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Iridium
Iridium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Iridium is a member of the platinum group of metals. It is the most corrosion resistant metal known. It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. It is alloyed with platinum to produce highly corrosive resistant electrical contacts for spark plugs. Iridium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Iridium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Iridium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Iridium is a Block D, Group 9, Period 6 element. The electronic configuration is [Xe] 4f14 5d7 6s2. In its elemental form iridium's CAS number is 7439-88-5. The iridium atom has a radius of 135.7.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Iridium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Iridium was first discovered by Smithson Tennant in 1804.

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Abundance. The following table shows the abundance of iridium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Ir-191
190.960591
37.3
Ir-193
192.962924
62.7

Safety Data. The safety data for iridium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for iridium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
865.19 kJ mol-1
2nd Ionization Energy
- kJ mol-1
3rd Ionization Energy
- kJ mol-1

Conductivity. As to iridium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 5.3 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.2. The thermal conductivity of iridium is 147 W m-1 K-1.

Thermal Properties. The melting point and boiling point for iridium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
26.4 kJ mol-1
Heat of Vaporization
612.1 kJ mol-1
Heat of Atomization
664.34 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Ir 77 192.2 g.mol -1 2.2 22.4 g.cm-3 at 20 °C 2450 °C 4527 °C 200.pm 0.066 nm (+4)) 865.19 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Iridium

  • Electrochemical treatment of tannery wastewater using DSA((R)) electrodes. J Hazard Mater. 2008 May 1;153(1-2):616-27. Epub 2007 Sep 6.

  • Light-emitting iridium complexes with tridentate ligands. Dalton Trans. 2008 Apr 28;(16):2081-99. Epub 2008 Feb 19.

  • Recent advances in enantioselective [2 + 2 + 2] cycloaddition. Org Biomol Chem. 2008 Apr 21;6(8):1317-23. Epub 2008 Mar 12.

  • Determining chondritic impactor size from the marine osmium isotope record. Science. 2008 Apr 11;320(5873):214-8.

  • Effective shielding of triplet energy transfer to conjugated polymer by its dense side chains from phosphor dopant for highly efficient electrophosphorescence. J Am Chem Soc. 2008 Apr 9;130(14):4699-707. Epub 2008 Mar 13.

  • Highly Efficient Sensitized Red Emission from Europium (III) in Ir-Eu Bimetallic Complexes by (3)MLCT Energy Transfer. Inorg Chem. 2008 Apr 7;47(7):2507-13. Epub 2008 Feb 27.

  • What is the value of emission tomography studies in patients with a primary glioblastoma multiforme treated by 192Ir brachytherapy? Acta Neurochir (Wien). 2008 Apr;150(4):345-9. Epub 2008 Feb 19.

  • Comparison of (60)Cobalt and (192)Iridium Sources in High Dose Rate Afterloading Brachytherapy. Strahlenther Onkol. 2008 Apr;184(4):187-192.

  • Effect of ultrasound sonication on electroplating of iridium. Ultrason Sonochem. 2008 Apr;15(4):283-8. Epub 2007 Nov 21.

  • Asymmetric Hydrogenation of Di and Trisubstituted Enol Phosphinates with N,P-Ligated Iridium Complexes. J Am Chem Soc. 2008 Mar 28; [Epub ahead of print]

  • Signal amplification via intramolecular energy transfer using tripodal neutral iridium(III) complexes upon binding to avidin. J Am Chem Soc. 2008 Mar 26;130(12):3726-7. Epub 2008 Mar 4.

  • Initial exploration of Ti-Ta, Ti-Ta-Ir and Ti-Ir alloys: Candidate materials for coronary stents. Acta Biomater. 2008 Mar 20; [Epub ahead of print]

  • Solid-state white light-emitting electrochemical cells using iridium-based cationic transition metal complexes. J Am Chem Soc. 2008 Mar 19;130(11):3413-9. Epub 2008 Feb 27.

  • Synthesis, Separation, and Circularly Polarized Luminescence Studies of Enantiomers of Iridium(III) Luminophores. Inorg Chem. 2008 Mar 17;47(6):2039-48. Epub 2008 Feb 14.

  • Luminescent Cyclometalated Rh(III), Ir(III), and (DIP)2Ru(II) Complexes with Carboxylated Bipyridyl Ligands: Synthesis, X-ray Molecular Structure, and Photophysical Properties. Inorg Chem. 2008 Mar 15; [Epub ahead of print]

  • Photophysical properties of heteroleptic iridium complexes containing carbazole-functionalized beta-diketonates. Chemphyschem. 2008 Mar 14;9(4):634-40.

  • Highly active iridium(I) complexes for catalytic hydrogen isotope exchange. Chem Commun (Camb). 2008 Mar 7;(9):1115-7. Epub 2008 Jan 3.

  • Paleontology. Experts find no evidence for a mammoth-killer impact. Science. 2008 Mar 7;319(5868):1331-2. No abstract available.

  • Iridium-catalyzed C-C coupling via transfer hydrogenation: carbonyl addition from the alcohol or aldehyde oxidation level employing 1,3-cyclohexadiene. Org Lett. 2008 Mar 6;10(5):1033-5. Epub 2008 Feb 7.

  • Novel four-pyridylbenzene-armed biphenyls as electron-transport materials for phosphorescent OLEDs. Org Lett. 2008 Mar 6;10(5):941-4. Epub 2008 Feb 1.

 

 

 

 

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