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Erbium
Erbium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Erbium has application in glass coloring, as an amplifier in fiber optics, and in lasers for medical and dental use. Erbium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. The ion has a very narrow absorption band coloring erbium salts pink. It is therefore used in eyeware and decorative glassware. It can neutralize discoloring impurities such as ferric ions and produce a neutral gray shade. It is used in a variety of glass products for this purpose. It is particularly useful as an amplifier for fiber optic data transfer. Erbium lases at the wavelength required to provide an efficient optical method of amplification, 1.55 microns. Lasers based on Er:YAG are ideally suited for surgical applications because of its ability to deliver energy without thermal build-up in tissue.

Erbium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

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      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Erbium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Erbium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f126s2. In its elemental form erbium's CAS number is 7440-52-0. The erbium atom has a radius of 173.4.pm and it's Van der Waals radius is unknown.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Erbium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Erbium was first discovered by Carl Mosander in 1843.

French erbium German Erbium Italian erbio Portuguese Érbio Spanish erbio Swedish Erbium

Erbium Abundance. The following table shows the abundance of Erbium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Er-162
161.929
0.14
Er-164
163.929
1.61
Er-166
165.930
33.6
Er-167
166.932
22.95
Er-168
167.932
26.8
Er-170
169.935
14.9

Erbium Safety Data. The safety data for Erbium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for Erbium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
589.31 kJ mol-1
2nd Ionization Energy
1151.08 kJ mol-1
3rd Ionization Energy
2194.09 kJ mol-1

Conductivity. As to Erbium's electrical and thermal conductivity, the electrical conductivity measured in terms of electrical resistivity @ 20 ºC is 107 µOcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.24. The thermal conductivity of Erbium is 14.3 W m-1 K-1.

Thermal Properties of Erbium. The melting point and boiling point for Erbium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
17.2 kJ mol-1
Heat of Vaporization
280 kJ mol-1
Heat of Atomization
318.32 kJ mol-1



 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Er 68 167.26 g.mol -1 1.2 9.2 g.cm-3 at 20 °C 1522 °C 2510 °C unknown unknown 587.6 kJ.mol-1

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Recent Research & Development for Erbium

  • Influence of etching time on bond strength in dentin irradiated with erbium lasers. Ferreira LS, Apel C, Francci C, Simoes A, Eduardo CP, Gutknecht N. Lasers Med Sci. 2009 Aug 6. [Epub ahead of print] PMID: 19655225 [PubMed - as supplied by publisher]

  • A phase-stabilized carbon nanotube fiber laser frequency comb. Lim J, Knabe K, Tillman KA, Neely W, Wang Y, Amezcua-Correa R, Couny F, Light PS, Benabid F, Knight JC, Corwin KL, Nicholson JW, Washburn BR. Opt Express. 2009 Aug 3;17(16):14115-20. PMID: 19654821 [PubMed - in process]

  • Widely tunable multi-wavelength Brillouinerbium fiber laser utilizing low SBS threshold photonic crystal fiber. Mohd Nasir MN, Yusoff Z, Al-Mansoori MH, Abdul Rashid HA, Choudhury PK. Opt Express. 2009 Jul 20;17(15):12829-34. PMID: 19654689 [PubMed - in process]

  • Multi-wavelength dissipative soliton operation of an erbium-doped fiber laser. Zhang H, Tang DY, Wu X, Zhao LM. Opt Express. 2009 Jul 20;17(15):12692-7. PMID: 19654674 [PubMed - in process]

  • The effect of erbium, chromium:yttrium-scandium-gallium-garnet laser etching on marginal integrity of a resin-based fissure sealant in primary teeth. Sungurtekin E, Oztas N. Lasers Med Sci. 2009 Aug 5. [Epub ahead of print] PMID: 19653059 [PubMed - as supplied by publisher]

  • Determination of the formation constant for the inclusion complex between Lanthanide ions and Dansyl chloride derivative by fluorescence spectroscopy: Theoretical and experimental investigation. Riahi S, Ganjali MR, Hariri M, Abdolahzadeh S, Norouzi P. Spectrochim Acta A Mol Biomol Spectrosc. 2009 Jun 16. [Epub ahead of print] PMID: 19643660 [PubMed - as supplied by publisher]

  • Evaluation of Effectiveness of Er,Cr:YSGG Laser For Root Canal Disinfection: Theoretical Simulation of Temperature Elevations in Root Dentin. Zhu L, Tolba M, Arola D, Salloum M, Meza F. J Biomech Eng. 2009 Jul;131(7):071004. PMID: 19640129 [PubMed - in process]

  • Comparison of a 1,550 nm Erbium:Glass fractional laser and a chemical reconstruction of skin scars (CROSS) method in the treatment of acne scars: A simultaneous split-face trial. Kim HJ, Kim TG, Kwon YS, Park JM, Lee JH. Lasers Surg Med. 2009 Jul 28. [Epub ahead of print] PMID: 19639620 [PubMed - as supplied by publisher]

  • In vitro investigation of intra-canal dentine-laser beam interaction aspects: I. Evaluation of ablation capability (ablation rate and efficiency). Minas NH, Meister J, Franzen R, Gutknecht N, Lampert F. Lasers Med Sci. 2009 Jul 28. [Epub ahead of print] PMID: 19636663 [PubMed - as supplied by publisher]

  • Er:Yag Laser application on titanium implant surfaces contaminated by Porphyromonas gingivalis: an histomorphometric evaluation. Quaranta A, Maida C, Scrascia A, Campus G, Quaranta M. Minerva Stomatol. 2009 Jul-Aug;58(7-8):317-30. PMID: 19633633 [PubMed - in process]

  • Homo- and Heterodinuclear Helicates of Lanthanide(III), Zinc(II) and Aluminium(III) Based on 8-Hydroxyquinoline Ligands. Albrecht M, Osetska O, Bünzli JC, Gumy F, Fröhlich R. Chemistry. 2009 Jul 20. [Epub ahead of print] PMID: 19621398 [PubMed - as supplied by publisher]

  • Combined fractional laser treatment with 1550-nm erbium glass and 10 600-nm carbon dioxide lasers. Cho SB, Lee SJ, Kang JM, Kim YK, Oh SH. J Dermatolog Treat. 2009 Jan 1:1-3. [Epub ahead of print] No abstract available. PMID: 19603309 [PubMed - as supplied by publisher]

  • A three-dimensional evaluation of microleakage of class V cavities prepared by the very short pulse mode of the erbium:yttrium-aluminium-garnet laser. Krmek SJ, Bogdan I, Simeon P, Mehicic GP, Katanec D, Anic I. Lasers Med Sci. 2009 Jul 11. [Epub ahead of print] PMID: 19593602 [PubMed - as supplied by publisher]

  • Role of laser therapy in pediatric patients. Burns AJ, Navarro JA. Plast Reconstr Surg. 2009 Jul;124(1 Suppl):82e-92e. PMID: 19568142 [PubMed - in process]

  • Enhancement of bonding to enamel and dentin prepared by Er,Cr:YSGG laser. Obeidi A, McCracken MS, Liu PR, Litaker MS, Beck P, Rahemtulla F. Lasers Surg Med. 2009 Aug;41(6):454-62. PMID: 19588530 [PubMed - in process] Related Articles 16: Frequency-switchable microwave generation based on a dual-wavelength single-longitudinal-mode fiber laser incorporating a high-finesse ring filter. Pan S, Yao J. Opt Express. 2009 Jul 6;17(14):12167-73. PMID: 19582131 [PubMed - in process]

  • Influence of energy-transfer-upconversion on threshold pump power in quasi-three-level solid-state lasers. Kim JW, Mackenzie JI, Clarkson WA. Opt Express. 2009 Jul 6;17(14):11935-43. PMID: 19582108 [PubMed - in process]

  • Investigation on the effect of EDFA location in ring cavity Brillouin-Erbium fiber laser. Hambali NA, Mahdi MA, Al-Mansoori MH, Abas AF, Saripan MI. Opt Express. 2009 Jul 6;17(14):11768-75. PMID: 19582091 [PubMed - in process]

  • Dissipative solitons in a passively mode-locked Er-doped fiber with strong normal dispersion. Cabasse A, Ortaç B, Martel G, Hideur A, Limpert J. Opt Express. 2008 Nov 10;16(23):19322-9. PMID: 19582026 [PubMed - indexed for MEDLINE]

  • Scaling of passively mode-locked soliton erbium waveguide lasers based on slow saturable absorbers. Pudo D, Byun H, Chen J, Sickler J, Kärtner FX, Ippen EP. Opt Express. 2008 Nov 10;16(23):19221-31. PMID: 19582014 [PubMed - indexed for MEDLINE]

 

 

 

 

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