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Lanthanum Calcium Manganite (LCM)
Lanthanum Manganite doped with Calcium Oxide
Fuel Cell Cathode |
La2O3/MnO/CaO |
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Lanthanum Calcium Manganite (Ca = 10%) Powder |
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Lanthanum Calcium Manganite (Ca = 10%) Ink |
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Lanthanum Calcium Manganite (Ca= 20%) Powder |
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Lanthanum Calcium Manganite (Ca = 20%) Ink |
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American Elements specializes in producing lanthanum calcium manganite (LCM) for fuel cell cathode applications utilizing solid state processing to produce single phase perovskite structures with various doping levels and surface areas (SSA) for use in thin film layers. Upon firing, American Elements' Lanthanum Calcium Manganite will partially sinter to form well-defined necks and open gas paths to permit simultaneous gas and electrical transfer. Lanthanum Calcium Manganite has an excellent thermal expansion match with Yttria Stabilized Zirconia (YSZ) electrolytes. It is highly electronically conductive and has proven long term stability. Lanthanum Calcium Manganite belongs to a class of "A" site and "B" site doped perovskite structures with these properties. These include Lanthanum Strontium Manganite (LSM), Lanthanum Strontium Ferrite (LSF), Lanthanum Strontium Cobaltite Ferrite (LSCF), Lanthanum Strontium Chromite (LSC), and Lanthanum Strontium Gallate Magnesite (LSGM). Lanthanum Calcium Manganite is available as a powder for tape casting, air spray/thermal spray/plasma spray, extrusion and sputtering fuel cell applications and as an ink for screen printing. Strontium doping levels are available at 10% and 20% and as specified by customer. Oxygen starved compositions are available. American Elements provides guidance on firing parameters, doping levels, and thermal expansion matching with American Elements' electrolyte and interconnect fuel cell layers.
Lanthanum is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe] 5d1 6s2. In its elemental form lanthanum 's CAS number is 7439-91-0. The lanthanum atom has a radius of 187.pm and it's Van der Waals radius is 200.pm. Lanthanum is one of the products manufactured and distributed under the tradename AE Rare Earths. Lanthanum is the first element in the rare earth or lanthanide series. It is the model for all the other trivalent rare earths. After cerium, it is the second most abundant of the rare earths. Lanthanum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Lanthanum-rich lanthanide compositions have been used extensively for cracking reactions in FCC catalysts, especially to manufacture low-octane fuel for heavy crude oil.
Calcium is a Block S, Group 2, Period 4 element. The electronic configuration is [Ar] 4s2. In its elemental form calcium's CAS number is 7440-70-2. The calcium atom has a radius of 197.4.pm and it's Van der Waals radius is 200.pm. Calcium is a member of the alkaline earth elements. Its primary commercial application is in its metallic form as a reducing agent in the production of other metals. In iron and steel production it is added to the melt to remove oxygen, sulfur and carbon. The various calcium compounds have wide application in food, pharmaceutical and cosmetics. It is used in small doses in alloys of copper and beryllium. It is used in dietary supplements and food production because it has been shown to improve bone and dental health. Calcium was first discovered by Sir Humphrey Davy in 1808.
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Periodic table of the elements science and academic information, elements and advanced materials data, scientific presentations and all pages, designs, concepts, logos, and color schemes herein are the copyrighted proprietary rights and intellectual property of American Elements. American Elements is a U.S. Registered Trademark. © 2001-2009. American Elements. All rights reserved. |
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Recent Research & Development for Lanthanum
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Development of heterogeneous base catalysts for biodiesel production.
Bioresour Technol. 2008 Jun;99(9):3439-43. Epub 2007 Sep 19.
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Removal of lanthanum and gadolinium from nitrate medium using Aliquat-336 impregnated onto Amberlite XAD-4.
J Hazard Mater. 2008 May 30;153(3):948-54. Epub 2007 Sep 16.
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Formation of molecular glasses and the aggregation in solutions for lanthanum(iii), calcium(ii), and yttrium(iii) complexes of octanoyl-dl-alaninate.
Dalton Trans. 2008 Apr 7;(13):1698-709. Epub 2008 Feb 14.
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Resistance against novel anticancer metal compounds: Differences and similarities.
Drug Resist Updat. 2008 Apr 2; [Epub ahead of print]
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Biokinetics of Cadmium and Zinc in a Marine Bacterium: Influences of Metal Interaction and Pre-Exposure.
Environ Toxicol Chem. 2008 Apr 2;:1 [Epub ahead of print]
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Ca(2+)/calmodulin-dependent invasion of microvascular endothelial cells of human brain by Escherichia coli K1.
Cell Tissue Res. 2008 Apr 1; [Epub ahead of print]
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Structural and functional characterization and physiological significance of a stimulator protein of Mg(2+)-independent Ca (2+)-ATPase isolated from goat spermatozoa.
Mol Cell Biochem. 2008 Apr;311(1-2):93-103. Epub 2007 Dec 30.
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Effect of Focused Ultrasound Applied With an Ultrasound Contrast Agent on the Tight Junctional Integrity of the Brain Microvascular Endothelium.
Ultrasound Med Biol. 2008 Mar 29; [Epub ahead of print]
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Hydration of Lanthanoid(III) Ions in Aqueous Solution and Crystalline Hydrates Studied by EXAFS Spectroscopy and Crystallography: The Myth of the "Gadolinium Break"
Chemistry. 2008 Mar 27;14(10):3056-3066.
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Characterization of root mucilage from Melastoma malabathricum, with emphasis on its roles in aluminum accumulation.
New Phytol. 2008 Mar 26; [Epub ahead of print]
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Matrix Isolation Infrared Spectroscopic Studies and Density Functional Theory Calculations of the MNN, (MN)(2) (M = Y and La), and Y(3)NN Molecules.
J Phys Chem A. 2008 Mar 18; [Epub ahead of print]
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Epithelial and endothelial barriers in the olfactory region of the nasal cavity of the rat.
Histochem Cell Biol. 2008 Mar 14; [Epub ahead of print]
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Radio-opaque appearance of lanthanum carbonate in a patient with chronic renal failure.
Nephrol Dial Transplant. 2008 Mar 13; [Epub ahead of print] No abstract available.
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Rare-Earth Metal Complexes Supported by 1,omega-Dithiaalkanediyl-Bridged Bis(phenolato) Ligands: Synthesis, Structure, and Heteroselective Ring-Opening Polymerization of rac-Lactide.
Inorg Chem. 2008 Mar 4; [Epub ahead of print]
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Neurotoxicological Evaluation of Long-term Lanthanum Chloride Exposure in Rats.
Toxicol Sci. 2008 Mar 3; [Epub ahead of print]
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[Therapeutic options for mineral metabolism disorders in dialysis patients: a case report.]
G Ital Nefrol. 2008 Mar-Apr;25(2):234-7. Italian.
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Rational design of a novel calcium-binding site adjacent to the ligand-binding site on CD2 increases its CD48 affinity.
Protein Sci. 2008 Mar;17(3):439-49.
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Can the Risk of Gadolinium be Extrapolated to Lanthanum?
Semin Dial. 2008 Mar-Apr;21(2):142-4. Epub 2008 Feb 1.
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E-NTPDases and ecto-5'-nucleotidase expression profile in rat heart left ventricle and the extracellular nucleotide hydrolysis by their nerve terminal endings.
Life Sci. 2008 Feb 27;82(9-10):477-86. Epub 2008 Jan 16.
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Local Ca2+ influx through Ca2+ release-activated Ca2+ (CRAC) channels stimulates production of an intracellular messenger and an intercellular pro-inflammatory signal.
J Biol Chem. 2008 Feb 22;283(8):4622-31. Epub 2007 Dec 21.
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