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Bismuth Nitrate Oxide

CAS #:

Linear Formula:

Bi(O)NO3

MDL Number:

MFCD00064844

EC No.:

233-792-3

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Bismuth(III) Nitrate Oxide
BA-NATOX-02-C
Pricing > SDS > Data Sheet >
(3N) 99.9% Bismuth(III) Nitrate Oxide
BA-NATOX-03-C
Pricing > SDS > Data Sheet >
(4N) 99.99% Bismuth(III) Nitrate Oxide
BA-NATOX-04-C
Pricing > SDS > Data Sheet >
(5N) 99.999% Bismuth(III) Nitrate Oxide
BA-NATOX-05-C
Pricing > SDS > Data Sheet >

Bismuth Nitrate Oxide Properties (Theoretical)

Compound Formula BiNO4
Molecular Weight 286.98
Appearance Beige to white powder
Melting Point 500 °C
Boiling Point N/A
Density 4.93 g/cm3
Solubility in H2O Insoluble
Exact Mass 286.963131
Monoisotopic Mass 286.963131

Bismuth Nitrate Oxide Health & Safety Information

Signal Word Danger
Hazard Statements H272-H315-H319-H335
Hazard Codes O, Xi
Precautionary Statements P221-P210-P220-P305+P351+P338-P405-P501
Risk Codes 8-36/37/38
Safety Statements 17-26-36/37/39
RTECS Number N/A
Harmonized Tariff Code 2834.29
Transport Information UN 1477 5.1 / PGII
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 12/13/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Bismuth Nitrate Oxide

Product Number: All applicable American Elements product codes, e.g. BA-NATOX-02-C 02 , BA-NATOX-03-C 03 , BA-NATOX-04-C 04 , BA-NATOX-05-C 05

CAS #: 10361-46-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS) GHS03 Flame over circle Ox. Sol. 2 H272 May intensify fire; oxidizer. GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. STOT SE 3 H335 May cause respiratory irritation. Hazards not otherwise classified No information known. Label elements GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS) Hazard pictograms
Flame Over Circle - GHS03 Exclamation Mark - GHS07
GHS03 GHS07 Signal word Danger Hazard statements H272 May intensify fire; oxidizer. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary statements P221 Take any precaution to avoid mixing with combustibles. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P220 Keep/Store away from clothing/combustible materials. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. WHMIS classification C - Oxidizing materials D2B - Toxic material causing other toxic effects Classification system HMIS ratings (scale 0-4) (Hazardous Materials Identification System) Health (acute effects) = 2 Flammability = 0 Physical Hazard = 1 Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances CAS# Description: 10361-46-3 Bismuth nitrate oxide Identification number(s): EC number: 233-792-3

SECTION 4. FIRST AID MEASURES

Description of first aid measures After inhalation Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice. After skin contact Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice. After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing Seek medical treatment. Information for doctor Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available.

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media Suitable extinguishing agents CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents Halocarbon extinguisher Special hazards arising from the substance or mixture This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. If this product is involved in a fire, the following can be released: Nitrogen oxides (NOx) Metal oxide fume Advice for firefighters Protective equipment: Wear self-contained respirator. Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Environmental precautions: Do not allow material to be released to the environment without proper governmental permits. Methods and material for containment and cleaning up: Ensure adequate ventilation. Prevention of secondary hazards: Acts as an oxidizing agent on organic materials such as wood, paper and fats Keep away from combustible material. Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling Precautions for safe handling Keep container tightly sealed. Store in cool, dry place in tightly closed containers. Ensure good ventilation at the workplace. Information about protection against explosions and fires: Substance/product can reduce the ignition temperature of flammable substances. This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Store away from flammable substances. Store away from reducing agents. Do not store with organic materials. Store away from metal powders. Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Specific end use(s) No further relevant information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems: Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute. Control parameters Components with limit values that require monitoring at the workplace: Not required. Additional information: No data Exposure controls Personal protective equipment General protective and hygienic measures The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Remove all soiled and contaminated clothing immediately. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Maintain an ergonomically appropriate working environment. Breathing equipment: Use suitable respirator when high concentrations are present. Protection of hands: Impervious gloves Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Eye protection: Safety glasses Body protection: Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties General Information Appearance: Form: Powder Color: White Odor: Not determined Odor threshold: Not determined. pH-value: Not applicable. Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined Sublimation temperature / start: Not determined Flash point: Not applicable Flammability (solid, gaseous) Contact with combustible material may cause fire. Ignition temperature: Not determined Decomposition temperature: Not determined Auto igniting: Not determined. Danger of explosion: Not determined. Explosion limits: Lower: Not determined Upper: Not determined Vapor pressure: Not applicable. Density at 20 °C (68 °F): 4.93 g/cm³ (41.141 lbs/gal) Relative density Not determined. Vapor density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with Water: Not determined Partition coefficient (n-octanol/water): Not determined. Viscosity: dynamic: Not applicable. kinematic: Not applicable. Other information No further relevant information available.

SECTION 10. STABILITY AND REACTIVITY

Reactivity May intensify fire; oxidizer. Chemical stability Stable under recommended storage conditions. Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications. Possibility of hazardous reactions Reacts with reducing agents Reacts with flammable substances Conditions to avoid No further relevant information available. Incompatible materials: Reducing agents Flammable substances Organic materials Metal powders Hazardous decomposition products: Nitrogen oxides Metal oxide fume

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects Acute toxicity: No effects known. LD/LC50 values that are relevant for classification: No data Skin irritation or corrosion: Causes skin irritation. Eye irritation or corrosion: Causes serious eye irritation. Sensitization: No sensitizing effects known. Germ cell mutagenicity: No effects known. Carcinogenicity: No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH. Reproductive toxicity: No effects known. Specific target organ system toxicity - repeated exposure: No effects known. Specific target organ system toxicity - single exposure: May cause respiratory irritation. Aspiration hazard: No effects known. Subacute to chronic toxicity: Bismuth and bismuth compounds are often poorly absorbed. Should absorption occur, however, exposure may cause loss of appetite, headache, skin rash, exodermatitis, kidney injury and jaundice. Repeated or prolonged exposure may cause a bismuth line or black spots on the gums, foul breath and salivation. Small doses of nitrates may cause weakness, general depression, headache and mental impairment. Larger doses may cause dizziness, abdominal cramps, vomiting, bloody diarrhea, convulsions and collapse. Subacute to chronic toxicity: No effects known. Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Do not allow material to be released to the environment without proper governmental permits. Do not allow undiluted product or large quantities to reach ground water, water course or sewage system. Avoid transfer into the environment. Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. Other adverse effects No further relevant information available.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods Recommendation Consult state, local or national regulations to ensure proper disposal. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number DOT, IMDG, IATA UN1477 UN proper shipping name DOT Nitrates, inorganic, n.o.s. (Bismuth nitrate oxide) IMDG, IATA NITRATES, INORGANIC, N.O.S. (Bismuth nitrate oxide) Transport hazard class(es) DOT Class 5.1 Oxidising substances. Label 5.1 Class 5.1 (O2) Oxidizing substances Label 5.1 IMDG, IATA Class 5.1 Oxidising substances. Label 5.1 Packing group DOT, IMDG, IATA II Environmental hazards: Not applicable. Special precautions for user Warning: Oxidizing substances Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Marine Pollutant (DOT): No UN "Model Regulation": UN1477, Nitrates, inorganic, n.o.s. (Bismuth nitrate oxide), 5.1, II

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS) Hazard pictograms GHS03 GHS07 Signal word Danger Hazard statements H272 May intensify fire; oxidizer. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary statements P221 Take any precaution to avoid mixing with combustibles. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P220 Keep/Store away from clothing/combustible materials. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. National regulations All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory. All components of this product are listed on the Canadian Domestic Substances List (DSL). SARA Section 313 (specific toxic chemical listings) Substance is not listed. California Proposition 65 Prop 65 - Chemicals known to cause cancer Substance is not listed. Prop 65 - Developmental toxicity Substance is not listed. Prop 65 - Developmental toxicity, female Substance is not listed. Prop 65 - Developmental toxicity, male Substance is not listed. Information about limitation of use: For use only by technically qualified individuals. Other regulations, limitations and prohibitive regulations Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed. The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed. Substance is not listed. Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed. Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Bismuth Nitrate Oxide

Bismuth Nitrate Oxide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Bismuth Nitrate Oxide Synonyms

Bismuth oxynitrate, Bismuth(III) nitrate basic, Bismuthyl nitrate, Bismuth(III) subnitrate, (Nitrooxy)oxobismuthine, Bismuth(III) Nitrate Oxide, Bismuthine, (nitrooxy)oxo-

Chemical Identifiers

Linear Formula Bi(O)NO3
MDL Number MFCD00064844
EC No. 233-792-3
Beilstein Registry No. N/A
Pubchem CID 16684898
IUPAC Name oxobismuthanyl nitrate
SMILES [N+](=O)([O-]) O[Bi]=O
InchI Identifier InChI=1S/Bi.NO3.O/c;2-1(3)4;/q+1;-1;
InchI Key OGCYGKRWXWQOAK-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Bismuth products. Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental BismuthBismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass.

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

Recent Research

TODAY'S SCIENCE POST!

December 13, 2019
Los Angeles, CA
Each business day American Elements' scientists & engineers post their choice for the most exciting materials science news of the day

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