL Pricing
(4N) 99.99% Tin Sulfate Solution
SN-SAT-04-SOL Pricing
(5N) 99.999% Tin Sulfate Solution
SN-SAT-05-SOL Pricing

Properties

Compound Formula O4SSn
Molecular Weight 214.75
Appearance

Liquid

Melting Point 378° C (712.4° F)
Boiling Point decomposes to SnO2 and SO2
Density 4.15 g/cm3
Monoisotopic Mass N/A
Exact Mass N/A

Health & Safety Information

Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes Xi
Risk Codes 36/37/38
Safety Statements 26-36
RTECS Number N/A
Transport Information N/A
WGK Germany nwg

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 07/28/2016
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Tin Sulfate Solution

Product Number: All applicable American Elements product codes, e.g. SN-SAT-02-SOL, SN-SAT-03-SOL, SN-SAT-04-SOL, SN-SAT-05-SOL

CAS #: 7488-55-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification (GHS-US)
Skin Corr. 1A H314
Carc. 1A H350

Corrosion - GHS05Health Hazard - GHS08

Signal word (GHS-US):
Danger
Hazard statements (GHS-US):
H314 - Causes severe skin burns and eye damage
H350 - May cause cancer
Precautionary statements (GHS-US):
P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P260 - Do not breathe mist/vapors/spray
P264 - Wash hand and other exposed areas thoroughly after handliong
P280 - Wear protective gloces/protective clothing/ eye protection/ face protection
P301+P330+P331 - IF SWALLOWED : rinse mouth. Do NOT induce vomiting
P303+P361+P353 - IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/shower
P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P308+P313 - If exposed or concerned:Get medical advice/attention
P337+P313 - If eye irritation persists: Get medical advice/ attention
P363 - Wash contaminated clothing before reuse
Other Hazards
Strong inorganic acid mists containing sulfuric acid are classified as a known human carcinogen. This classification does not apply to sulfuric acid solutions.
Unknown acute toxicity (GHS-US)
None of the ingredients in the mixture are of unknown toxicity


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance
Not applicable - product is a mixture
Mixture
Sulfuric Acid
CAS: 7664-93-9
0-2%
GHS-US
Skin Corr. 1A, H314
Carc. 1A, H350
Sulfuric Acid, Tin(II) Salt
CAS: 7488-55-3
15-25%
GHS-US
Not classified


SECTION 4. FIRST AID MEASURES

Swallowing:
Do NOT induce vomiting. Give large quantities of water. Call a physician. Do NOT neutralize the acid. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air immediately and have patient lie down if breathing is difficult. Call a physician.
Eyes/Skin:
IMMEDIATEDLY (within seconds) flush eyes or skin with plenty of water. Promptly get
medical help – apply compresses of iced water if there is a delay before medical treatment


SECTION 5. FIREFIGHTING MEASURES

Flashpoint (oF):
N/A
Flammable limits in air
LOWER: N/A UPPER: N/A
Extinguishing media:
Water, fog, foam
Special firefighting method:
Wear SCBA if fumes or mists are present
Unusual fire and explosion hazards:
Neutralize run-off with lime, soda ash, etc. Hydrogen gas formation is possible.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Steps to be taken if material is released or spilled:
Soak up small spills with sand, clay or distomoceous earth.
Neutralize large spills with lime or soda ash and transfer to a waste water treatment system.
Waste disposal method:
Cleaned-up material may be a RCRA hazardous waste on disposal. Do not flush to surface water or sanitary sewer system. Dispose of in accordance with all local, state, and federal regulations.


SECTION 7. HANDLING AND STORAGE

Precautions to be taken in handling and storage:
Keep out of sun and away from heat, sparks and flame.
Loosen closure carefully.
Other precautions:
Do not wash out container or use it for other purposes; replace closure after each withdrawal.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Sulfuric Acid, Tin(II) Salt
CAS: 7488-55-3
USA ACGIH
ACGIH TWA (mg/m3)
2mg/m3 (Tin)
USA OSHA
OSHA PEL (TWA) (mg/m3)
2mg/m3 (Tin)
Sulfuric Acid
CAS: 7664-93-9
USA ACGIH
ACGIH TWA (mg/m3)
0.2mg/m3
USA OSHA
OSHA PEL (TWA) (mg/m3)
1mg/m3
Appropriate Engineering Controls: Ensure tha eyewash station and safety showers are close to the workstation location.
Personal Protective equipment: Avoid all unnecessary exposure.
Hand Protection: Wear protective gloves.
Eye Protection: Chemical goggles or face shield
Skin and body protection: Wear suitable protective clothing.
Respiratory Protection: Not typically required if exposures are below established limits. If needed, use NIOS appproved respirator.
Other information: Do not eat, drink or smoke during use.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point (oF @ 760 mmHg): > 212
Specific gravity (H2O = 1 @ 72oF): 1.210
Solubility in water: Complete
Evaporation rate (butyl acetate = 1): > 1


SECTION 10. STABILITY AND REACTIVITY

Stability considerations/Conditions to avoid:
Stable / Water, organic materials (potential violent reaction, heat)
Hazardous polymerization/Conditions to avoid:
Will not occur / None
Incompatibility/Conditions to avoid:
Alkaline solutions, metals. Strong oxidizing, reducing or combustible organic materials.
Hazardous combustion or Decomposition products:
Hazardous gases may be generated on contact with cyanides, sulfides and carbides.


SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity: Not classified
Sulfuric Acid
CAS: 7664-93-9
LD50 oral rat: 2140 mg/kg
LC50 inhalation rat: 510 mg/m3 (Exposure time:2 h)
Skin Corrosion/irritation: Causes severe skin burns and eye damage
Serious eye damage/irritation: Causes serious eye damage
Respiratory or Skin sentization: Not Classified
Germ cell mutagenicity: Not Classified
Carcinogenicity: May cause cancer in mist form
Sulfuric Acid
CAS: 7664-93-9
IARC group
1 - Carcinogenic to humans (only "strong inorganic acid mists containing sulfuric acid")
Reproductive toxicity: Not Classified
Specific target organ toxicity (single exposure): Not classified
Specific target organ toxicity (repeated exposure): Not classified
Aspiration hazard: Not classified
Potantial Adverse Human health effects and symptoms: No additonal infomation available
Symptoms/injuries after inhalation: May cause cancer by Inhalation
Symptoms/injuries after eye contact: causes serious eye irritation


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Sulfuric Acid
CAS: 7664-93-9
LC50 fish 1 > 500mg/l (Exposure time: 96 h - Species: Brachydanio rerio [static])
Persistence and degradability:
Not established
Bioaccumulative potential:
Stannous Sulfate Solution
Not established
Sulfuric Acid
BCF fish 1 (no bioaccumulation)
Mobility in soil
No additional information available
Other adverse effects
Other information: Avoid release to the environment


SECTION 13. DISPOSAL CONSIDERATIONS

Waste disposal recommendations: Dispose in a safe manner in accordance with local, state, and federal regulations
Ecology - waste materials: Avoid release to the environment.


SECTION 14. TRANSPORT INFORMATION

Department of Transportation: Domestic Ground
Proper shipping name: Corrosive Liquid, N.O.S.
Hazard Class: 8
ID & Packing Group Number: UN 1760, PG III
ERG Guide Number: 154


SECTION 15. REGULATORY INFORMATION

SARA Title III Program Section 313 Supplier Notifica
tion. This product contains the following toxic
chemicals:
Chemical Name CAS Number Concentration
Sulfuric Acid 7664-93-9 < 20%
State Right-to-Know Programs
Pennsylvania: This product contains the following chemicals listed in PA Code Title 34,
Hazardous Substance List: Sulfuric Acid
California: This product contains the following compounds subject to the reporting and
labeling requirements of Proposition 65: None


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About

Tin Sulfate Solutions are moderate to highly concentrated liquid solutions of Tin Sulfate. They are an excellent source of Tin Sulfate for applications requiring solubilized materials. American Elements can prepare dissolved homogeneous solutions at customer specified concentrations or to the maximum stoichiometric concentration. Packaging is available in 55 gallon drums, smaller units and larger liquid totes. American Elements maintains solution production facilities in the United States, Northern Europe (Liverpool, UK), Southern Europe (Milan, Italy), Australia and China to allow for lower freight costs and quicker delivery to our customers.. American Elements metal and rare earth compound solutions have numerous applications, but are commonly used in petrochemical cracking and automotive catalysts, water treatment, plating, textiles, research and in optic, laser, crystal and glass applications. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Tin Sulfate Powder.Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Organometallic forms are soluble in organic solutions and sometimes in both aqueous and organic solutions. Metallic ions can also be dispersed utilizing suspended or coated nanoparticles and deposited utilizing sputtering targets and evaporation materials for uses such as solar cells and fuel cells. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Tin(4+) disulfate, Tin(+2) cation sulfate, Tin(II) sulfate, Stannous sulfate

Chemical Identifiers

Linear Formula SnSO4
CAS 7488-55-3
Pubchem CID 62643
MDL Number MFCD00011246
EC No. N/A
Beilstein Registry No. N/A
IUPAC Name Tin(+2) cation sulfate
SMILES [O-]S(=O)(=O)[O-].[Sn+2]
InchI Identifier InChI=1S/H2O4S.Sn/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2
InchI Key OBBXFSIWZVFYJR-UHFFFAOYSA-L

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Products & Element Information

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

Tin Bohr ModelSee more Tin products. Tin (atomic symbol: Sn, atomic number: 50) is a Block P, Group 14, Period 5 element with an atomic weight of 118.710. The number of electrons in each of tin's shells is 2, 8, 18, 18, 4 and its electron configuration is [Kr] 4d10 5s2 5p2. The tin atom has a radius of 140.5 pm and a Van der Waals radius of 217 pm.In its elemental form, tin has a silvery-gray metallic appearance. It is malleable, ductile and highly crystalline. High Purity (99.9999%) Tin (Sn) MetalTin has nine stable isotopes and 18 unstable isotopes. Under 3.72 degrees Kelvin, Tin becomes a superconductor. Applications for tin include soldering, plating, and such alloys as pewter. The first uses of tin can be dated to the Bronze Age around 3000 BC in which tin and copper were combined to make the alloy bronze. The origin of the word tin comes from the Latin word Stannum which translates to the Anglo-Saxon word tin. For more information on tin, including properties, safety data, research, and American Elements' catalog of tin products, visit the Tin element page.

Recent Research

A study of radiogallium aqueous chemistry: in vitro and in vivo characterisation of (67) Ga-hydrolysed-stannous fluoride particles., Tsopelas, Chris , J Labelled Comp Radiopharm, 2016 May 15, Volume 59, Issue 5, p.197-204, (2016)

High Performance Liquid Metal Battery with Environmentally Friendly Antimony-Tin Positive Electrode., Li, Haomiao, Wang Kangli, Cheng Shijie, and Jiang Kai , ACS Appl Mater Interfaces, 2016 May 13, (2016)

A new membrane electro-deposition based process for tin recovery from waste printed circuit boards., Jian-Guang, Yang, Jie Lei, Si-Yao Peng, Yuan-Lu Lv, and Wei-Qiang Shi , J Hazard Mater, 2016 Mar 5, Volume 304, p.409-16, (2016)

Adsorptive desulphurization study of liquid fuels using Tin (Sn) impregnated activated charcoal., Shah, Syed Sikandar, Ahmad Imtiaz, and Ahmad Waqas , J Hazard Mater, 2016 Mar 5, Volume 304, p.205-13, (2016)

Spectroelectrochemical Properties of Ultra-Thin Indium Tin Oxide Films under Electric Potential Modulation., Han, Xue, and Mendes Sergio B. , Thin Solid Films, 2016 Mar 31, Volume 603, p.230-237, (2016)

Building Self-Healing Alloy Architecture for Stable Sodium-Ion Battery Anodes: A Case Study of Tin Anode Materials., Mao, Jianfeng, Fan Xiulin, Luo Chao, and Wang Chunsheng , ACS Appl Mater Interfaces, 2016 Mar 23, Volume 8, Issue 11, p.7147-55, (2016)

Tin Tungstate Nanoparticles: A Photosensitizer for Photodynamic Tumor Therapy., Seidl, Carmen, Ungelenk Jan, Zittel Eva, Bergfeldt Thomas, Sleeman Jonathan P., Schepers Ute, and Feldmann Claus , ACS Nano, 2016 Mar 22, Volume 10, Issue 3, p.3149-57, (2016)

Enhanced visible light photocurrent response and photodegradation efficiency over TiO2-graphene nanocomposite pillared with tin porphyrin., Zargari, Solmaz, Rahimi Rahmatollah, Ghaffarinejad Ali, and Morsali Ali , J Colloid Interface Sci, 2016 Mar 15, Volume 466, p.310-21, (2016)

Effect of organic solar cells using various power O2 plasma treatments on the indium tin oxide substrate., Ke, Jhong-Ciao, Wang Yeong-Her, Chen Kan-Lin, and Huang Chien-Jung , J Colloid Interface Sci, 2016 Mar 1, Volume 465, p.311-5, (2016)

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