Reactive Silver Oxalate Ink Composition with Enhanced Curing Conditions for Flexible Substrates.

Title Reactive Silver Oxalate Ink Composition with Enhanced Curing Conditions for Flexible Substrates.
Authors K.Ramesh Zope; D.D. Cormier; S. Williams
Journal ACS Appl Mater Interfaces
DOI 10.1021/acsami.7b19161
Abstract

A solid silver - ligand complex, µ-oxolato-bis(ethylenediaminesilver(I)), was developed for formulating particle-free conductive metal-organic decomposition (MOD) ink jet inks. The complex comprises both a high molar silver content and solubility in ink-jet compatible polar solvents. An aqueous ink formulation with 29.5 wt.% silver content was developed and ink jet printed onto glass, polyethylene terephthalate (PET), and polyimide substrates. A new hybrid thermal-photonic curing approach resulting in substantially improved electrical properties and substrate adhesion is presented. Silver conductive traces were measured to have bulk resistivity of 4.26 x 10-8 ??m, which is 2.7 times that of bulk silver. One-pot complex synthesis yielded an easily isolated, and stable, solid product that can be formulated when needed thereby improving shelf-life.

Citation K.Ramesh Zope; D.D. Cormier; S. Williams.Reactive Silver Oxalate Ink Composition with Enhanced Curing Conditions for Flexible Substrates.. ACS Appl Mater Interfaces. 2018. doi:10.1021/acsami.7b19161

Related Elements

Silver

See more Silver products. Silver (atomic symbol: Ag, atomic number: 47) is a Block D, Group 11, Period 5 element with an atomic weight of 107.8682. Silver Bohr ModelThe number of electrons in each of Silver's shells is 2, 8, 18, 18, 1 and its electron configuration is [Kr]4d10 5s1. The silver atom has a radius of 144 pm and a Van der Waals radius of 203 pm. Silver was first discovered by Early Man prior to 5000 BC. In its elemental form, silver has a brilliant white metallic luster. Elemental SilverIt is a little harder than gold and is very ductile and malleable, being exceeded only by gold and perhaps palladium. Pure silver has the highest electrical and thermal conductivity of all metals and possesses the lowest contact resistance. It is stable in pure air and water, but tarnishes when exposed to ozone, hydrogen sulfide, or air containing sulfur. It is found in copper, copper-nickel, lead, and lead-zinc ores, among others. Silver was named after the Anglo-Saxon word "seolfor" or "siolfur," meaning 'silver'.

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