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Iridium
Iridium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Iridium is a member of the platinum group of metals. It is the most corrosion resistant metal known. It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. It is alloyed with platinum to produce highly corrosive resistant electrical contacts for spark plugs. Iridium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Iridium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Iridium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Iridium is a Block D, Group 9, Period 6 element. The electronic configuration is [Xe] 4f14 5d7 6s2. In its elemental form iridium's CAS number is 7439-88-5. The iridium atom has a radius of 135.7.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Iridium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Iridium was first discovered by Smithson Tennant in 1804.

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Abundance. The following table shows the abundance of iridium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Ir-191
190.960591
37.3
Ir-193
192.962924
62.7

Safety Data. The safety data for iridium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for iridium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
865.19 kJ mol-1
2nd Ionization Energy
- kJ mol-1
3rd Ionization Energy
- kJ mol-1

Conductivity. As to iridium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 5.3 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.2. The thermal conductivity of iridium is 147 W m-1 K-1.

Thermal Properties. The melting point and boiling point for iridium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
26.4 kJ mol-1
Heat of Vaporization
612.1 kJ mol-1
Heat of Atomization
664.34 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Ir 77 192.2 g.mol -1 2.2 22.4 g.cm-3 at 20 °C 2450 °C 4527 °C 200.pm 0.066 nm (+4)) 865.19 kJ.mol-1

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Recent Research & Development for Iridium

  • High Oxidation State Rhodium and Iridium Bis(silyl)dihydride Complexes Supported by a Chelating Pyridyl-Pyrrolide Ligand. McBee JL, Escalada J, Tilley TD. J Am Chem Soc. 2009 Aug 14. [Epub ahead of print] PMID: 19681602 [PubMed - as supplied by publisher]

  • Polymorphism-induced dual phosphorescent emission from solid-state iridium(III) complex. Shin CH, Huh JO, Lee MH, Do Y. Dalton Trans. 2009 Sep 7;(33):6476-9. Epub 2009 Jul 2. PMID: 19672491 [PubMed - in process]

  • Oxygen Atom Transfer Reactions of Iridium and Osmium Complexes: Theoretical Study of Characteristic Features and Significantly Large Differences Between These Two Complexes. Ishikawa A, Nakao Y, Sato H, Sakaki S. Inorg Chem. 2009 Aug 11. [Epub ahead of print] PMID: 19670885 [PubMed - as supplied by publisher]

  • Authentic-Blue Phosphorescent Iridium(III) Complexes Bearing Both Hydride and Benzyl Diphenylphosphine; Control of the Emission Efficiency by Ligand Coordination Geometry. Chiu YC, Lin CH, Hung JY, Chi Y, Cheng YM, Wang KW, Chung MW, Lee GH, Chou PT. Inorg Chem. 2009 Aug 11. [Epub ahead of print] PMID: 19670882 [PubMed - as supplied by publisher]

  • Synthetic, Mechanistic, and Theoretical Studies on the Generation of Iridium Hydride Alkylidene and Iridium Hydride Alkene Isomers. Lara P, Paneque M, Poveda ML, Santos LL, Valpuesta JE, Salazar V, Carmona E, Moncho S, Ujaque G, Lledós A, Maya C, Mereiter K. Chemistry. 2009 Aug 7. [Epub ahead of print] PMID: 19670194 [PubMed - as supplied by publisher]

  • Bifunctional Green Iridium Dendrimers with a "Self-Host" Feature for Highly Efficient Nondoped Electrophosphorescent Devices. Ding J, Wang B, Yue Z, Yao B, Xie Z, Cheng Y, Wang L, Jing X, Wang F. Angew Chem Int Ed Engl. 2009 Aug 7;48(36):6664-6666. [Epub ahead of print] No abstract available. PMID: 19662672 [PubMed - as supplied by publisher]

  • Efficient deep-red light-emitting electrochemical cells based on a perylenediimide-iridium-complex dyad. Costa RD, Céspedes-Guirao FJ, Ortí E, Bolink HJ, Gierschner J, Fernández-Lázaro F, Sastre-Santos A. Chem Commun (Camb). 2009 Jul 14;(26):3886-8. Epub 2009 May 20. PMID: 19662241 [PubMed - in process]

  • Iridium Phosphite-Oxazoline Catalysts for the Highly Enantioselective Hydrogenation of Terminal Alkenes. Mazuela J, Verendel JJ, Coll M, Scha¨ffner B, Bo¨rner A, Andersson PG, Pa`mies O, Die´guez M. J Am Chem Soc. 2009 Aug 6. [Epub ahead of print] PMID: 19658416 [PubMed - as supplied by publisher]

  • Experimental and Computational Studies on the Iridium Activation of Aliphatic and Aromatic C--H Bonds of Alkyl Aryl Ethers and Related Molecules. Lara P, Paneque M, Poveda ML, Santos LL, Valpuesta JE, Carmona E, Moncho S, Ujaque G, Lledós A, Alvarez E, Mereiter K. Chemistry. 2009 Aug 5. [Epub ahead of print] PMID: 19658130 [PubMed - as supplied by publisher]

  • Catalytic (transfer) deuterogenation in D(2)O as deuterium source with H(2) and HCO(2)H as electron sources. Himeda Y, Miyazawa S, Onozawa-Komatsuzaki N, Hirose T, Kasuga K. Dalton Trans. 2009 Aug 28;(32):6286-8. Epub 2009 Jun 29. PMID: 19655059 [PubMed - in process]

  • Dosimetric parameters in partial breast irradiation through brachytherapy. Gloi A, McCourt S, Buchanan R, Goetller A, Zuge C, Balzoa P, Cooley G. Med Dosim. 2009 Fall;34(3):207-13. Epub 2008 Sep 21. PMID: 19647630 [PubMed - in process]

  • White-light phosphorescence emission from a single molecule: application to OLED. Bolink HJ, De Angelis F, Baranoff E, Klein C, Fantacci S, Coronado E, Sessolo M, Kalyanasundaram K, Grätzel M, Nazeeruddin MK. Chem Commun (Camb). 2009 Aug 21;(31):4672-4. Epub 2009 Jun 23. PMID: 19641805 [PubMed - in process]

  • Site-isolated iridium complexes on MgO powder: individual Ir atoms imaged by scanning transmission electron microscopy. Uzun A, Ortalan V, Browning ND, Gates BC. Chem Commun (Camb). 2009 Aug 21;(31):4657-9. Epub 2009 Mar 23. PMID: 19641800 [PubMed - in process]

  • A single-atom sharp iridium tip as an emitter of gas field ion sources. Kuo HS, Hwang IS, Fu TY, Hwang YS, Lu YH, Lin CY, Hou JL, Tsong TT. Nanotechnology. 2009 Aug 19;20(33):335701. Epub 2009 Jul 28. PMID: 19636091 [PubMed - in process]

  • Luminescence Switching of a Cyclometalated Iridium(III) Complex through a Redox-active Tetrathiafulvalene-based Ligand. Xu CH, Sun W, Zhang C, Zhou C, Fang CJ, Yan CH. Chemistry. 2009 Jul 23. [Epub ahead of print] No abstract available. PMID: 19630023 [PubMed - as supplied by publisher]

  • Intramolecular Ir(I)-Catalyzed Benzylic C-H Bond Amination of ortho-Substituted Aryl Azides. Sun K, Sachwani R, Richert KJ, Driver TG. Org Lett. 2009 Jul 23. [Epub ahead of print] PMID: 19627144 [PubMed - as supplied by publisher]

  • Microwave-Accelerated Iridium-Catalyzed Borylation of Aromatic C-H Bonds. Harrisson P, Morris J, Marder TB, Steel PG. Org Lett. 2009 Jul 23. [Epub ahead of print] PMID: 19627109 [PubMed - as supplied by publisher]

  • Toward real-time continuous brain glucose and oxygen monitoring with a smart catheter. Li C, Ahn CH, Shutter LA, Narayan RK. Biosens Bioelectron. 2009 Sep 15;25(1):173-8. Epub 2009 Jun 26. PMID: 19625179 [PubMed - in process]

  • Late Metal Carbene Complexes Generated by Multiple C-H Activations: Examining the Continuum of M horizontal lineC Bond Reactivity. Whited MT, Grubbs RH. Acc Chem Res. 2009 Jul 22. [Epub ahead of print] PMID: 19624162 [PubMed - as supplied by publisher]

  • Carbon-hydrogen vs. carbon-halogen oxidative addition of chlorobenzene by a neutral iridium complex explored by DFT. Wu H, Hall MB. Dalton Trans. 2009 Aug 14;(30):5933-42. Epub 2009 May 5. PMID: 19623394 [PubMed - in process]

 

 

 

 

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