Aluminum Acetylacetonate

Al(CH3COCHCOCH3)3

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About

Aluminum Acetylacetonate is an Aluminum source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic compounds). It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures (as demonstrated by a 2013 experiment by researchers at the Leibniz Institute for Solid State and Materials Research Dresden) via the use of chemical vapor deposition (CVD) and laser evaporation techniques. Aluminum Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Aluminum include the coating of telescope mirrors and the construction of modern aircrafts and rockets. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Aluminum 2, 4-pentanedionate; Aluminum tris[(2Z)-4-oxopent-2-en-2-olate]; Tris(acetylacetonato)aluminum(III); Al(acac)3; 3-penten-2-one, 4-hydroxy-, aluminum salt, (3Z)- (3:1); aluminium, tris(pentane-2, 4-dionato); Aluminum(III) acetylacetonate

Chemical Identifiers

Formula Al(CH3COCHCOCH3)3
CAS 13963-57-0
Pubchem CID 16683006
MDL MFCD00000013
EC No. 237-741-6
IUPAC Name (Z)-4-bis[[(Z)-4-oxopent-2-en-2-yl]oxy]alumanyloxypent-3-en-2-one
Beilstein Registry No. 4157942
SMILES [Al+3].O=C(C)\C=C(/[O-])C.[O-]\C(C)=C/C(C)=O.[O-]\C(C)=C/C(C)=O
InchI Identifier InChI=1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
InchI Key KILURZWTCGSYRE-LNTINUHCSA-K

Properties

Compound Formula C15H21AlO6
Molecular Weight 324.31
Appearance White
Melting Point 190-193 °C
Boiling Point 315 °C
Density N/A
Exact Mass 324.115352
Monoisotopic Mass 324.115352

Health & Safety Info  |  MSDS / SDS

Signal Word Danger
Hazard Statements H300-H315-H319-H335
Hazard Codes T
Risk Codes 25-36/37/38
Safety Statements 26-36/37/39-45
RTECS Number BD2230000
Transport Information UN 3467 6.1/PG 2
WGK Germany 3
Globally Harmonized System of Classification and Labelling (GHS) N/A
MSDS / SDS

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

Related Products

AlSee more Aluminum products. Aluminum (or Aluminum) (atomic symbol: Al, atomic number: 13) is a Block P, Group 13, Period 3 element with an atomic weight of 26.9815386. It is the third most abundant element in the earth's crust and the most abundant metallic element. Aluminum Bohr Model Aluminum's name is derived from alumina, the mineral from which Sir Humphrey Davy attempted to refine it from in 1812. It wasn't until 1825 that Aluminum was first isolated by Hans Christian Oersted. Aluminum is a silvery gray metal that possesses many desirable characteristics. It is light, nonmagnetic and non-sparking. It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in many industrial applications where a strong, light, easily constructed material is needed. Elemental AluminumAlthough it has only 60% of the electrical conductivity of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements it imparts a variety of useful properties. Aluminum was first predicted by Antoine Lavoisierin 1787 and first isolated by Friedrich Wöhler in 1827.

Research

Recent Research & Development for Aluminum

  • Condensate Microdrop Self-Propelling Aluminum Surfaces Based on Controllable Fabrication of Alumina Rod -Capped Nanopore Structures. Zhao Y, Luo Y, Li J, Yin F, Zhu J, Gao X. ACS Appl Mater Interfaces. 2015 May 18.
  • Helical growth of aluminum nitride: new insights into its growth habit from nanostructures to single crystals. Zhang XH, Shao RW, Jin L, Wang JY, Zheng K, Zhao CL, Han JC, Chen B, Sekiguchi T, Zhang Z, Zou J, Song B. Sci Rep. 2015 May 15
  • Hardness and wear resistance of carbon nanotube reinforced aluminum-copper matrix composites. Nam DH, Kim JH, Cha SI, Jung SI, Lee JK, Park HM, Park HD, Hong H. J Nanosci Nanotechnol. 2014 Dec
  • Co-Ni alloy nanowires prepared by anodic aluminum oxide template via electrochemical deposition. Kwag YG, Ha JK, Kim HS, Cho HJ, Cho KK. J Nanosci Nanotechnol. 2014 Dec
  • Suspended 2-D photonic crystal aluminum nitride membrane reflector. Ho CP, Pitchappa P, Soon BW, Lee C. Opt Express. 2015 Apr 20
  • A molecular beacon biosensor based on the nanostructured aluminum oxide surface. Che X, He Y, Yin H, Que L. Biosens Bioelectron. 2015 May 9
  • Efficacy and safety of aluminum chloride in controlling external hemorrhage: an animal model study. Nouri S, Sharif MR, Panahi Y, Ghanei M, Jamali B. Iran Red Crescent Med J. 2015 Mar 20
  • Quaternary polymethacrylate-magnesium aluminum silicate films: Water uptake kinetics and film permeability. Rongthong T, Sungthongjeen S, Siepmann F, Siepmann J, Pongjanyakul T. Int J Pharm. 2015 May 21.
  • Coagulation behavior and floc properties of compound bioflocculant-polyaluminum chloride dual-coagulants and polymeric aluminum in low temperature surface water treatment. Huang X, Sun S, Gao B, Yue Q, Wang Y, Li Q. J Environ Sci (China). 2015 Apr 1: J Environ Sci (China)
  • Tannoid principles of Emblica officinalis renovate cognitive deficits and attenuate amyloid pathologies against aluminum chloride induced rat model of Alzheimer's disease. Justin Thenmozhi A, Dhivyabharathi M, William Raja TR, Manivasagam T, Mohamed Essa M. Nutr Neurosci. 2015 Apr 4. : Nutr Neurosci

Recent Research & Development for Acetylacetonates

  • Binary Diffusion Coefficients of Platinum(II) Acetylacetonate in Supercritical Carbon Dioxide. Kong CY, Siratori T, Wang G, Sako T, Funazukuri T. J Chem Eng Data. 2013 Nov 14
  • Growth mechanisms and size control of FePt nanoparticles synthesized using Fe(CO)x (x < 5)-oleylamine and platinum(ii) acetylacetonate. Bian B, Xia W, Du J, Zhang J, Liu JP, Guo Z, Yan A. Nanoscale. 2013 Mar 21
  • Antitumor efficacy and tolerability of systemically administered gallium acetylacetonate-loaded gelucire-stabilized nanoparticles. Wehrung D, Bi L, Geldenhuys WJ, Oyewumi MO. J Biomed Nanotechnol. 2013 Jun
  • High performance polymer solar cells with as-prepared zirconium acetylacetonate film as cathode buffer layer. Tan Z, Li S, Wang F, Qian D, Lin J, Hou J, Li Y. Sci Rep. 2014 Apr 15
  • Vanadyl acetylacetonate upregulates PPARγ and adiponectin expression in differentiated rat adipocytes. Wu Y, Huang M, Zhao P, Yang X. J Biol Inorg Chem. 2013 Aug
  • Effect of magnesium acetylacetonate on the signal of organic forms of vanadium in graphite furnace atomic absorption spectrometry. Kowalewska Z, Welz B, Castilho IN, Carasek E. Talanta. 2013 Jan 15
  • [Differentiated fluorescence centers in europium acetylacetonate hydrate doped poly methyl methacrylate]. Zhang YY, Zhong H, Chen BJ, Xia Y, Lin H. Guang Pu Xue Yu Guang Pu Fen Xi. 2014 Jun
  • Photophysical properties of an unusual bichromophoric species constructed from a cyclometalated Pt(II) chromophore and a blue Bodipy-acetylacetonate species. Nastasi F, Puntoriero F, Serroni S, Campagna S, Olivier JH, Ziessel R. Dalton Trans. 2014 Dec 21
  • Binary Diffusion Coefficients of Platinum(II) Acetylacetonate in Supercritical Carbon Dioxide. Kong CY, Siratori T, Wang G, Sako T, Funazukuri T. J Chem Eng Data. 2013 Nov 14
  • Growth mechanisms and size control of FePt nanoparticles synthesized using Fe(CO)x (x < 5)-oleylamine and platinum(ii) acetylacetonate. Bian B, Xia W, Du J, Zhang J, Liu JP, Guo Z, Yan A. Nanoscale. 2013 Mar 21

Free Test Sample Program

We recognize many of our customers are purchasing small quantities directly online as trial samples in anticipation of placing a larger future order or multiple orders as a raw material for production. Since our primary business is the production of industrial quantities and/or highly consistent batches which can be used for commercial production and purchased repeatedly in smaller quantity, American Elements offers trial samples at no charge on the following basis. Within 6 months of purchasing materials directly online from us, you have the option to refer back to that order and advise that it is the intention of your company, institution or lab to either purchase a larger quantity, purchase the material in regular intervals or purchase more on some other basis.

We will then evaluate your future needs and assuming the quantity or number of future purchases qualify, we will fully credit your purchase price with the next order. Because of the many variables in the quantity and number of orders you may place, it is impossible to evaluate whether your future order(s) will qualify for this program prior to your placing your next order. Please know American Elements strongly desires to make this free sample program available to you and will make every effort to do so once your next order is placed.