Structural and spectroscopic study of arsenate and vanadate incorporation into apatite group: Implications for semi-quantitative estimation of As and V contents in apatite.

Title Structural and spectroscopic study of arsenate and vanadate incorporation into apatite group: Implications for semi-quantitative estimation of As and V contents in apatite.
Authors H. Song; J. Liu; H. Cheng
Journal Spectrochim Acta A Mol Biomol Spectrosc
DOI 10.1016/j.saa.2017.07.028
Abstract

The solid solutions of mimetite-vanadinite series were synthesized at room temperature through aqueous precipitation method and were characterized with Scanning Electron Microscope-Energy Dispersive Spectrometer (SEM-EDS), X-ray diffraction (XRD), infrared and Raman spectroscopy. Based on the XRD analyses, it showed that all the samples crystallize with the same structure. A and c parameters vary smoothly with substitution of AsO43- for VO43-. In the FT-IR spectra of mimetite-vanadinite solid solutions series, the bands corresponding to stretching (v3) vibrations of AsO43- and VO43- ions were observed in the range 700-900cm-1, and the bending (v4) vibrations of OAsO and OVO were observed in the range 310-400cm-1. In the Raman spectra, the bands attributed to vibrations in the VO43- appeared at 830-700cm-1, 420-290cm-1. The bands attributed to vibrations in the AsO43- appeared in the ranges 740-820cm-1, 410-310cm-1. In addition, the peak positions of the dominant antisymmetric stretching (v3) of VO bond around 706cm-1 of IR spectra for the prepared solids also varies with the different As/(As+V) ratio, and the relationship is linear, which can be an implication for semi-quantitative estimation of As and V contents in lead apatites.

Citation H. Song; J. Liu; H. Cheng.Structural and spectroscopic study of arsenate and vanadate incorporation into apatite group: Implications for semi-quantitative estimation of As and V contents in apatite.. Spectrochim Acta A Mol Biomol Spectrosc. 2018;188:488494. doi:10.1016/j.saa.2017.07.028

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Vanadium

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