Tantalum Zirconium Oxide is a highly insoluble thermally stable Aluminum source suitable for glass, optic and ceramic applications. Oxide compounds are not conductive to electricity. However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems. They are compounds containing at least one oxygen anion and one metallic cation. They are typically insoluble in aqueous solutions (water) and extremely stable making them useful in ceramic structures as simple as producing clay bowls to advanced electronics and in light weight structural components in aerospace and electrochemical applications such as fuel cells in which they exhibit ionic conductivity. Metal oxide compounds are basic anhydrides and can therefore react with acids and with strong reducing agents in redox reactions. Tantalum Zirconium Oxide is also available in pellets, pieces, powder, sputtering targets, tablets, and nanopowder (from American Elements' nanoscale production facilities). See Nanotechnology for more nanotechnology applications information. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety (MSDS) information is available.
Tantalum is a Block D, Group 5, Period 6 element. The number of electrons in each of Tantalum's shells is 2, 8, 18, 32, 11, 2 and its electronic configuration is [Xe] 4f14 5d3 6s2. In its elemental form tantalum's CAS number is 7440-25-7. The tantalum atom has a radius of 143.pm and it's Van der Waals radius is 200.pm. Tantalum is not toxic. Tantalum has a number of interesting properties that make it particularly useful in electronic applications. Tantalum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It has the third highest melting point, surpassed only by rhenium and tungsten, yet it is highly conductive to heat and electricity. This has made it the material of choice for electronic capacitors for most telecommunications and hand held electronics equipment, such as cell phones, laptop computers and pagers. Tantalum compounds, such as the oxide and chloride, are the basis for di-electric coatings. Tantalum is added to glass for its high refractive index. It has various applications in nuclear energy. Due to the close relation of tantalum to niobium in the periodic table, Tantalum's name originates from the Greek word Tantalos meaning Father of Niobe in Greek mythology. See Tantalum research below. See Tantalum research below.
Zirconium is a Block D, Group 4, Period 5 element. The number of electrons in each of Zirconium's shells is 2, 8, 18, 10, 2 and its electronic configuration is [Kr] 4d2 5s2. In its elemental form zirconium's CAS number is 7440-67-7. The zirconium atom has a radius of 159.pm and it's Van der Waals radius is 200.pm. Zirconium is non-toxic. Zirconium’s principal mineral is zircon (Zirconium Silicate) and is primarily used in its oxide or zirconia form. Zirconium dioxide has a high melting point (2,700° C) and a low thermal conductivity. Its polymorphism, however, restricts its widespread use in ceramic industry. During a heating process, zirconia will undergo a phase transformation process. The change in volume associated with this transformation makes the usage of pure zirconia in many applications impossible. Addition of some oxides, such as CaO, MgO, and Y2O3, into the zirconia structure in a certain degree results in a solid solution, which is a cubic form and has no phase transformation during heating and cooling. This solid solution material is termed as stabilized zirconia, a valuable refractory. Stabilized zirconia is used as a grinding media and engineering ceramics due to its increased hardness and high thermal shock resistivity. Stabilized zirconia is also used in applications such as oxygen sensors and solid oxide fuel cells due to its high oxygen ion conductivity.Zirconium was first discovered by William Gregor in 1791. The name Zirconium originated from the Persian word 'zargun' meaning gold color or gold-like. See Zirconium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Mitral Valve Annuloplasty : A Quantitative Clinical and Mechanical Comparison of Different Annuloplasty Devices.
Rausch MK, Bothe W, Kvitting JP, Swanson JC, Miller DC, Kuhl E.
Ann Biomed Eng. 2011 Oct 25. [Epub ahead of print]
PMID:
22037916
[PubMed - as supplied by publisher]
The Tetrahydrometalate Species VH2(H2), NbH4, and TaH4: Matrix Infrared Spectra and Quantum Chemical Calculations.
Wang X, Andrews L.
J Phys Chem A. 2011 Oct 24. [Epub ahead of print]
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Controlled Synthesis of Tantalum Oxynitride and Nitride Nanoparticles.
Gao Q, Giordano C, Antonietti M.
Small. 2011 Oct 19. doi: 10.1002/smll.201101207. [Epub ahead of print]
PMID:
22009942
[PubMed - as supplied by publisher]
Surgical Technique: Porous Tantalum Reconstruction for Destructive Nonprimary Periacetabular Tumors.
Khan FA, Rose PS, Yanagisawa M, Lewallen DG, Sim FH.
Clin Orthop Relat Res. 2011 Oct 12. [Epub ahead of print]
PMID:
21989784
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Carbon Radical Generation by d(0) Tantalum Complexes with ?-Diimine Ligands through Ligand-Centered Redox Processes.
Tsurugi H, Saito T, Tanahashi H, Arnold J, Mashima K.
J Am Chem Soc. 2011 Oct 26. [Epub ahead of print]
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21981364
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Trabecular metal cup without augments for acetabular revision in case of extensive bone loss and low bone-prosthesis contact.
Pierannunzii L, Mambretti A, D'Imporzano M.
Int J Immunopathol Pharmacol. 2011 Jan-Mar;24(1 Suppl 2):133-7.
PMID:
21669152
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Effects of the [OC6F5] moiety upon structural geometry: crystal structures of half-sandwich tantalum(V) aryloxide complexes from reaction of Cp*Ta(N(t)Bu)(CH2R)2 with pentafluorophenol.
Cole JM, Chan MC, Gibson VC, Howard JA.
Acta Crystallogr B. 2011 Oct;67(Pt 5):416-24. Epub 2011 Aug 31.
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21931211
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Surgical Technique: A Cup-in-Cup Technique to Restore Offset in Severe Protrusio Acetabular Defects.
Blumenfeld TJ, Bargar WL.
Clin Orthop Relat Res. 2011 Sep 14. [Epub ahead of print]
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21915769
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Tantalum (oxy)nitrides: Preparation, characterisation and enhancement of photo-Fenton-like degradation of atrazine under visible light.
Du Y, Zhao L, Su Y.
J Hazard Mater. 2011 Nov 15;195:291-7. Epub 2011 Aug 22.
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Prospective Results of Uncemented Tantalum Monoblock Tibia in Total Knee Arthroplasty Minimum 5-Year Follow-up in Patients Younger Than 55 Years.
Kamath AF, Lee GC, Sheth NP, Nelson CL, Garino JP, Israelite CL.
J Arthroplasty. 2011 Aug 25. [Epub ahead of print]
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X-ray absorption, photoemission spectroscopy, and Raman scattering analysis of amorphous tantalum oxide with a large extent of oxygen nonstoichiometry.
Tsuchiya T, Imai H, Miyoshi S, Glans PA, Guo J, Yamaguchi S.
Phys Chem Chem Phys. 2011 Oct 14;13(38):17013-8. Epub 2011 Aug 24.
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Evaluation of gene expression in MG63 human osteoblastlike cells exposed to tantalum powder by microarray technology.
Sollazzo V, Pezzetti F, Massari L, Palmieri A, Brunelli G, Zollino I, Lucchese A, Caruso G, Carinci F.
Int J Periodontics Restorative Dent. 2011 Jul-Aug;31(4):e17-28.
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Hemocompatibility investigation of the NiTi alloy implanted with tantalum.
Zhao T, Li Y, Gao Y, Xiang Y, Chen H, Zhang T.
J Mater Sci Mater Med. 2011 Oct;22(10):2311-8. Epub 2011 Aug 11.
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[Treatment of adult early femur head necrosis with the tantalum screw].
Luo HY, Chen CW.
Zhongguo Gu Shang. 2011 Jun;24(6):482-5. Chinese.
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A comparison of calibration methods for stereo fluoroscopic imaging systems.
Kaptein BL, Shelburne KB, Torry MR, Giphart JE.
J Biomech. 2011 Sep 2;44(13):2511-5. Epub 2011 Jul 23.
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Titanium and tantalum as mesenchymal stem cell scaffolds for spinal fusion: an in vitro comparative study.
Blanco JF, Sánchez-Guijo FM, Carrancio S, Muntion S, García-Briñon J, del Cañizo MC.
Eur Spine J. 2011 Aug;20 Suppl 3:353-60. Epub 2011 Jul 16.
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Synthetic and structural studies of monocyclopentadienyl cyclometalated aryl tantalum(V) compounds.
Galajov M, Galindo A, García C, Gómez M, Gómez-Sal P, Parra A.
Dalton Trans. 2011 Sep 7;40(33):8399-406. Epub 2011 Jul 22.
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21779602
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Designing catalysts for nitrene transfer using early transition metals and redox-active ligands.
Heyduk AF, Zarkesh RA, Nguyen AI.
Inorg Chem. 2011 Oct 17;50(20):9849-63. Epub 2011 Jul 20.
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A randomised study of peri-prosthetic bone density after cemented versus trabecular fixation of a polyethylene acetabular component.
Periasamy K, Watson WS, Mohammed A, Murray H, Walker B, Patil S, Meek RM.
J Bone Joint Surg Br. 2011 Aug;93(8):1033-44.
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Bis(?-2-tert-butyl-phenyl-imido-1:2?N:N)chlorido-2?Cl-(diethyl ether-1?O)(2?-penta-methyl-cyclo-penta-dien-yl)lithiumtantalum(V).
Cole JM, Chan MC, Gibson VC, Howard JA.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m688-9. Epub 2011 May 7.
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Recent Research & Development for Zirconium
Elution behavior of polyethylene and polypropylene standards on carbon sorbents.
Chitta R, Macko T, Brüll R, Kalies G.
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Effect of Cyclic Impact Load on Shear Bond Strength of Zirconium Dioxide Ceramics.
Kawai N, Shinya A, Yokoyama D, Gomi H, Shinya A.
J Adhes Dent. 2010 Sep 28. doi: 10.3290/j.jad.a19471. [Epub ahead of print]PMID: 20978648 [PubMed - as supplied by publisher]Related citations
Differences in metal ion release following cobalt-chromium and oxidized zirconium total knee arthroplasty.
Garrett S, Jacobs N, Yates P, Smith A, Wood D.
Acta Orthop Belg. 2010 Aug;76(4):513-20.PMID: 20973359 [PubMed - indexed for MEDLINE]Related citations
DNA binding studies of new valine derived chiral complexes of tin(IV) and zirconium(IV).
Arjmand F, Jamsheera A.
Spectrochim Acta A Mol Biomol Spectrosc. 2010 Jun 12. [Epub ahead of print]PMID: 20965776 [PubMed - as supplied by publisher]Related citations
Influence of counter-ions on the self-assembly of ZrO(2) nanodisks.
Ji H, Liu X, Wang X, Yao X.
J Colloid Interface Sci. 2011 Jan 15;353(2):356-62. Epub 2010 Oct 16.PMID: 20951993 [PubMed - in process]Related citations
The interaction of osteoblasts with bone-implant materials: 1. the effect of physico-chemical surface properties of implant materials.
Kubies D, Himmlová L, Riedel T, Tresohlavá E, Balík K, Douderová M, Bártová J, Pesáková V.
Physiol Res. 2010 Oct 15. [Epub ahead of print]PMID: 20945966 [PubMed - as supplied by publisher]Free ArticleRelated citations
Fracture resistance of endodontically-treated teeth: effect of combination bleaching and an antioxidant.
Khoroushi M, Feiz A, Khodamoradi R.
Oper Dent. 2010 Sep-Oct;35(5):530-7.PMID: 20945744 [PubMed - indexed for MEDLINE]Related citations
Mechanism of catalytic cyclohydroamination by zirconium salicyloxazoline complexes.
Allan LE, Clarkson GJ, Fox DJ, Gott AL, Scott P.
J Am Chem Soc. 2010 Nov 3;132(43):15308-20.PMID: 20939579 [PubMed - in process]Related citations
Antibacterial properties of nine pure metals: a laboratory study using Staphylococcus aureus and Escherichia coli.
Yasuyuki M, Kunihiro K, Kurissery S, Kanavillil N, Sato Y, Kikuchi Y.
Biofouling. 2010 Oct;26(7):851-8.PMID: 20938849 [PubMed - in process]Related citations
One-Pot Preparation and Uranyl Adsorption Properties of Hierarchically Porous Zirconium Titanium Oxide Beads using Phase Separation Processes to Vary Macropore Morphology.
Drisko GL, Chee Kimling M, Scales N, Ide A, Sizgek E, Caruso RA, Luca V.
Langmuir. 2010 Nov 16;26(22):17581-8. Epub 2010 Oct 11.PMID: 20936801 [PubMed - in process]Related citations
Renewable high-octane gasoline by aqueous-phase hydrodeoxygenation of C5 and C6 carbohydrates over Pt/Zirconium phosphate catalysts.
Li N, Tompsett GA, Huber GW.
ChemSusChem. 2010 Oct 25;3(10):1154-7. No abstract available. PMID: 20936668 [PubMed - in process]Related citations
Can the method of fixation influence the wear behaviour of ZrN coated unicompartmental mobile knee prostheses?
Affatato S, Spinelli M, Lopomo N, Grupp TM, Marcacci M, Toni A.
Clin Biomech (Bristol, Avon). 2010 Oct 7. [Epub ahead of print]PMID: 20934240 [PubMed - as supplied by publisher]Related citations
Measurement of dissolved reactive phosphorus using the diffusive gradients in thin films technique with a high-capacity binding phase.
Ding S, Xu D, Sun Q, Yin H, Zhang C.
Environ Sci Technol. 2010 Nov 1;44(21):8169-74.PMID: 20886846 [PubMed - in process]Related citations
Raman microspectroscopy of organic inclusions in spodumenes from Nilaw (Nuristan, Afghanistan).
Weselucha-Birczynska A, Slowakiewicz M, Natkaniec-Nowak L, Proniewicz LM.
Spectrochim Acta A Mol Biomol Spectrosc. 2010 Sep 28. [Epub ahead of print]PMID: 20884283 [PubMed - as supplied by publisher]Related citations
Effect of thermocycling on the bond strength between dual-cured resin cements and zirconium-oxide ceramics.
D'Amario M, Campidoglio M, Morresi AL, Luciani L, Marchetti E, Baldi M.
J Oral Sci. 2010;52(3):425-30.PMID: 20881336 [PubMed - in process]Free ArticleRelated citations
Surface damages of zirconia by Nd:YAG dental laser irradiation.
Noda M, Okuda Y, Tsuruki J, Minesaki Y, Takenouchi Y, Ban S.
Dent Mater J. 2010 Oct 14;29(5):536-41. Epub 2010 Sep 18.PMID: 20877130 [PubMed - in process]Free ArticleRelated citations
Conjunctive and compromised data fusion schemes for identification of multiple notches in an aluminium plate using Lamb wave signals.
Lu Y, Ye L, Wang D, Wang X, Su Z.
IEEE Trans Ultrason Ferroelectr Freq Control. 2010 Sep;57(9):2005-16.PMID: 20875990 [PubMed - in process]Related citations
A new smile for Judy: a multimaterial approach.
Nash RW.
Dent Today. 2010 Aug;29(8):92, 94. No abstract available. PMID: 20873651 [PubMed - indexed for MEDLINE]Related citations
Matched-pair total knee arthroplasty retrieval analysis: Oxidized zirconium vs. CoCrMo.
Heyse TJ, Chen DX, Kelly N, Boettner F, Wright TM, Haas SB.
Knee. 2010 Sep 22. [Epub ahead of print]PMID: 20869251 [PubMed - as supplied by publisher]Related citations
Surface modification of chromatography adsorbents by low temperature low pressure plasma.
Arpanaei A, Winther-Jensen B, Theodosiou E, Kingshott P, Hobley TJ, Thomas OR.
J Chromatogr A. 2010 Oct 29;1217(44):6905-16. Epub 2010 Sep 23.PMID: 20869062 [PubMed - in process]Related citations
Recent Research & Development for Oxides
Arsenic in
drinking water wells on the Bolivian high plain: Field monitoring and effect of
salinity on removal efficiency of iron-oxides-containing filters. Van Den Bergh K, Du Laing G, Montoya JC, De Deckere E, Tack FM. J Environ Sci
Health A Tox Hazard Subst Environ Eng. 2010 Nov;45(13):1741-9. PubMed PMID:
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Nanoparticles as contrast
agents for in-vivo bioimaging: current status and future perspectives. Hahn MA, Singh AK, Sharma P, Brown SC, Moudgil BM. Anal
Bioanal Chem. 2010 Oct 6. [Epub ahead of print] PubMed PMID: 20924568.
Magnetic and contrast properties of labeled
platelets for magnetomotive optical coherence tomography. Oldenburg AL, Gallippi CM, Tsui F, Nichols TC, Beicker KN, Chhetri RK, Spivak
D, Richardson A, Fischer TH. Biophys J. 2010 Oct
6;99(7):2374-83. PubMed PMID: 20923673.
Nanosheets of Oxides and Hydroxides: Ultimate 2D
Charge-Bearing Functional Crystallites. Ma R, Sasaki T. Adv Mater. 2010 Oct 5. [Epub ahead of
print] PubMed PMID: 20925100.
Determination of Intermediates
and Mechanism for Soot Combustion with NO(x)/O(2) on Potassium-Supported Mg-Al
Hydrotalcite Mixed Oxides by In Situ FTIR. Zhang Z, Zhang Y, Su Q, Wang Z, Li Q, Gao X. Environ Sci Technol. 2010 Oct 5. [Epub
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Blue light induced A2E oxidation in rat eyes - experimental animal model of dry
AMD. Wielgus AR, Collier RJ, Martin E, Lih FB, Tomer KB, Chignell CF, Roberts JE. Photochem Photobiol Sci. 2010 Oct 5. [Epub ahead of print] PubMed PMID:
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Secondary Organic Aerosol from Photooxidation of
Polycyclic Aromatic Hydrocarbons. Shakya KM, Griffin RJ. Environ Sci Technol. 2010 Oct 4. [Epub ahead of
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Study of the integrated growth of dielectric films on GaN
semiconductor substrates. Li Y, Zhu J, Luo W. IEEE Trans Ultrason Ferroelectr Freq Control. 2010
Oct;57(10):2192-7. PubMed PMID: 20889404.
Reduced pressure pain thresholds in
response to exercise in chronic fatigue syndrome but not in chronic low back
pain: an experimental study. Meeus M, Roussel NA, Truijen S, Nijs J. J Rehabil Med. 2010 Oct;42(9):884-90. PubMed PMID:
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Distribution of (210)Pb and (210)Po in
boreal forest soil. Vaaramaa K, Aro L, Solatie D, Lehto J. Sci Total Environ. 2010 Sep 30. [Epub ahead of print] PubMed
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The Effect of a
Strong Stellar Flare on the Atmospheric Chemistry of an Earth-like Planet
Orbiting an M Dwarf. Segura AX, Walkowicz LM, Meadows V, Kasting J, Hawley S. Astrobiology. 2010 Sep 29. [Epub ahead of print] PubMed
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Inorganic Nitrate and Nitrite and Control
of Blood Pressure. Gilchrist M, Shore AC, Benjamin N. Cardiovasc Res. 2010 Sep 29. [Epub ahead of print] PubMed
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Determination of
acid-base dissociation constants of very weak zwitterionic heterocyclic bases by
capillary zone electrophoresis. Ehala S, Grishina AA, Sheshenev AE, Lyapkalo IM, Kasicka V. J Chromatogr A. 2010 Sep 29. [Epub ahead of
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Micropatterned TiO(2) nanotube surfaces for
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The Diesel Exhaust in Miners Study: III. Interrelations
between Respirable Elemental Carbon and Gaseous and Particulate Components of
Diesel Exhaust derived from Area Sampling in Underground Non-metal Mining
Facilities. Vermeulen R, Coble JB, Yereb D, Lubin JH, Blair A, Portengen L, Stewart PA,
Attfield M, Silverman DT. Ann Occup Hyg. 2010 Sep 27. [Epub ahead of print] PubMed PMID:
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Surface oxide net charge of a titanium
alloy: Comparison between effects of treatment with heat or radiofrequency plasma
glow discharge. Macdonald DE, Rapuano BE, Schniepp HC. Colloids Surf B Biointerfaces. 2010 Sep 27. [Epub ahead of print]
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Mitigation of arsenic-mediated renal oxidative stress in rat by Pleurotus florida
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Volatile fraction of lavender and bitter fennel
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Coating of tips for electrochemical scanning tunneling microscopy
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Sep;81(9):093703. PubMed PMID: 20886983.
Manganese and trace-metal
mobility under reducing conditions following in situ oxidation of TCE by KMnO(4):
A laboratory column experiment. Loomer DB, Al TA, Banks VJ, Parker BL, Mayer KU. J Contam Hydrol. 2010 Aug 26. [Epub ahead of
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