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Cerium(III) Bromide Hydrate
CeBr3·xH2O
Product
Product Code
 Order or Specifications
(2N) 99% Cerium(III) Bromide Hydrate
CE-BR-02-XHYD
 Contact American Elements
(2N5) 99.5% Cerium(III) Bromide Hydrate
CE-BR-025-XHYD
 Contact American Elements
(3N) 99.9% Cerium(III) Bromide Hydrate
CE-BR-03-XHYD
 Contact American Elements
(3N5) 99.95% Cerium(III) Bromide Hydrate
CE-BR-035-XHYD
 Contact American Elements
(4N) 99.99% Cerium(III) Bromide Hydrate
CE-BR-04-XHYD
 Contact American Elements
(5N) 99.999% Cerium(III) Bromide Hydrate
CE-BR-05-XHYD
 Contact American Elements
Bromide IonCerium(III) Bromide Hydrate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Cerium(Ce) atomic and molecular weight, atomic number and elemental symbolCerium is a Block F, Group 3, Period 6 element. The number of electrons in each of Cerium's shells is 2, 8, 18, 19, 9, 2 and its electronic configuration is [Xe]4f2 6s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is moderately toxic. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueousCerium Bohr Model solutions.It is, therefore,Elemental Cerium strongly acidic and moderately toxic. It is also a strong oxidizer.The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolor glass by keeping iron in its ferrous state. The ability of cerium-doped glass to block out ultra violet light is utilized in the manufacturing of medical glassware and aerospace windows. It is also used to prevent polymers from darkening in sunlight and to suppress discoloration of television glass. Cerium was first discovered by W. von Hisinger in 1903. The element was named after the asteroid Ceres. See Cerium research below.

Formula CAS No. Appearance Molecular Weight
CeBr3·xH2O     379.83
PRODUCT CATALOG Cerium Products Foil Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Home

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

 

 

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Recent Research & Development for Cerium

  • Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium(iii) bromide. Vasudevan KV, Smith NA, Scott BL, Bennett BL, Muenchausen RE, Gordon JC. Dalton Trans. 2011 Dec 23. [Epub ahead of print] PMID: 22193947 [PubMed - as supplied by publisher]

  • Selected Trace Elements in the Sacramento River, California: Occurrence and Distribution. Taylor HE, Antweiler RC, Roth DA, Alpers CN, Dileanis P. Arch Environ Contam Toxicol. 2011 Dec 23. [Epub ahead of print] PMID: 22193863 [PubMed - as supplied by publisher]

  • Electrooxidation of nitrite on a silica-cerium mixed oxide carbon paste electrode. Silveira G, Morais AD, Villis PC, Maroneze CM, Gushikem Y, Lucho AM, Pissetti FL. J Colloid Interface Sci. 2011 Dec 6. [Epub ahead of print] PMID: 22192596 [PubMed - as supplied by publisher]

  • Ceria-engineered nanomaterial distribution in, and clearance from, blood: size matters. Dan M, Wu P, Grulke EA, Graham UM, Unrine JM, Yokel RA. Nanomedicine (Lond). 2012 Jan;7(1):95-110. PMID: 22191779 [PubMed - in process]

  • Effect of Ce(3+) on soluble microbial products production in anaerobic granular sludge digestion. Fu B, Liang R, Xia Q, Ding L, Xu K, Ren H. Water Sci Technol. 2011;64(7):1459-65. PMID: 22179643 [PubMed - in process]

  • [Removal of gaseous elemental mercury over cerium doped low vanadium loading V2O5-WO3/TiO2 in simulated coal-fired flue gas]. Wan Q, Duan L, He KB, Chen L, Li JH. Huan Jing Ke Xue. 2011 Sep;32(9):2800-4. Chinese. PMID: 22165254 [PubMed - in process]

  • Operando DRIFTS study of the redox and catalytic properties of CuO/Ce(1-x)Tb(x)O(2-d) (x = 0-0.5) catalysts: evidence of an induction step during CO oxidation. Martínez-Arias A, Hungría AB, Fernández-García M, Iglesias-Juez A, Soria J, Conesa JC, Anderson JA, Munuera G. Phys Chem Chem Phys. 2011 Dec 8. [Epub ahead of print] PMID: 22159154 [PubMed - as supplied by publisher]

  • Classical oxidant induced chemiluminescence of fluorescent carbon dots. Lin Z, Xue W, Chen H, Lin JM. Chem Commun (Camb). 2011 Dec 8. [Epub ahead of print] PMID: 22158939 [PubMed - as supplied by publisher]

  • Gamma-ray fast-timing coincidence measurements from the (18)O+(18)O fusion-evaporation reaction using a mixed LaBr(3)-HPGe array. Alharbi T, Mason PJ, Regan PH, Podolyák Z, Marginean N, Nakhostin M, Bowry M, Bucurescu D, Cata-Danil G, Cata-Danil I, Deleanu D, Filipescu D, Glodariu T, Ghita D, Marginean R, Mihai C, Negret A, Pascu S, Sava T, Stroe L, Suliman G, Zamfir NV, Bruce AM, Rodriguez Triguero C, Bender PC, Garg U, Erduran MN, Kusoglu A, Bostan M, Detistov P, Alkhomashi N, Sinha AK, Chakrabarti R, Ghugre SS. Appl Radiat Isot. 2011 Dec 3. [Epub ahead of print] PMID: 22154387 [PubMed - as supplied by publisher]

  • Cationic Surface Reconstructions on Cerium Oxide Nanocrystals: An Aberration Corrected HRTEM Study. Bhatta UM, Ross IM, Sayle TX, Sayle DC, Parker SC, Reid D, Seal S, Kumar A, Moebus G. ACS Nano. 2011 Dec 13. [Epub ahead of print] PMID: 22148265 [PubMed - as supplied by publisher]

  • In-house SAD phasing with surface-bound cerium ions. Vennila KN, Velmurugan D. Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Dec 1;67(Pt 12):1662-5. Epub 2011 Nov 25. PMID: 22139192 [PubMed - in process]

  • High concentrations of cadmium, cerium and lanthanum in indoor air due to environmental tobacco smoke. Böhlandt A, Schierl R, Diemer J, Koch C, Bolte G, Kiranoglu M, Fromme H, Nowak D. Sci Total Environ. 2011 Dec 1. [Epub ahead of print] PMID: 22137652 [PubMed - as supplied by publisher]

  • A cholesterol and actinide dependent shadow biosphere of archaea and viroids in autoimmune diseases. Kurup R, Kurup PA. Immunobiology. 2011 Oct 25. [Epub ahead of print] PMID: 22137029 [PubMed - as supplied by publisher]

  • On the interaction of Mg with the (111) and (110) surfaces of ceria. Nolan M, Lykhach Y, Tsud N, Skála T, Staudt T, Prince KC, Matolín V, Libuda J. Phys Chem Chem Phys. 2011 Dec 14;14(3):1293-301. Epub 2011 Dec 1. PMID: 22134463 [PubMed - in process]

  • Measurement of redox potential in nanoecotoxicological investigations. Tantra R, Cackett A, Peck R, Gohil D, Snowden J. J Toxicol. 2012;2012:270651. Epub 2011 Oct 31. PMID: 22131988 [PubMed - in process]

  • In situ characterization of Pt catalysts supported on ceria modified TiO(2) for the WGS reaction: influence of ceria loading. Barrio L, Zhou G, González ID, Estrella M, Hanson J, Rodriguez JA, Navarro RM, Fierro JL. Phys Chem Chem Phys. 2011 Dec 1. [Epub ahead of print] PMID: 22130010 [PubMed - as supplied by publisher]

  • The oxidation state of Hadean magmas and implications for early Earth's atmosphere. Trail D, Watson EB, Tailby ND. Nature. 2011 Nov 30;480(7375):79-82. doi: 10.1038/nature10655. PMID: 22129728 [PubMed - in process]

  • Preparation methods and thermal stability of Ba-Mn-Ce oxide catalyst for NO(x)-assisted soot oxidation. Wu X, Lin F, Wang L, Weng D, Zhou Z. J Environ Sci (China). 2011;23(7):1205-10. PMID: 22125916 [PubMed - indexed for MEDLINE]

  • The oxidative degradation of dibenzoazepine derivatives by cerium(iv) complexes in acidic sulfate media. Wisniewska J, Wrzeszcz G, Kurzawa M, van Eldik R. Dalton Trans. 2011 Nov 29. [Epub ahead of print] PMID: 22124379 [PubMed - as supplied by publisher]

  • Effect of support size on the catalytic activity of metal-oxide-doped silica particles in the glycolysis of polyethylene terephthalate. Wi R, Imran M, Lee KG, Yoon SH, Cho BG, Kim do H. J Nanosci Nanotechnol. 2011 Jul;11(7):6544-9. PMID: 22121753 [PubMed - in process]

 

Recent Research & Development for Bromides
  • Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids. Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C. Org Lett. 2010 Jan 5. [Epub ahead of print] PMID: 19689116 [PubMed - as supplied by publisher]

  • Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides. Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Science. 2009 Aug 13. [Epub ahead of print] PMID: 19679769 [PubMed - as supplied by publisher]

  • (2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides. Zhang Q, Wang D, Wang X, Ding K. J Org Chem. 2009 Aug 12. [Epub ahead of print] PMID: 19673481 [PubMed - as supplied by publisher]

  • Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides. Vechorkin O, Barmaz D, Proust V, Hu X. J Am Chem Soc. 2009 Aug 11. [Epub ahead of print] PMID: 19670863 [PubMed - as supplied by publisher]

  • Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia. Huang JM, Dong Y. Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28. PMID: 19662260 [PubMed - in process]

  • Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols. Salvi L, Kim JG, Walsh PJ. J Am Chem Soc. 2009 Aug 4. [Epub ahead of print] PMID: 19653691 [PubMed - as supplied by publisher]

  • Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines. Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J. J Comb Chem. 2009 Jul 31. [Epub ahead of print] PMID: 19645499 [PubMed - as supplied by publisher]

  • Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids. del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N. Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29. PMID: 19641822 [PubMed - in process]

  • Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides. Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639999 [PubMed - as supplied by publisher]

  • Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies. Snelders DJ, van Koten G, Klein Gebbink RJ. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639941 [PubMed - as supplied by publisher]

  • Can One Predict Changes from S(N)1 to S(N)2 Mechanisms? Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H. J Am Chem Soc. 2009 Jul 27. [Epub ahead of print] PMID: 19634906 [PubMed - as supplied by publisher]

  • A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides. Liao Q, Wang Y, Zhang L, Xi C. J Org Chem. 2009 Jul 15. [Epub ahead of print] PMID: 19603753 [PubMed - as supplied by publisher]

  • Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides. Shi L, Chu Y, Knochel P, Mayr H. Org Lett. 2009 Jul 14. [Epub ahead of print] PMID: 19601592 [PubMed - as supplied by publisher]

  • C5-Modified nucleosides exhibiting anticancer activity. Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH. Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21. PMID: 19596579 [PubMed - in process]

  • Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines. Vo GD, Hartwig JF. J Am Chem Soc. 2009 Jul 10. [Epub ahead of print] PMID: 19591470 [PubMed - as supplied by publisher]

  • New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes. Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B. Org Lett. 2009 Jul 2. [Epub ahead of print] PMID: 19572730 [PubMed - as supplied by publisher]

  • The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives. Jo Y, Ju J, Choe J, Song KH, Lee S. J Org Chem. 2009 Jul 2. [Epub ahead of print] PMID: 19572571 [PubMed - as supplied by publisher]

  • Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents. Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH. Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8. PMID: 19557114 [PubMed - in process]

  • A facile route to C2-substituted imidazolium ionic liquids. Ennis E, Handy ST. Molecules. 2009 Jun 19;14(6):2235-45. PMID: 19553895 [PubMed - in process]

  • Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines. McCall WS, Comins DL. Org Lett. 2009 Jul 2;11(13):2940-2. PMID: 19552467 [PubMed - indexed for MEDLINE]

 

 

 

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