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Terbium
Terbium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Terbium is primarily used in phosphors, particularly in fluorescent lamps and as the high intensity green emitter used in projection televisions, such as the yttrium-aluminum-garnet (Tb:YAG) variety. Terbium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Terbium responds efficiently in x-ray excitation and is, therefore, used as an x-ray phosphor. Terbium alloys are also used in magneto-optic recording films, such as Tb-Fe-Co.

Terbium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Terbium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Terbium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f96s2. In its elemental form terbium's CAS number is 7440-27-9. The terbium atom has a radius of 176.3.pm and it's Van der Waals radius is unknown.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Terbium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Terbium was first discovered by Carl Mosander in 1843.

French terbium German Terbium Italian terbio Portuguese Térbio Spanish terbio Swedish Terbium

Terbium Abundance. The following table shows the abundance of Terbium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Tb-159
158.925
100

Terbium Safety Data. The safety data for Terbium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for Terbium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
565.77 kJ mol-1
2nd Ionization Energy
1111.52 kJ mol-1
3rd Ionization Energy
2114.01 kJ mol-1

Conductivity. As to Terbium's electrical and thermal conductivity, the electrical conductivity measured in terms of electrical resistivity @ 20 ºC is 116 µOcm and its electronegativities (or its ability to draw electrons relative to other elements) is non-detectable. The thermal conductivity of Terbium is 11.1 W m-1 K-1.

Thermal Properties of Terbium. The melting point and boiling point for Terbium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
16.3 kJ mol-1
Heat of Vaporization
391 kJ mol-1
Heat of Atomization
390.62 kJ mol-1



 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Tb 65 158.92534 g.mol -1 1.2 8.3 g.cm-3 at 20 °C 1360 °C 3041 °C unknown unknown 563.5 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Terbium

  • The study on the effect and mechanism of the second ligands on the luminescence properties of terbium complexes. Spectrochim Acta A Mol Biomol Spectrosc. 2007 Aug 30; [Epub ahead of print]

  • Paramagnetism-Based NMR Restraints Provide Maximum Allowed Probabilities for the Different Conformations of Partially Independent Protein Domains. J Am Chem Soc. 2007 Oct 2; [Epub ahead of print]

  • Geometric and Electronic Structures of Terbium-Silicon Mixed Clusters (TbSi(n)(); 6
  • Fast determination of salicylic acid in pharmaceuticals by using a terbium-sensitized luminescent SIA optosensor. J Pharm Sci. 2007 Sep 17; [Epub ahead of print]

  • Two-Photon Microscopy and Spectroscopy of Lanthanide Bioprobes. Chemphyschem. 2007 Oct 8;8(14):2125-2132.

  • A mechanistic study of the dynamic quenching of the excited state of europium(III) and terbium(III) macrocyclic complexes by charge- or electron transfer. Org Biomol Chem. 2007 Sep 21;5(18):2975-82. Epub 2007 Aug 7.

  • Terbium luminescence sensitized through three-photon excitation in a self-assembled unlinked antenna. J Phys Chem B. 2007 Sep 20;111(37):10858-61. Epub 2007 Aug 29.

  • Chromatographic determination of flumequine in food samples by post-column derivatisation with terbium(III). Anal Chim Acta. 2006 Sep 25;578(2):220-6. Epub 2006 Jun 30.

  • Synthesis, characterizations and luminescent properties of terbium complexes with methoxy derivatives of 2'-hydroxy-2-phenylacetophenone. Spectrochim Acta A Mol Biomol Spectrosc. 2007 Jun 28; [Epub ahead of print]

  • Synthesis and microstructural characterization of Ce1-xTb(x)O2-delta (0 < or = x < or = 1) nano-powders. J Nanosci Nanotechnol. 2007 Jul;7(7):2521-5.

  • Spectrofluorimetric determination of trace amounts of coenzyme A using a terbium ion-ciprofloxacin complex probe in the presence of periodic acid.
    Anal Bioanal Chem. 2007 Jan 17; [Epub ahead of print]

  • Luminescence dynamics of terbium monodipicolinate in ethyl ammonium nitrate.
    Appl Spectrosc. 2006 Dec;60(12):1453-60.

  • Solvent effect on the luminescent properties of new europium and terbium nitrate complexes with 3,3,7,7-tetra[N-methyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane.
    Spectrochim Acta A Mol Biomol Spectrosc. 2006 Apr 19; [Epub ahead of print]

  • Photoluminescence response of terbium-exchanged MFI-type materials to Si/Al ratio, texture, and hydration state.
    J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2006 Dec 28;110(51):25707-15.

  • Determination of fluoroquinolones in milk samples by postcolumn derivatization liquid chromatography with luminescence detection.
    J Agric Food Chem. 2006 Dec 27;54(26):9670-6.

  • Nonlithographic fabrication of microfluidic devices.
    J Am Chem Soc. 2006 Dec 20;128(50):16062-72.

  • A substrate for deubiquitinating enzymes based on time-resolved fluorescence resonance energy transfer between terbium and yellow fluorescent protein.
    Anal Biochem. 2007 Jan 1;360(1):138-43. Epub 2006 Aug 10.

  • Effect of terbium(III) chloride on the micellization properties of sodium decyl- and dodecyl-sulfate solutions.
    J Colloid Interface Sci. 2007 Feb 1;306(1):166-74. Epub 2006 Oct 27.

  • Improved photoluminescence properties of ternary terbium complexes in mesoporous molecule sieves.
    J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2006 Nov 23;110(46):23164-9.

  • Synthesis of fluorescent analogs of alpha-conotoxin MII.
    Bioconjug Chem. 2006 Nov-Dec;17(6):1612-7.

 

 

 

 

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