20th anniversary seal20th anniversary seal20th anniversary seal

Gallium Nitrate Solution

CAS #:

Linear Formula:

Ga(NO3)3

MDL Number:

MFCD00011016

EC No.:

236-815-5

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Gallium Nitrate Solution
GA-NAT-02-SOL
Pricing > SDS > Data Sheet >
(3N) 99.9% Gallium Nitrate Solution
GA-NAT-03-SOL
Pricing > SDS > Data Sheet >
(4N) 99.99% Gallium Nitrate Solution
GA-NAT-04-SOL
Pricing > SDS > Data Sheet >
(5N) 99.999% Gallium Nitrate Solution
GA-NAT-05-SOL
Pricing > SDS > Data Sheet >

Gallium Nitrate Solution Properties (Theoretical)

Compound Formula GaN3O9
Molecular Weight 255.74
Appearance White to clear liquid
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass 254.889027
Monoisotopic Mass 254.889027

Gallium Nitrate Solution Health & Safety Information

Signal Word Danger
Hazard Statements H272-H315-H319-H335
Hazard Codes C, O
Risk Codes Aug-35
Safety Statements 23-26-36-45
RTECS Number N/A
Transport Information UN3218 5.1/PG 2
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 10/20/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Gallium Nitrate Solution

Product Number: All applicable American Elements product codes, e.g. GA-NAT-02-SOL 02 , GA-NAT-03-SOL 03 , GA-NAT-04-SOL 04 , GA-NAT-05-SOL 05

CAS #: 13494-90-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Physical hazards
Category 1A
Skin corrosion/irritation
Health hazards
Category 1
Serious eye damage/eye irritation
Category 2
Specific target organ toxicity, repeated exposure
Not classified.
Environmental hazards
Not classified.
OSHA defined hazards
Label elements

Corrosion - GHS05 Health Hazard - GHS08

Signal word
Danger
Hazard statement
Causes severe skin burns and eye damage. Causes serious eye damage. May cause damage to
organs through prolonged or repeated exposure.
Precautionary statement
Prevention
Do not breathe mist or vapor. Wear protective gloves/protective clothing/eye protection/face
protection.
Response
If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/physician. Wash contaminated clothing before reuse.
Storage
Store locked up.
Disposal
Not available.
Hazard(s) not otherwise classified (HNOC)
None known.
Supplemental information
None.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

CAS No. / Substance Name:
Gallium (III) nitrate solution
13494-90-1


SECTION 4. FIRST AID MEASURES

Inhalation
Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact
Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician. Wash
contaminated clothing before reuse.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Ingestion
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important
symptoms/effects, acute and delayed
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
blindness could result. Prolonged exposure may cause chronic effects.
Indication of immediate medical attention and special treatment needed
Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
General information
If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves.


SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from the chemical
During fire, gases hazardous to health may be formed.
Special protective equipment and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire fighting equipment/instructions
Move containers from fire area if you can do so without risk.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards
No unusual fire or explosion hazards noted.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe
mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant
spillages cannot be contained. For personal protection, see section 8 of the SDS.
Methods and materials for containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions
Avoid discharge into drains, water courses or onto the ground.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid prolonged
exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe
good industrial hygiene practices.
Conditions for safe storage, including any incompatibilities
Store locked up. Store in original tightly closed container. Store away from incompatible materials
(see Section 10 of the SDS).


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Wear appropriate chemical resistant gloves.
Other
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations
Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state
Liquid.
Form
Liquid.
Color
Colorless.
Odor
Odorless.
Odor threshold
Not available.
pH
Not available.
Melting point/freezing point
32 °F (0 °C) estimated
Initial boiling point and
boiling range
212 °F (100 °C) estimated
Flash point
Not available.
Evaporation rate
Not available.
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Not available.
Flammability limit - upper (%)
Not available.
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
Not available.
Vapor density
Not available.
Relative density
Not available.
Solubility(ies)
Solubility (water)
Miscible.
Partition coefficient (n-octanol/water)
Not available.
Auto-ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
Not available.
Other information
Density
1.02 g/cm3 estimated
Percent volatile
< 95 %
Specific gravity
1.02 estimated


SECTION 10. STABILITY AND REACTIVITY

Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous reactions
Hazardous polymerization does not occur.
Conditions to avoid
Contact with incompatible materials.
Incompatible materials
Strong oxidizing agents.
Hazardous decomposition
products
No hazardous decomposition products are known.


SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure
Inhalation
May cause damage to organs through prolonged or repeated exposure by inhalation. May cause
irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact
Causes severe skin burns.
Eye contact
Causes serious eye damage.
Ingestion
Causes digestive tract burns.
Symptoms related to the physical, chemical and toxicological characteristics
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
blindness could result.
Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitization
Respiratory sensitization
Not available.
Skin sensitization
This product is not expected to cause skin sensitization.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not available.
US. National Toxicology Program (NTP) Report on Carcinogens
Not available.
Reproductive toxicity
This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity- single exposure
Not classified.
Specific target organ toxicity- repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
Not available.
Chronic effects
Prolonged inhalation may be harmful. May cause damage to organs through prolonged or repeated exposure.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability:
No data is available on the degradability of this product.
Bioaccumulative potential:
No data available.
Mobility in soil:
No data available.
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.


SECTION 13. DISPOSAL CONSIDERATIONS

Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused products
Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.


SECTION 14. TRANSPORT INFORMATION

DOT
UN3264
Corrosive liquid, acidic, inorganic, n.o.s. (Gallium nitrate)
UN proper shipping name
8
Transport hazard class(es)
Subsidiary risk
8
Label(s)
III
Packing group
Read safety instructions, SDS and emergency procedures before handling.
Special precautions for user
IB3, T7, TP1, TP28
Special provisions
154
Packaging exceptions
203
Packaging non bulk
241
Packaging bulk
IATA
UN3264
Corrosive liquid, acidic, inorganic, n.o.s. (Gallium nitrate)
UN proper shipping name
8
Class
Transport hazard class(es)
Subsidiary risk
III
Packing group
No.
Environmental hazards
8L
ERG Code
Read safety instructions, SDS and emergency procedures before handling.
Special precautions for user
Allowed.
Passenger and cargo aircraft
Other information
Allowed.
Cargo aircraft only
IMDG
UN3264
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Gallium nitrate)
UN proper shipping name
8
Class
Transport hazard class(es)
Subsidiary risk
III
Packing group
No.
Marine pollutant
Environmental hazards
F-A, S-B


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
SARA Section 313 (specific toxic chemical listings)
Gallium (III) nitrate solution
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Gallium Nitrate Solution

Gallium Nitrate Solutions are moderate to highly concentrated liquid solutions of Gallium Nitrate. They are an excellent source of Gallium Nitrate for applications requiring solubilized materials. American Elements can prepare dissolved homogeneous solutions at customer specified concentrations or to the maximum stoichiometric concentration. Packaging is available in 55 gallon drums, smaller units and larger liquid totes. American Elements maintains solution production facilities in the United States, Northern Europe (Liverpool, UK), Southern Europe (Milan, Italy), Australia and China to allow for lower freight costs and quicker delivery to our customers. American Elements metal and rare earth compound solutions have numerous applications, but are commonly used in petrochemical cracking and automotive catalysts, water treatment, plating, textiles, research and in optic, laser, crystal and glass applications. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Gallium Nitrate Powder. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Gallium Nitrate Solution Synonyms

Gallium nitrate, Gallium trinitrate hydrate, Gallium(III) nitrate, Gallium(3+) nitrate, hydrated gallium nitrate, Ganite, gallium nitrate nonahydrate, gallium nitrate octahydrate, gallium(+3) cation trinitrate, aqueous gallium nitrate, Gallium(III) nitrate solution

Chemical Identifiers

Linear Formula Ga(NO3)3
MDL Number MFCD00011016
EC No. 236-815-5
Beilstein Registry No. N/A
Pubchem CID 61635
IUPAC Name gallium; trinitrate
SMILES [Ga+3].O=[N+]([O-]) [O-].[O-][N+]([O-])= O.[O-][N+]([O-])=O
InchI Identifier InChI=1S/Ga.3NO3/c ;3*2-1(3)4/q+3;3*-1
InchI Key CHPZKNULDCNCBW-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Gallium products. Gallium (atomic symbol: Ga, atomic number: 31) is a Block P, Group 13, Period 4 element with an atomic weight of 69.723.The number of electrons in each of Gallium's shells is 2, 8, 18, 3 and its electron configuration is [Ar] 3d10 4s2 4p1. The gallium atom has a radius of 122.1 pm and a Van der Waals radius of 187 pm. Gallium Bohr ModelGallium was predicted by Dmitri Mendeleev in 1871. It was first discovered and isolated by Lecoq de Boisbaudran in 1875. In its elemental form, gallium has a silvery appearance. Elemental GalliumGallium is one of three elements that occur naturally as a liquid at room temperature, the other two being mercury and cesium. Gallium does not exist as a free element in nature and is sourced commercially from bauxite and sphalerite. Currently, gallium is used in semiconductor devices for microelectronics and optics. The element name originates from the Latin word 'Gallia', the old name of France, and the word 'Gallus,' meaning rooster.

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

TODAY'S SCIENCE POST!

October 20, 2019
Los Angeles, CA
Each business day American Elements' scientists & engineers post their choice for the most exciting materials science news of the day

Scientists discover unique stretchable conductor - Polymerized Liquid Metal Networks