Ti3AlN MAX Phase Powder

Linear Formula:

Ti3AlN

MDL Number:

N/A

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Titanium Aluminum Nitride Ti3AlN
TI-ALN-02-P
Pricing > SDS > Data Sheet >
(3N) 99.9% Titanium Aluminum Nitride Ti3AlN
TI-ALN-03-P
Pricing > SDS > Data Sheet >
(4N) 99.99% Titanium Aluminum Nitride Ti3AlN
TI-ALN-04-P
Pricing > SDS > Data Sheet >
(5N) 99.999% Titanium Aluminum Nitride Ti3AlN
TI-ALN-05-P
Pricing > SDS > Data Sheet >

Titanium Aluminum Nitride Ti3AlN Properties (Theoretical)

Compound Formula Ti3AlN
Molecular Weight 184.59
Appearance Dark gray to black powder
Melting Point N/A
Boiling Point N/A
Density 4.35 g/cm3
Solubility in H2O N/A
Crystal Phase / Structure Cubic - perovskite

Titanium Aluminum Nitride Ti3AlN Health & Safety Information

Signal Word Danger
Hazard Statements H251
Hazard Codes F
Precautionary Statements P235+P410-P280-P407-P420
Risk Codes R17
Safety Statements N/A
Harmonized Tariff Code 8108.20
Transport Information UN 2546 4.2/PG II
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Created: 5/15/2015
Date Revised: 5/15/2015

SECTION 1. IDENTIFICATION

Product Name: Titanium Aluminum Nitride Ti3AlN

Product Number: All applicable American Elements product codes, e.g. TI-ALN-02-P, TI-ALN-03-P, TI-ALN-04-P, TI-ALN-05-P

Relevant identified uses of the substance: Scientific research and development


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 Flame
Self-heat. 1 H251 Self-heating: may catch fire.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
F; Highly flammable
R17: Spontaneously flammable in air.
Information concerning particular hazards for human and environment:
Not applicable
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms

Flame - GHS02

GHS02
Signal word
Danger
Hazard statements
H251 Self-heating: may catch fire.
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P235+P410 Keep cool. Protect from sunlight.
P420 Store away from other materials.
P407 Maintain air gap between stacks/pallets.
WHMIS classification
B6 - Reactive flammable material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 1
Flammability = 3
Physical Hazard = 2
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
7440-32-6 Titanium
24304-00-5 Aluminium Nitride


SECTION 4. FIRST AID MEASURES

Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing agents
Carbon dioxide
Water
Special hazards arising from the substance or mixture
Spontaneously flammable in air.
If this product is involved in a fire, the following can be released:
Titanium oxides
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow product to reach sewage system or any water course.
Do not allow to penetrate the ground/soil.
Methods and material for containment and cleaning up:
Keep away from ignition sources.
Ensure adequate ventilation.
Prevention of secondary hazards:
Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Substance/product is self ignitable.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from air.
Store away from oxidizing agents.
Store away from mineral acids
Store away from halogens.
Store away from halocarbons.
Further information about storage conditions:
Store under dry inert gas.
This product is air sensitive.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood desi
gned for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type N95 (USA) or PE (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes)
480
Glove thickness
0.11 mm
Eye protection:
Safety glasses
Full face protection
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder
Color: Not determined.
Odor: Not determined.
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: Not determined.
Boiling point/Boiling range: Not determined.
Sublimation temperature / start: Not determined
Flammability (solid, gaseous)
Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density at 20 °C (68 °F): Not determined.
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Not determined.
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity
Catches fire spontaneously if exposed to air.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Spontaneously flammable in air.
Reacts with strong oxidizing agents
Conditions to avoid
No further relevant information available.
Incompatible materials:
Air
Oxidizing agents
Halogens
Halocarbons
Mineral acids
Hazardous decomposition products:
Titanium oxides


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
No effects known.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or carcinogenic and/or neoplastic data for this substance.
Reproductive toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this substance.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN2546
UN proper shipping name
DOT
Titanium powder, dry
IMDG, IATA
TITANIUM POWDER, DRY
Transport hazard class(es)
DOT
Class
4.2 Substances liable to spontaneous combustion.
Label
4.2
Class
4.2 (S4) Substances liable to spontaneous combustion
Label
4.2
IMDG, IATA
Class
4.2 Substances liable to spontaneous combustion.
Label
4.2
Packing group
DOT, IMDG, IATA
II
Environmental hazards:
Not applicable.
Special precautions for user
Warning: Substances liable to spontaneous combustion
EMS Number: F-G,S-M
Segregation groups
Heavy metals and their salts (including their organometallic compounds), powdered metals
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN2546, Titanium powder, dry, 4.2, II


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
REACH - Pre-registered substances
Substance is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Titanium Aluminum Nitride Ti3AlN

Titanium Aluminum Nitride Ti3AlN is a ternary layered MAX phase compound of the general type Mn+1AXn, where M is a transition metal, A is an element such as aluminum or silicon, and X is either carbon or nitrogen, with n=1, 2, or 3. MAX phase compunds are precursors for the production of MXenes, novel 2D materials notable for their properties that combine aspects of both metals and ceramics. MXene from the bulk three dimensional MAX phase compound involves exfoliation or etching to selectively remove the A layer, resulting in layers which can be separated by other ions (known as intercalation) which enhances their properties. American Elements manufactures a comprehensive catalog of ultra high purity (>e;99.999%) MAX phase and MXene materials. Please request a quote above to receive pricing information based on your specifications.

Titanium Aluminum Nitride Ti3AlN Synonyms

Ti3AlN MAXene Phase

Chemical Identifiers

Linear Formula Ti3AlN
MDL Number N/A
EC No. N/A
Pubchem CID N/A

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Titanium

See more Titanium products. Titanium (atomic symbol: Ti, atomic number: 22) is a Block D, Group 4, Period 4 element with an atomic weight of 47.867. The number of electrons in each of Titanium's shells is [2, 8, 10, 2] and its electron configuration is [Ar] 3d2 4s2. Titanium Bohr ModelThe titanium atom has a radius of 147 pm and a Van der Waals radius of 187 pm. Titanium was discovered by William Gregor in 1791 and first isolated by Jöns Jakob Berzelius in 1825. In its elemental form, titanium has a silvery grey-white metallic appearance. Titanium's properties are chemically and physically similar to zirconium, both of which have the same number of valence electrons and are in the same group in the periodic table. Elemental TitaniumTitanium has five naturally occurring isotopes: 46Ti through 50Ti, with 48Ti being the most abundant (73.8%). Titanium is found in igneous rocks and the sediments derived from them. It is named after the word Titanos, which is Greek for Titans.

Aluminum

See more Aluminum products. Aluminum (or Aluminium) (atomic symbol: Al, atomic number: 13) is a Block P, Group 13, Period 3 element with an atomic weight of 26.9815386. It is the third most abundant element in the earth's crust and the most abundant metallic element. Aluminum Bohr Model Aluminum's name is derived from alumina, the mineral from which Sir Humphrey Davy attempted to refine it from in 1812. Aluminum was first predicted by Antoine Lavoisier 1787 and first isolated by Hans Christian Øersted in 1825. Aluminum is a silvery gray metal that possesses many desirable characteristics. It is light, nonmagnetic and non-sparking. It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in many industrial applications where a strong, light, easily constructed material is needed. Elemental AluminumAlthough it has only 60% of the electrical conductivity of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements, it imparts a variety of useful properties.

Nitrogen

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

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