American Elements specializes in producing Lanthanum Calcium Manganite (LCM) for fuel cell cathode applications utilizing solid state processing to produce single phase perovskite structures with various doping levels and surface areas (SSA) for use in thin film layers. Upon firing, American Elements' Lanthanum Calcium Manganite will partially sinter to form well-defined necks and open gas paths to permit simultaneous gas and electrical transfer. Lanthanum Calcium Manganite has an excellent thermal expansion match with Yttria Stabilized Zirconia (YSZ) electrolytes. It is highly electronically conductive and has proven long term stability. Lanthanum Calcium Manganite belongs to a class of "A" site and "B" site doped perovskite structures with these properties. These include Lanthanum Strontium Manganite (LSM), Lanthanum Strontium Ferrite (LSF), Lanthanum Strontium Cobaltite Ferrite (LSCF), Lanthanum Strontium Chromite (LSC), and Lanthanum Strontium Gallate Magnesite (LSGM). Lanthanum Calcium Manganite is available as a powder for tape casting, air spray/thermal spray/plasma spray, extrusion and sputtering fuel cell applications and as an ink for screen printing. Strontium doping levels are available at 10% and 20% and as specified by customer. Oxygen starved compositions are available. American Elements provides guidance on firing parameters, doping levels, and thermal expansion matching with American Elements' electrolyte and interconnect fuel cell layers.
Lanthanum is a Block F, Group 3, Period 6 element. The number of electrons in each of Lanthanum's shells is 2, 8, 18, 18, 9, 2 and its electronic configuration is [Xe] 5d1 6s2. In its elemental form lanthanum 's CAS number is 7439-91-0. The lanthanum atom has a radius of 187.pm and it's Van der Waals radius is 200.pm. Lanthanum and compounds of Lanthanum are somewhat toxic. Lanthanum is one of the products manufactured and distributed under the tradename AE Rare Earths. Lanthanum is the first element in the rare earth or lanthanide series. It is the model for all the other trivalent rare earths. After cerium, it is the second most abundant of the rare earths. Lanthanum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.Lanthanum-rich lanthanide compositions have been used extensively for cracking reactions in FCC catalysts, especially to manufacture low-octane fuel for heavy crude oil. The name Lanthanum originates from the Greek word Lanthaneia which means 'To lie hidden'. See Lanthanum research below.
Calcium is a Block S, Group 2, Period 4 element. The number of electrons in each of Calcium's shells is 2, 8, 8, 2 and its electronic configuration is [Ar] 4s2. In its elemental form calcium's CAS number is 7440-70-2. The calcium atom has a radius of 197.4.pm and it's Van der Waals radius is 200.pm. Calcium is a member of the alkaline earth elements. Calcium is an essential metal for living organisms and is non-toxic. Its primary commercial application is in its metallic form as a reducing agent in the production of other metals. In iron and steel production it is added to the melt to remove oxygen, sulfur and carbon. The various calcium compounds have wide application in food, pharmaceutical and cosmetics. It is used in small doses in alloys of copper and beryllium. It is used in dietary supplements and food production because it has been shown to improve bone and dental health. Calcium information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed here. Calcium was first discovered by Sir Humphrey Davy in 1808. The name calcium originates from the Latin word 'calics' meaning lime. See Calcium research below.
Manganese is a Block D, Group 7, Period 4 element. The number of electrons in each of Manganese's shells is 2, 8, 13, 2 and its electronic configuration is [Ar] 3d5 4s2. In its elemental form manganese's CAS number is 7439-96-5. The manganese atom has a radius of 136.7.pm and it's Van der Waals radius is 200.pm. Manganese in excess is toxic, in particular the inhalation of manganese in powder or dust form. Manganese metal is a key component of aluminumalloys. Manganese oxide is used in dry cell batteries. Manganese is used in steel production to remove sulfur and oxygen. Manganese is the colorant in natural amethyst stones and is used in glass and ceramics to also create the amethyst color. It is used like the element cerium to "decolorize" glass by offsetting the green from impurities of ferric ions. Permanganate is a powerful oxidizing agent and is used in medicine. It is added as a nutritional supplement for both human and animal consumption. Recently, the oxide in the form of various perovskite structures have demonstrated applications in oxygen generation and solid oxide fuel cells. Manganese was first discovered by Johann Gahn in 1774. The name Manganese originates from the Latin word mangnes meaning magnet. See Manganese research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Intestinal pseudo-obstruction secondary to persistent constipation due to lanthanum carbonate.
Camarero-Temiño V, Mercado-Valdivia V, Hijazi-Prieto B, Abaigar-Luquin P.
Nefrologia. 2012 Jan 27;32(1):129. doi: 10.3265/Nefrologia.pre2011.Nov.11191. English, Spanish. No abstract available.
PMID:
22294019
[PubMed - as supplied by publisher]
Chlorination of Lanthanum Oxide.
Gaviría JP, Navarro LG, Bohé AE.
J Phys Chem A. 2012 Jan 25. [Epub ahead of print]
PMID:
22280490
[PubMed - as supplied by publisher]
Dipyridyl ?-diketonate complexes and their use as metalloligands in the formation of mixed-metal coordination networks.
Burrows AD, Mahon MF, Renouf CL, Richardson C, Warren AJ, Warren JE.
Dalton Trans. 2012 Jan 26. [Epub ahead of print]
PMID:
22278306
[PubMed - as supplied by publisher]
Multifunctional lanthanum tetraphosphonates: Flexible, ultramicroporous and proton-conducting hybrid frameworks.
Colodrero RM, Olivera-Pastor P, Losilla ER, Aranda MA, Leon-Reina L, Papadaki M, McKinlay AC, Morris RE, Demadis KD, Cabeza A.
Dalton Trans. 2012 Jan 25. [Epub ahead of print]
PMID:
22278089
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Biosorption and desorption of lanthanum(III) and neodymium(III) in fixed-bed columns with Sargassum sp.: Perspectives for separation of rare earth metals.
Oliveira RC, Guibal E, Garcia O.
Biotechnol Prog. 2012 Jan 24. doi: 10.1002/btpr.1525. [Epub ahead of print]
PMID:
22275117
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Mid-infrared spectral broadening in an ultrafast laser inscribed gallium lanthanum sulphide waveguide.
McCarthy JE, Bookey HT, Psaila ND, Thomson RR, Kar AK.
Opt Express. 2012 Jan 16;20(2):1545-51. doi: 10.1364/OE.20.001545.
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22274497
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Redetermination of LaZn(5) based on single crystal X-ray diffraction data.
Oshchapovsky I, Zelinska O, Rozdzynska-Kielbik B, Pavlyuk V.
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan 1;68(Pt 1):i1. Epub 2011 Dec 3.
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Novel LaBO(3) hollow nanospheres of size 34±2nm templated by polymeric micelles.
Sasidharan M, Gunawardhana N, Luitel HN, Yokoi T, Inoue M, Yusa SI, Watari T, Yoshio M, Tatsumi T, Nakashima K.
J Colloid Interface Sci. 2011 Dec 28. [Epub ahead of print]
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22257959
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Lanthanum Carbonate Reduces Urine Phosphorus Excretion: Evidence of High-Capacity Phosphate Binding.
Pennick M, Poole L, Dennis K, Smyth M.
Ren Fail. 2012 Jan 17. [Epub ahead of print]
PMID:
22250993
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Effect of Lanthanum on Rooting of In Vitro Regenerated Shoots of Saussurea involucrata Kar. et Kir.
Guo B, Xu LL, Guan ZJ, Wei YH.
Biol Trace Elem Res. 2012 Jan 13. [Epub ahead of print]
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Fabrication, Characterization, and Application of a Composite Adsorbent for Simultaneous Removal of Arsenic and Fluoride.
Jing C, Cui J, Huang Y, Li A.
ACS Appl Mater Interfaces. 2012 Jan 25. [Epub ahead of print]
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22235839
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Gas-phase lanthanide chloride clusters: relationships among ESI abundances and DFT structures and energetics.
Rutkowski PX, Michelini MC, Gibson JK.
Phys Chem Chem Phys. 2012 Feb 14;14(6):1965-77. Epub 2012 Jan 6.
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Enhanced electrochemical properties of fluoride-coated LiCoO2 thin films.
Lee HJ, Kim SB, Park YJ.
Nanoscale Res Lett. 2012 Jan 5;7(1):16. [Epub ahead of print]
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La(5)Zn(2)Sn.
Oshchapovsky I, Pavlyuk V, Dmytriv G, Chumak I, Ehrenberg H.
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov 1;67(Pt 11):i65. Epub 2011 Oct 22.
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Lanthanum chloride bidirectionally influences calcification in bovine vascular muscle smooth cells.
Zhao WH, Gou BD, Zhang TL, Wang K.
J Cell Biochem. 2011 Dec 28. doi: 10.1002/jcb.24049. [Epub ahead of print]
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22213182
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The Intramolecular Rearrangement of Phosphinohydrazides [R'(2)P-NR-NR-M] ? [RN?PR'(2)-NR-M]: General Rules and Exceptions. Transformations of Bulky Phosphinohydrazines (R-NH-N(PPh(2))(2), R = tBu, Ph(2)P).
Kornev AN, Sushev VV, Panova YS, Belina NV, Lukoyanova OV, Fukin GK, Ketkov SY, Abakumov GA, Lönnecke P, Hey-Hawkins E.
Inorg Chem. 2012 Jan 16;51(2):874-81. Epub 2011 Dec 30.
PMID:
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Medicare Part D: challenges for dialysis patients. Part 1.
Smith S, Witten B, Paykin C, Weiner S, Chianchiano D, St Peter WL.
Nephrol News Issues. 2011 Nov;25(12):38-40, 42, 44-5.
PMID:
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[PubMed - indexed for MEDLINE]
Nanocrystalline Brookite with Enhanced Stability and Photocatalytic Activity: Influence of Lanthanum(III) Doping.
Perego C, Wang YH, Durupthy O, Cassaignon S, Revel R, Jolivet JP.
ACS Appl Mater Interfaces. 2012 Jan 17. [Epub ahead of print]
PMID:
22201282
[PubMed - as supplied by publisher]
The light-sensitive conductance of melanopsin-expressing Joseph and Hesse cells in amphioxus.
Pulido C, Malagón G, Ferrer C, Chen JK, Angueyra JM, Nasi E, Gomez Mdel P.
J Gen Physiol. 2012 Jan;139(1):19-30.
PMID:
22200946
[PubMed - in process]
Preparation and characterization of La(III) encapsulated silica gel/chitosan composite and its metal uptake studies.
Gandhi MR, Meenakshi S.
J Hazard Mater. 2012 Feb 15;203-204:29-37. Epub 2011 Nov 28.
PMID:
22197561
[PubMed - in process]
Prevention of preterm labour: 2011 update on tocolysis.
Hubinont C, Debieve F.
J Pregnancy. 2011;2011:941057. Epub 2011 Nov 15.
PMID:
22175022
[PubMed - in process]
Efficient conversion of astrocytes to functional midbrain dopaminergic neurons using a single polycistronic vector.
Addis RC, Hsu FC, Wright RL, Dichter MA, Coulter DA, Gearhart JD.
PLoS One. 2011;6(12):e28719. Epub 2011 Dec 9.
PMID:
22174877
[PubMed - in process]
Dysferlin Interacts with Histone Deacetylase 6 and Increases alpha-Tubulin Acetylation.
Di Fulvio S, Azakir BA, Therrien C, Sinnreich M.
PLoS One. 2011;6(12):e28563. Epub 2011 Dec 8.
PMID:
22174839
[PubMed - in process]
Regulation of Brain-Derived Neurotrophic Factor Exon IV Transcription through Calcium Responsive Elements in Cortical Neurons.
Zheng F, Zhou X, Luo Y, Xiao H, Wayman G, Wang H.
PLoS One. 2011;6(12):e28441. Epub 2011 Dec 9.
PMID:
22174809
[PubMed - in process]
Adeno-associated virus-mediated rescue of the cognitive defects in a mouse model for angelman syndrome.
Daily JL, Nash K, Jinwal U, Golde T, Rogers J, Peters MM, Burdine RD, Dickey C, Banko JL, Weeber EJ.
PLoS One. 2011;6(12):e27221. Epub 2011 Dec 9.
PMID:
22174738
[PubMed - in process]
Nifedipine Protects INS-1 ß-Cell from High Glucose-Induced ER Stress and Apoptosis.
Wang Y, Gao L, Li Y, Chen H, Sun Z.
Int J Mol Sci. 2011;12(11):7569-80. Epub 2011 Nov 7.
PMID:
22174617
[PubMed - in process]
Chitosan Fibers Modified with HAp/ß-TCP Nanoparticles.
Wawro D, Pighinelli L.
Int J Mol Sci. 2011;12(11):7286-300. Epub 2011 Oct 25.
PMID:
22174598
[PubMed - in process]
Mild and moderate pre-dialysis chronic kidney disease is associated with increased coronary artery calcium.
Roy SK, Cespedes A, Li D, Choi TY, Budoff MJ.
Vasc Health Risk Manag. 2011;7:719-24. Epub 2011 Dec 2.
PMID:
22174582
[PubMed - in process]
Ambulatory blood pressure response to triple therapy with an angiotensin-receptor blocker (ARB), calcium-channel blocker (CCB), and HCTZ versus dual therapy with an ARB and HCTZ.
Duprez D, Ferdinand K, Purkayastha D, Samuel R, Wright R.
Vasc Health Risk Manag. 2011;7:701-8. Epub 2011 Nov 24.
PMID:
22174580
[PubMed - in process]
Leukotriene E4 Activates Human Th2 Cells for Exaggerated Proinflammatory Cytokine Production in Response to Prostaglandin D2.
Xue L, Barrow A, Fleming VM, Hunter MG, Ogg G, Klenerman P, Pettipher R.
J Immunol. 2011 Dec 14. [Epub ahead of print]
PMID:
22174450
[PubMed - as supplied by publisher]
Association Between Depression and Vascular Disease in Systemic Lupus Erythematosus.
Greco CM, Li T, Sattar A, Kao AH, Danchenko N, Edmundowicz D, Sutton-Tyrrell K, Tracy RP, Kuller LH, Manzi S.
J Rheumatol. 2011 Dec 15. [Epub ahead of print]
PMID:
22174200
[PubMed - as supplied by publisher]
A rare electrocardiographic manifestation of a rare form of multiple electrolyte disturbances: hyperparathyroid crisis.
Hajsadeghi S, Chitsazan M, Miresmail SJ.
Acta Med Iran. 2011 Dec;49(12):824-7.
PMID:
22174173
[PubMed - in process]
A cross-sectional study to determine the prevalence of calcium metabolic disorder in malignant childhood cancers in patients admitted to the pediatric ward of vali-asr hospital.
Moayeri H, Oloomi Z, Sambo SA.
Acta Med Iran. 2011 Dec;49(12):818-23.
PMID:
22174172
[PubMed - in process]
Study to Evaluate Two Dosage Regimens of Vitamin D through an Academic Year in Middle School Girls: a Randomized Trial.
Shakiba M, Ghadir M, Nafei Z, Akhavan Karbasi S, Lotfi MH, Shajari A.
Acta Med Iran. 2011 Dec;49(12):780-3.
PMID:
22174164
[PubMed - in process]
Oxidative stress due to aluminium exposure induces eryptosis which is prevented by erythropoietin.
Vota DM, Crisp RL, Nesse AB, Vittori DC.
J Cell Biochem. 2011 Dec 15. doi: 10.1002/jcb.24026. [Epub ahead of print]
PMID:
22174104
[PubMed - as supplied by publisher]
Parameters Affecting the Efficient Delivery of Mesoporous Silica Nanoparticle Materials and Gold Nanorods into Plant Tissues by the Biolistic Method.
Martin-Ortigosa S, Valenstein JS, Sun W, Moeller L, Fang N, Trewyn BG, Lin VS, Wang K.
Small. 2011 Dec 16. doi: 10.1002/smll.201101294. [Epub ahead of print]
PMID:
22174078
[PubMed - as supplied by publisher]
Cell Excitability Necessary for Male Mating Behavior in Caenorhabditis elegans is Coordinated by Interactions Between BK and EAG Family K+ Channels.
Leboeuf B, Garcia LR.
Genetics. 2011 Dec 14. [Epub ahead of print]
PMID:
22174070
[PubMed - as supplied by publisher]
Dantrolene rescues arrhythmogenic RYR2 defect in a patient-specific stem cell model of catecholaminergic polymorphic ventricular tachycardia.
Jung CB, Moretti A, Schnitzler MM, Iop L, Storch U, Bellin M, Dorn T, Ruppenthal S, Pfeiffer S, Goedel A, Dirschinger RJ, Seyfarth M, Lam JT, Sinnecker D, Gudermann T, Lipp P, Laugwitz KL.
EMBO Mol Med. 2011 Dec 15. doi: 10.1002/emmm.201100194. [Epub ahead of print]
PMID:
22174035
[PubMed - as supplied by publisher]
Vitamin D Regulates Anti-Mullerian Hormone Expression in Granulosa Cells of the Hen.
Wojtusik J, Johnson PA.
Biol Reprod. 2011 Dec 14. [Epub ahead of print]
PMID:
22174023
[PubMed - as supplied by publisher]
Mechanistic involvement of the calpain-calpastatin system in Alzheimer neuropathology.
Higuchi M, Iwata N, Matsuba Y, Takano J, Suemoto T, Maeda J, Ji B, Ono M, Staufenbiel M, Suhara T, Saido TC.
FASEB J. 2011 Dec 15. [Epub ahead of print]
PMID:
22173972
[PubMed - as supplied by publisher]
Mn(II) removal from groundwater with manganese
oxide-coated filter media. Piispanen JK, Sallanko JT. J Environ Sci Health A Tox Hazard Subst Environ Eng.
2010 Nov;45(13):1732-40. PubMed PMID: 20924918.
Decolourization of synthetic wastewater
containing azo dyes by immobilized Phanerochaete chrysosporium in a continuously
operated RBC reactor. Pakshirajan K, Sivasankar A, Sahoo NK. Appl Microbiol Biotechnol. 2010 Oct 6. [Epub ahead of
print] PubMed PMID: 20924578.
A fast black-blood sequence for four-dimensional cardiac
manganese-enhanced MRI in mouse. Lefrançois W, Miraux S, Calmettes G, Pourtau L, Franconi JM, Diolez P,
Thiaudière E. NMR Biomed. 2010 Oct 6. [Epub ahead of print]
PubMed PMID: 20925127.
Functional TRPV4 channels are expressed in mouse skeletal muscle and can modulate
resting Ca(2+) influx and muscle fatigue. Pritschow BW, Lange T, Kasch J, Kunert-Keil C, Liedtke W, Brinkmeier H. Pflugers Arch. 2010 Oct 6. [Epub ahead
of print] PubMed PMID: 20924600.
Effects of Aluminum Exposure on Bone
Mineral Density, Mineral, and Trace Elements in Rats. Li X, Hu C, Zhu Y, Sun H, Li Y, Zhang Z. Biol Trace Elem Res. 2010
Oct 1. [Epub ahead of print] PubMed PMID: 20886309.
An artificial model of photosynthetic
photosystem II: visible-light-derived O(2) production from water by a
di-µ-oxo-bridged manganese dimer as an oxygen evolving center. Yagi M, Toda M, Yamada S, Yamazaki H. Chem Commun
(Camb). 2010 Oct 1. [Epub ahead of print] PubMed PMID: 20890491.
The unexpected role of
pyridine-2-carboxylic acid in manganese based oxidation catalysis with
pyridin-2-yl based ligands. Pijper D, Saisaha P, de Boer JW, Hoen R, Smit C, Meetsma A, Hage R, van
Summeren RP, Alsters PL, Feringa BL, Browne WR. Dalton Trans. 2010 Oct 1. [Epub ahead of print]
PubMed PMID: 20886164.
Dieckol rescues mice from lethal irradiation by accelerating hemopoiesis and
curtailing immunosuppression. Park E, Ahn G, Yun JS, Kim MJ, Bing SJ, Kim DS, Lee J, Lee NH, Park JW, Jee Y. Int J Radiat Biol. 2010 Oct;86(10):848-59. PubMed
PMID: 20883140.
Manganese enhancement in non-CNS organs. Lee LW, So PW, Price AN, Parkinson JR, Larkman DJ, Halliday J, Poucher SM,
Pugh JA, Cox AG, McLeod CW, Bell JD. NMR
Biomed. 2010 Oct;23(8):931-8. PubMed PMID: 20878971.
Fractionated manganese injections: effects on MRI contrast enhancement
and physiological measures in C57BL/6 mice. Grünecker B, Kaltwasser SF, Peterse Y, Sämann PG, Schmidt MV, Wotjak CT,
Czisch M. NMR Biomed. 2010 Oct;23(8):913-21.
PubMed PMID: 20878969.
Micro- to Macroscopic Observations of
MnAlPO-5 Nanocrystal Growth in Ionic-Liquid Media. Ng EP, Itani L, Sekhon SS, Mintova S. Chemistry. 2010 Sep 30. [Epub
ahead of print] PubMed PMID: 20886470.
Studies of magnetic
properties and HFEPR of octanuclear manganese single-molecule magnets. Wu CC, Datta S, Wernsdorfer W, Lee GH, Hill S, Yang EC. Dalton
Trans. 2010 Sep 30. [Epub ahead of print] PubMed PMID: 20886147.
Case
Study on a Rare Effect: The Experimental and Theoretical Analysis of a
Manganese(III) Spin-Crossover System. Wang S, Ferbinteanu M, Marinescu C, Dobrinescu A, Ling QD, Huang W. Inorg Chem. 2010 Sep 30. [Epub ahead of
print] PubMed PMID: 20883036.
Distribution of (210)Pb and (210)Po in
boreal forest soil. Vaaramaa K, Aro L, Solatie D, Lehto J. Sci Total Environ. 2010 Sep 30. [Epub ahead of print] PubMed
PMID: 20888619.
The effect of hydrogen peroxide-induced oxidative stress on
leukocytes depends on age and physical training in healthy human subjects
carrying the same genotypes of antioxidant enzymes' gene polymorphisms. Miranda-Vilela AL, Alves PC, Akimoto AK, Pereira LC, Nazaré Klautau-Guimarães
MD, Grisolia CK. Am J Hum
Biol. 2010 Sep 28. [Epub ahead of print] PubMed PMID: 20878976.
Magnetothermal Studies of a
Series of Coordination Clusters Built from Ferromagnetically Coupled {Mn(II)
(4)Mn(III) (6)} Supertetrahedral Units. Nayak S, Evangelisti M, Powell AK, Reedijk J. Chemistry. 2010 Sep 28. [Epub ahead of
print] PubMed PMID: 20878813.
In Vivo
Measurement of Brain GABA Concentrations by Magnetic Resonance Spectroscopy in
Smelters Occupationally Exposed to Manganese. Dydak U, Jiang YM, Long LL, Zhu H, Chen J, Li WM, Edden RA, Hu S, Fu X, Long
Z, Mo XA, Meier D, Harezlak J, Aschner M, Murdoch JB, Zheng W. Environ Health Perspect. 2010 Sep
28. [Epub ahead of print] PubMed PMID: 20876035.
EFFECTIVE
DOSE OF MINERS DUE TO NATURAL RADIOACTIVITY IN A MANGANESE MINE IN HUNGARY.
Kávási N, Vigh T, Sorimachi A, Ishikawa T, Tokonami S, Hosoda M. Radiat Prot Dosimetry. 2010 Sep 27. [Epub ahead of print] PubMed PMID: 20876071.
Manganese and trace-metal
mobility under reducing conditions following in situ oxidation of TCE by KMnO(4):
A laboratory column experiment. Loomer DB, Al TA, Banks VJ, Parker BL, Mayer KU. J Contam Hydrol. 2010 Aug 26. [Epub ahead of
print] PubMed PMID: 20889229.
[Endemic and biogeochemical features of the territory of Chuvash Republic].
Vestn Ross Akad Med Nauk. 2010;(8):40-6. Russian. PubMed PMID: 20922843.