Monodispersed gold nanoparticles supported on a zirconium-based porous metal-organic framework and their high catalytic ability for the reverse water-gas shift reaction.

Title Monodispersed gold nanoparticles supported on a zirconium-based porous metal-organic framework and their high catalytic ability for the reverse water-gas shift reaction.
Authors H. Xu; Y. Li; X. Luo; Z. Xu; J. Ge
Journal Chem Commun (Camb)
DOI 10.1039/c7cc02130e
Abstract

A highly active and selective Au@UIO-67 catalyst has been assembled. Gold nanoparticles (AuNPs) are monodispersed on the UIO-67 surface of a porous metal-organic framework, the micropores in UIO-67 as templates for adsorbing Au ions and enhancing interaction between AuNPs and UIO-67, favoring the formation of isolated and well-dispersed AuNPs. The catalyst exhibits high catalytic activity and CO selectivity for the reverse water-gas shift reaction in a fixed-bed flow reactor.

Citation H. Xu; Y. Li; X. Luo; Z. Xu; J. Ge.Monodispersed gold nanoparticles supported on a zirconium-based porous metal-organic framework and their high catalytic ability for the reverse water-gas shift reaction.. Chem Commun (Camb). 2017. doi:10.1039/c7cc02130e

Related Elements

Zirconium

See more Zirconium products. Zirconium (atomic symbol: Zr, atomic number: 40) is a Block D, Group 4, Period 5 element with an atomic weight of 91.224. Zirconium Bohr ModelThe number of electrons in each of Zirconium's shells is 2, 8, 18, 10, 2 and its electron configuration is [Kr]4d2 5s2. The zirconium atom has a radius of 160 pm and a Van der Waals radius of 186 pm. Zirconium was discovered by Martin Heinrich Klaproth in 1789 and first isolated by Jöns Jakob Berzelius in 1824. In its elemental form, zirconium has a silvery white appearance that is similar to titanium. Zirconium's principal mineral is zircon (zirconium silicate). Elemental ZirconiumZirconium is commercially produced as a byproduct of titanium and tin mining and has many applications as a opacifier and a refractory material. It is not found in nature as a free element. The name of zirconium comes from the mineral zircon, the most important source of zirconium, and from the Persian wordzargun, meaning gold-like.

Gold

See more Gold products. Gold (atomic symbol: Au, atomic number: 79) is a Block D, Group 11, Period 6 element with an atomic weight of 196.966569. The number of electrons in each of Gold's shells is 2, 8, 18, 32, 18, 1 and its electron configuration is [Xe]4f142 5d10 6s1. Gold Bohr ModelThe gold atom has a radius of 144 pm and a Van der Waals radius of 217 pm. Gold was first discovered by Early Man prior to 6000 B.C. In its elemental form, gold has a metallic yellow appearance. Gold is a soft metal and is usually alloyed to give it more strength.Elemental Gold It is a good conductor of heat and electricity, and is unaffected by air and most reagents. It is one of the least reactive chemical elements. Gold is often found as a free element and with silver as a gold-silver alloy. Less commonly, it is found in minerals as gold compounds, usually with tellurium.

Related Forms & Applications