SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 Flame
Pyr. Sol. 1 H250 Catches fire spontaneously if exposed to air.
Self-heat. 2 H252 Self-heating in large quantities; may catch fire.
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labeled according to the CLP regulation.
Hazard pictogram

GHS02
Signal word
Danger
Hazard statements
H250 Catches fire spontaneously if exposed to air.
H252 Self-heating in large quantities; may catch fire.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P222 Do not allow contact with air.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
P422 Store contents under inert gas.
P420 Store away from other materials.
WHMIS classification
B6 - Reactive flammable material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 1
Flammability = 4
Physical Hazard = 2
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Dangerous components:
CAS: 7440-32-6
EINECS: 231-142-3
Titanium
F R17
Pyr. Sol. 1, H250; Self-heat. 1, H251
CAS: 7429-90-5
EINECS: 231-072-3
Index number: 013-001-00-6
Aluminum
F R15-17
Pyr. Sol. 1, H250; Water-react. 2, H261
CAS: 7440-62-2
EINECS: 231-171-1
Vanadium
Xi R36/37/38;
F R11
Flam. Sol. 1, H228;
Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335
Additional information
None known.
Non-Hazardous Ingredients
CAS: 7732-18-5
EINECS: 231-791-2

SECTION 4. FIRST AID MEASURES

Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly. Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing
Seek medical treatment.
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
In case of fire, use sand, carbon dioxide or powdered extinguishing agent. Never use water.
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing agents
Water.
Special hazards arising from the substance or mixture
Spontaneously flammable in air.
If this product is involved in a fire, the following can be released:
Metal oxide
Advice for firefighters
Protective equipment:
Wear self-contained breathing apparatus. Wear full protective suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
Do not allow product to reach sewage system or water bodies.
Methods and material for containment and cleaning up:
Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents
Prevention of secondary hazards:
Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Substance/product is auto-flammable.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and containers:
No special requirements.
Information about storage in one common storage facility:
Store away from air. Do not store together with acids. Store away from oxidising agents.
Further information about storage conditions:
Store under dry inert gas.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components with critical values that require monitoring at the workplace:
7429-90-5 Aluminum (6.0%)
PEL (USA) Long-term value: 15*; 15** mg/m³
*Total dust; ** Respirable fraction
REL (USA) Long-term value: 10* 5** mg/m³
*Total dust **Respirable fraction
TLV (USA) Long-term value: 1* mg/m³
as Al; *as respirable fraction
7440-62-2 Vanadium (4.0%)
Ingredients with biological limit values:
7429-90-5 Aluminum (6.0%)
Parameter: Aluminium
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use breathing protection with high concentrations.
Recommended filter device for short term use:
Use a respirator with type N95 (USA) or PE (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards.
Protection of hands:
Check protective gloves prior to each use for their proper condition.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Material of gloves
Butyl rubber, BR
Penetration time of glove material (in minutes)
Not determined
Eye protection:
Safety glasses
Full face protection
Body protection:
Protective work clothing

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form:
Powder
Color:
Silver grey
Smell:
Odorless
Odor threshold:
Not determined.
pH-value:
Not applicable.
Change in condition
Melting point/Melting range:
ca 1650 °C
Boiling point/Boiling range:
Not determined
Sublimation temperature / start:
Not determined
Inflammability (solid, gaseous)
Not determined.
Ignition temperature:
400 °C
Decomposition temperature:
Not determined
Self-inflammability:
Spontaneously flammable in air.
Danger of explosion:
Not determined.
Critical values for explosion:
Lower:
Not determined
Upper:
Not determined
Steam pressure at 20 °C:
23 hPa
Density
Not determined
Relative density
Not determined.
Vapour density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with
Water:
Insoluble
Partition coefficient (n-octanol/water):
Not determined.
Viscosity:
dynamic:
Not applicable.
kinematic:
Not applicable.
Solvent content:
Organic solvents:
0.0 %
Solids content:
100.0 %
Other information
No further relevant information available

SECTION 10. STABILITY AND REACTIVITY

Reactivity
Catches fire spontaneously if exposed to air.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidising agents
Spontaneously flammable in air.
Conditions to avoid
No further relevant information available.
Incompatible materials:
Acids
Air
Oxidising agents
Hazardous decomposition products:
Metal oxide

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effect known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of its carcinogenicity in humans and/or animals.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or carcinogenic and/or neoplastic data for components in this product.
Reproductive toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for components in this product.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system. Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Hand over to disposers of hazardous waste
Must be specially treated under adherence to official regulations.
Consult state, local or national regulations for proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number
ADR, IMDG, IATA
UN2546
UN proper shipping name
ADR
2546 TITANIUM POWDER, DRY
IMDG, IATA
TITANIUM POWDER, DRY
Transport hazard class(es)
ADR
Class
4.2 (S4) Substances liable to spontaneous combustion.
Label
4.2
IMDG, IATA
Class
4.2 Substances liable
to spontaneous combustion.
Label
4.2
Packing group
ADR, IMDG, IATA
I
Environmental hazards:
Marine pollutant:
No
Special precautions for user
Warning: Substances liable to spontaneous combustion.
EMS Number:
F-G,S-M
Segregation groups
Heavy metals and their salts (including their organometallic compounds), powdered metals
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
ADR
Excepted quantities (EQ):
E0
Limited quantities (LQ)
0
Transport category
0
Tunnel restriction code
E
UN "Model Regulation":
UN2546, TITANIUM POWDER, DRY, 4.2, I

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
Australian Inventory of Chemical Substances
All ingredients are listed.
Standard for the Uniform Scheduling of Drugs and Poisons
None of the ingredients is listed.
National regulations
Information about limitation of use:
Employment restrictions concerning young persons must be observed.
For use only by technically qualified individuals.
Classification according to VbF:
Not applicable
Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Other regulations, limitations and prohibitive regulations
ELINCS (European List of Notified Chemical Substances)
None of the ingredients is listed.
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No.1907/2006.
None of the ingredients are listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
None of the ingredients is listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
None of the ingredients is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out