Cerium(III) Bromide Hydrate

CeBr3•XH2O
CAS 14457-87-5


Product Product Code Order or Specifications
(2N) 99% Cerium(III) Bromide Hydrate CE-BR-02-XHYD Contact American Elements
(2N5) 99.5% Cerium(III) Bromide Hydrate CE-BR-025-XHYD Contact American Elements
(3N) 99.9% Cerium(III) Bromide Hydrate CE-BR-03-XHYD Contact American Elements
(3N5) 99.95% Cerium(III) Bromide Hydrate CE-BR-035-XHYD Contact American Elements
(4N) 99.99% Cerium(III) Bromide Hydrate CE-BR-04-XHYD Contact American Elements
(5N) 99.999% Cerium(III) Bromide Hydrate CE-BR-05-XHYD Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
CeBr3 •XH2O 14457-87-5 24880085 292780 MFCD00016004 238-447-0 tribromocerium N/A [Ce+3].[Br-].[Br-].[Br-] InChI=1S/3BrH.Ce
/h3*1H;/q;;;+3/p-3
MOOUSOJAOQPDEH-UHFFFAOYSA-K

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
CeBr3 379.83 White Crystalline Solid 722° C
(1,332° F)
1,457° C
(2,655° F)
5.10 g/cm³ 378.6584 376.660447 0 Safety Data Sheet

Bromide IonCerium(III) Bromide Hydrate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Cerium (Ce) atomic and molecular weight, atomic number and elemental symbolCerium (atomic symbol: Ce, atomic number: 58) is a Block F, Group 3, Period 6 element with an atomic weight of 140.116. The number of electrons in each of cerium's shells is 2, 8, 18, 19, 9, 2 and its electron configuration is [Xe]4f2 6s2. Cerium Bohr ModelThe cerium atom has a radius of 182.5 pm and a Van der Waals radius of 235 pm. In its elemental form, cerium has a silvery white appearance. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states, the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueous solutions. Elemental CeriumIt is, therefore, strongly acidic and moderately toxic. It is also a strong oxidizer. The cerous state closely resembles the other trivalent rare earths. Cerium is found in the minerals allanite, bastnasite, hydroxylbastnasite, monazite, rhabdophane, synchysite and zircon. Cerium was discovered by Martin Heinrich Klaproth, Jöns Jakob Berzelius, and Wilhelm Hisinger in 1803 and first isolated by Carl Gustaf Mosander in 1839. The element was named after the asteroid Ceres. For more information on cerium, including properties, safety data, research, and American Elements' catalog of cerium products, visit the Cerium Information Center.

HEALTH, SAFETY & TRANSPORTATION INFORMATION
Warning
H315-H319-H335
Xi
36/37/38
26-36
N/A
N/A
3
Exclamation Mark-Acute Toxicity        

CERIUM(III) BROMIDE SYNONYMS
Cerium(III) Bromide Hexahydrate, cerium tribromide, Cerium(III) tribromide

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Cerium

  • Gordon A. Alanko, Brian Jaques, Allyssa Bateman, Darryl P. Butt, Mechanochemical synthesis and spark plasma sintering of the cerium silicides, Journal of Alloys and Compounds, Volume 616, 15 December 2014
  • Chao Lu, Hao Wu, Yun Zhang, Heng Liu, Baojun Chen, Naiteng Wu, Sen Wang, Cerium fluoride coated layered oxide Li1.2Mn0.54Ni0.13Co0.13O2 as cathode materials with improved electrochemical performance for lithium ion batteries, Journal of Power Sources, Volume 267, 1 December 2014
  • Martynas Misevicius, Martynas Kilmanas, Serdar Culunlu, Simas Sakirzanovas, Ayse Uztetik Morkan, Aldona Beganskiene, Aivaras Kareiva, On the sol–gel fabrication and characterization of undoped and cerium-doped Sr4Al14O25, Journal of Alloys and Compounds, Volume 614, 25 November 2014
  • Horng-Huey Ko, Guoli Yang, Moo-Chin Wang, Xiujian Zhao, Thermal behavior and crystallization kinetics of cerium dioxide precursor powders, Ceramics International, Volume 40, Issue 9, Part A, November 2014
  • Lingguang Sun, Qiang Chen, Jiagang Wu, Zhihang Peng, Zhi Tan, Dingquan Xiao, Jianguo Zhu, Dielectric and piezoelectric properties of cerium-doped (NaBi)0.49[ ]0.02Bi2Nb1.98Ta0.02O9-based piezoceramics, Ceramics International, Volume 40, Issue 9, Part A, November 2014
  • Junghwa Park, Dukjoon Kim, Effect of cerium/18-crown-6-ether coordination complex OH quencher on the properties of sulfonated poly(ether ether ketone) fuel cell electrolyte membranes, Journal of Membrane Science, Volume 469, 1 November 2014
  • Leopold Kokou, Jincheng Du, Short- and medium-range structures of cerium aluminophosphate glasses: A molecular dynamics study, Journal of Non-Crystalline Solids, Volume 403, 1 November 2014
  • R. Suresh, V. Ponnuswamy, R. Mariappan, Consequence of source material on the surface properties of nebulizer spray coated cerium oxide thin films, Vacuum, Volume 109, November 2014
  • B. Valdez, S. Kiyota, M. Stoytcheva, R. Zlatev, J.M. Bastidas, Cerium-based conversion coatings to improve the corrosion resistance of aluminium alloy 6061-T6, Corrosion Science, Volume 87, October 2014
  • Yongdeuk Gong, Daewoong Choi, Bo-Young Han, Jonghyun Yoo, Song-Hee Han, Yonghoon Lee, Remote quantitative analysis of cerium through a shielding window by stand-off laser-induced breakdown spectroscopy, Journal of Nuclear Materials, Volume 453, Issues 1–3, October 2014
  • Christofer E. Whiting, John M. Douglas, Bethany M. Cremeans, Chadwick D. Barklay, Daniel P. Kramer, Oxygen exchange reaction kinetics for cerium(IV) oxide at 1000 °C, Journal of Solid State Chemistry, Volume 218, October 2014
  • J.P. Winterstein, C.B. Carter, Electron-beam damage and point defects near grain boundaries in cerium oxide, Journal of the European Ceramic Society, Volume 34, Issue 12, October 2014
  • Saadi Berri, Djamel Maouche, Miloud Ibrir, Badis Bakri, Electronic structure and magnetic properties of the perovskite cerium manganese oxide from ab initio calculations, Materials Science in Semiconductor Processing, Volume 26, October 2014
  • Jayapalan Saranya, Kugalur Shanmugam Ranjith, Padmanaban Saravanan, Devanesan Mangalaraj, Ramasamy Thangavelu Rajendra Kumar, Cobalt-doped cerium oxide nanoparticles: Enhanced photocatalytic activity under UV and visible light irradiation, Materials Science in Semiconductor Processing, Volume 26, October 2014
  • Mahdi Robat Sarpoushi, Mahdi Nasibi, Mohammad Ali Golozar, Mohammad Reza Shishesaz, Mohammad Reza Borhani, Sajad Noroozi, Electrochemical investigation of graphene/cerium oxide nanoparticles as an electrode material for supercapacitors, Materials Science in Semiconductor Processing, Volume 26, October 2014
  • M. van Soestbergen, V. Baukh, S.J.F. Erich, H.P. Huinink, O.C.G. Adan, Release of cerium dibutylphosphate corrosion inhibitors from highly filled epoxy coating systems, Progress in Organic Coatings, Volume 77, Issue 10, October 2014
  • D. Naga Durgasri, T. Vinodkumar, Fangjian Lin, Ivo Alxneit, Benjaram M. Reddy, Gadolinium doped cerium oxide for soot oxidation: Influence of interfacial metal–support interactions, Applied Surface Science, Volume 314, 30 September 2014
  • Cui Ye, Huan Guo, Menghuan Zhang, Hongguo Zhu, Jianqiang Hu, Xuandi Lai, Aiqing Li, Synthesis and enhanced electrochemical property of Au-doped cerium phosphate nanowires, Materials Letters, Volume 131, 15 September 2014
  • Jie Sun, Gang Wang, Preparation and corrosion resistance of cerium conversion coatings on AZ91D magnesium alloy by a cathodic electrochemical treatment, Surface and Coatings Technology, Volume 254, 15 September 2014
  • X. Jiang, S.-H. Song, Enhanced hot ductility of a Cr–Mo low alloy steel by rare earth cerium, Materials Science and Engineering: A, Volume 613, 8 September 2014

Recent Research & Development for Bromides

  • I-Li Chen, Yu-Chen Wei, Tsan-Yao Chen, Chi-Chang Hu, Tsang-Lang Lin, Oxidative precipitation of ruthenium oxide for supercapacitors: Enhanced capacitive performances by adding cetyltrimethylammonium bromide, Journal of Power Sources, Volume 268, 5 December 2014
  • Sarzamin Khan, Leonardo S.A. Carneiro, Eric C. Romani, Dunieskys G. Larrudé, Ricardo Q. Aucelio, Quantification of thyroxine by the selective photoluminescence quenching of l-cysteine–ZnS quantum dots in aqueous solution containing hexadecyltrimethylammonium bromide, Journal of Luminescence, Volume 156, December 2014
  • Ranit Biswas, Karunesh Keshav, Dheeraj Kumar, Anil J. Elias, Reactions of allylzinc bromide with ethynylferrocene derived fluorinated cyclophosphazenes, Journal of Organometallic Chemistry, Volume 768, 1 October 2014
  • Wojciech Streciwilk, Frauke Hackenberg, Helge Müller-Bunz, Matthias Tacke, Synthesis and cytotoxicity studies of p-benzyl substituted NHC–copper(I) bromide derivatives, Polyhedron, Volume 80, 25 September 2014
  • Xiangfeng Jia, Jingfei Chen, Baogang Wang, Weimin Liu, Jingcheng Hao, Molecular dynamics simulation of shape and structure evolution of preassembled cylindrical cetyltrimethylammonium bromide micelles induced by octanol, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 457, 5 September 2014
  • Fei Lu, Lijuan Shi, Han Yan, Xiujie Yang, Liqiang Zheng, Aggregation behavior of dodecyltriphenylphosphonium bromide in aqueous solution: Effect of aromatic ionic liquids, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 457, 5 September 2014
  • C. Carbone, A. Campisi, D. Manno, A. Serra, M. Spatuzza, T. Musumeci, R. Bonfanti, G. Puglisi, The critical role of didodecyldimethylammonium bromide on physico-chemical, technological and biological properties of NLC, Colloids and Surfaces B: Biointerfaces, Volume 121, 1 September 2014
  • Yohei Onodera, Takeshi Usuki, Toshio Nasu, Shinji Kohara, Structure of silver bromide doped chalcogenide glasses, Solid State Ionics, Volume 262, 1 September 2014
  • Zhenjin Fu, Lin Su, Jing Li, Ruizhuang Yang, Zhanwen Zhang, Meifang Liu, Jie Li, Bo Li, Elastic silicone encapsulation of n-hexadecyl bromide by microfluidic approach as novel microencapsulated phase change materials, Thermochimica Acta, Volume 590, 20 August 2014
  • Kaiyue Zhang, Lida Wang, Wen Sun, Guichang Liu, Corrosion inhibitor embedded spherical micro-pits fabricated using cetyltrimethyl ammonium bromide as etching template for self-healing corrosion protection, Corrosion Science, Available online 10 August 2014
  • Maciej Zawadzki, Marta Królikowska, Pawel Lipinski, Physicochemical and thermodynamic characterization of N-alkyl-N-methylpyrrolidinium bromides and its aqueous solutions, Thermochimica Acta, Volume 589, 10 August 2014
  • Magdalena Bielawska, Bronislaw Janczuk, Anna Zdziennicka, Behavior of cetyltrimethylammonium bromide and Triton X-100 mixture at solution–air interface in presence of short-chain alcohols, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 454, 20 July 2014
  • Yawei Shi, Guozhu Liu, Li Wang, Xiangwen Zhang, Ionothermal synthesis of phase pure AlPO4-5 using a series of tri-substituted imidazolium bromides, Microporous and Mesoporous Materials, Volume 193, 15 July 2014
  • Qiang Li, Jin-Hong Lin, Zu-Yong Deng, Jian Zheng, Ji Cai, Ji-Chang Xiao, Wittig gem-difluoroolefination of aldehydes with difluoromethyltriphenylphosphonium bromide, Journal of Fluorine Chemistry, Volume 163, July 2014
  • Edite Cunha, Marieta L.C. Passos, Paula C.A.G. Pinto, M. Lúcia M.F.S. Saraiva, Improved activity of a-chymotrypsin in mixed micelles of cetyltrimethylammonium bromide (CTAB) and ionic liquids: A kinetic study resorting to sequential injection analysis, Colloids and Surfaces B: Biointerfaces, Volume 118, 1 June 2014
  • Shun-Ping Zhao, Yan-Jun She, Chen Xue, Xiao-Qing Huang, Rong-Yi Huang, Heng Xu, Crystal structure and dielectric property of the first bromide/iodide heteroleptic haloplumbate-based lamellate inorganic–organic hybrid compound, Inorganic Chemistry Communications, Volume 44, June 2014
  • Aykut Evren Yavuz, Özgür Masalci, Nadide Kazanci, Phase diagram of tetradecyltrimethylammonium bromide (TTAB) + water + octanol system with application of mechanical deformation, Applied Surface Science, Available online 26 April 2014
  • Huiping Zhang, Highly regioselective ruthenium-catalyzed direct arylation of thiazolo[3,2-b]-1,2,4-triazoles with aryl iodides and aryl bromides via C–H bond activation, Journal of Organometallic Chemistry, Volume 756, 15 April 2014
  • Laura Corte, Matteo Tiecco, Luca Roscini, Raimondo Germani, Gianluigi Cardinali, FTIR analysis of the metabolomic stress response induced by N-alkyltropinium bromide surfactants in the yeasts Saccharomyces cerevisiae and Candida albicans, Colloids and Surfaces B: Biointerfaces, Volume 116, 1 April 2014
  • Wei Hong, Jin Wang, Erkang Wang, Bromide ion mediated synthesis of carbon supported ultrathin palladium nanowires with enhanced catalytic activity toward formic acid/ethanol electrooxidation, International Journal of Hydrogen Energy, Volume 39, Issue 7, 25 February 2014