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Lanthanum
Lanthanum information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Lanthanum is the first element in the rare earth or lanthanide series. It is the model for all the other trivalent rare earths. After cerium, it is the second most abundant of the rare earths. Lanthanum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Lanthanum-rich lanthanide compositions have been used extensively for cracking reactions in FCC catalysts, especially to manufacture low-octane fuel for heavy crude oil. It is utilized in green phosphors based on the aluminate (La0.4Ce0.45Tb0.15)PO4. Lanthanide zirconates and lanthanum strontium manganites are used for their catalytic and conductivity properties and lanthanum stabilized zirconia has useful electrical and mechanical properties. Lanthanum's ability to bind with phosphates in water creates numerous uses in water treatment. It is utilized in laser crystals based on the yttrium-lanthanum-fluoride (YLF) composition.

Lanthanum facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Lanthanum is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Lanthanum is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe] 5d1 6s2. In its elemental form lanthanum 's CAS number is 7439-91-0. The lanthanum atom has a radius of 187.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Lanthanum compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Lanthanum was first discovered by Carl Mosander in 1839.

French lanthane German Lanthan Italian lantanio Portuguese Lantânio Spanish lantano Swedish Lantan

Abundance. The following table shows the abundance of lanthanum and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
La-138
137.907107
0.09
La-139
138.906348
99.91

Safety Data. The safety data for lanthanum metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for lanthanum (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
538.10 kJ mol-1
2nd Ionization Energy
1067.14 kJ mol-1
3rd Ionization Energy
1850.34 kJ mol-1

Conductivity. As to lanthanum 's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 57 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.1. The thermal conductivity of lanthanum is 13.5 W m-1 K-1.

Thermal Properties. The melting point and boiling point for lanthanum are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
10.04 kJ mol-1
Heat of Vaporization
402.1 kJ mol-1
Heat of Atomization
431.29 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
La 57 138.91 g.mol -1 1.1 6.18 g.cm-3 at 20 °C 826 °C Unknown °C 200.pm 0.104 nm (+3) 538.10 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Lanthanum

  • Development of heterogeneous base catalysts for biodiesel production. Bioresour Technol. 2008 Jun;99(9):3439-43. Epub 2007 Sep 19.

  • Removal of lanthanum and gadolinium from nitrate medium using Aliquat-336 impregnated onto Amberlite XAD-4. J Hazard Mater. 2008 May 30;153(3):948-54. Epub 2007 Sep 16.

  • Formation of molecular glasses and the aggregation in solutions for lanthanum(iii), calcium(ii), and yttrium(iii) complexes of octanoyl-dl-alaninate. Dalton Trans. 2008 Apr 7;(13):1698-709. Epub 2008 Feb 14.

  • Resistance against novel anticancer metal compounds: Differences and similarities. Drug Resist Updat. 2008 Apr 2; [Epub ahead of print]

  • Biokinetics of Cadmium and Zinc in a Marine Bacterium: Influences of Metal Interaction and Pre-Exposure. Environ Toxicol Chem. 2008 Apr 2;:1 [Epub ahead of print]

  • Ca(2+)/calmodulin-dependent invasion of microvascular endothelial cells of human brain by Escherichia coli K1. Cell Tissue Res. 2008 Apr 1; [Epub ahead of print]

  • Structural and functional characterization and physiological significance of a stimulator protein of Mg(2+)-independent Ca (2+)-ATPase isolated from goat spermatozoa. Mol Cell Biochem. 2008 Apr;311(1-2):93-103. Epub 2007 Dec 30.

  • Effect of Focused Ultrasound Applied With an Ultrasound Contrast Agent on the Tight Junctional Integrity of the Brain Microvascular Endothelium. Ultrasound Med Biol. 2008 Mar 29; [Epub ahead of print]

  • Hydration of Lanthanoid(III) Ions in Aqueous Solution and Crystalline Hydrates Studied by EXAFS Spectroscopy and Crystallography: The Myth of the "Gadolinium Break" Chemistry. 2008 Mar 27;14(10):3056-3066.

  • Characterization of root mucilage from Melastoma malabathricum, with emphasis on its roles in aluminum accumulation. New Phytol. 2008 Mar 26; [Epub ahead of print]

  • Matrix Isolation Infrared Spectroscopic Studies and Density Functional Theory Calculations of the MNN, (MN)(2) (M = Y and La), and Y(3)NN Molecules. J Phys Chem A. 2008 Mar 18; [Epub ahead of print]

  • Epithelial and endothelial barriers in the olfactory region of the nasal cavity of the rat. Histochem Cell Biol. 2008 Mar 14; [Epub ahead of print]

  • Radio-opaque appearance of lanthanum carbonate in a patient with chronic renal failure. Nephrol Dial Transplant. 2008 Mar 13; [Epub ahead of print] No abstract available.

  • Rare-Earth Metal Complexes Supported by 1,omega-Dithiaalkanediyl-Bridged Bis(phenolato) Ligands: Synthesis, Structure, and Heteroselective Ring-Opening Polymerization of rac-Lactide. Inorg Chem. 2008 Mar 4; [Epub ahead of print]

  • Neurotoxicological Evaluation of Long-term Lanthanum Chloride Exposure in Rats. Toxicol Sci. 2008 Mar 3; [Epub ahead of print]

  • [Therapeutic options for mineral metabolism disorders in dialysis patients: a case report.] G Ital Nefrol. 2008 Mar-Apr;25(2):234-7. Italian.

  • Rational design of a novel calcium-binding site adjacent to the ligand-binding site on CD2 increases its CD48 affinity. Protein Sci. 2008 Mar;17(3):439-49.

  • Can the Risk of Gadolinium be Extrapolated to Lanthanum? Semin Dial. 2008 Mar-Apr;21(2):142-4. Epub 2008 Feb 1.

  • E-NTPDases and ecto-5'-nucleotidase expression profile in rat heart left ventricle and the extracellular nucleotide hydrolysis by their nerve terminal endings. Life Sci. 2008 Feb 27;82(9-10):477-86. Epub 2008 Jan 16.

  • Local Ca2+ influx through Ca2+ release-activated Ca2+ (CRAC) channels stimulates production of an intracellular messenger and an intercellular pro-inflammatory signal. J Biol Chem. 2008 Feb 22;283(8):4622-31. Epub 2007 Dec 21.

 

 

 

 

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