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Manganese
Manganese information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Manganese has numerous low and high tech applications. Manganese is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Manganese metal is a key component of aluminum alloys. Manganese oxide is used in dry cell batteries. Manganese is used in steel production to remove sulfur and oxygen. Manganese is the colorant in natural amethyst stones and is used in glass and ceramics to also create the amethyst color. It is used like the element Cerium to "decolorize" glass by offsetting the green from impurities of ferric ions. Permanganate is a powerful oxidizing agent and is used in medicine. It is added as a nutritional supplement for both human and animal consumption. Recently, the oxide in the form of various perovskite structures have demonstrated applications in oxygen generation and solid oxide fuel cells.

Manganese facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Manganese is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Manganese is a Block D, Group 7, Period 4 element. The electronic configuration is [Ar] 3d5 4s2. In its elemental form manganese's CAS number is 7439-96-5. The manganese atom has a radius of 136.7.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Manganese compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Manganese was first discovered by Johann Gahn in 1774.

French manganèse German Mangan Italian manganese Portuguese Manganésio Spanish manganeso Swedish Mangan

Abundance. The following table shows the abundance of manganese and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Mn-55
54.938050
100

Safety Data. The safety data for manganese metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for manganese (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
717.28 kJ mol-1
2nd Ionization Energy
1509.04 kJ mol-1
3rd Ionization Energy
3248.49 kJ mol-1

Conductivity. As to manganese's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 144 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.55. The thermal conductivity of manganese is 7.82 W m-1 K-1.

Thermal Properties. The melting point and boiling point for manganese are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
14.4 kJ mol-1
Heat of Vaporization
220.5 kJ mol-1
Heat of Atomization
279.37 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Mn 25 54.9380 g.mol -1 1.5 7.43 g.cm-3 at 20 °C 1247 °C 2061 °C 200.pm 0.008 nm (+2) ; 0.046 nm (+7) 717.28 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Manganese

  • The influence of the ectomycorrhizal fungus Rhizopogon subareolatus on growth and nutrient element localisation in two varieties of Douglas fir (Pseudotsuga menziesii var. menziesii and var. glauca) in response to manganese stress. Mycorrhiza. 2008 Apr 24; [Epub ahead of print]

  • Exercise restores endothelial function independently of weight loss or hyperglycaemic status in db/db mice. Diabetologia. 2008 Apr 25; [Epub ahead of print]

  • Hepatic Effects of a Fructose Diet in the Stroke-prone Spontaneously Hypertensive Rat. Am J Hypertens. 2008 Apr 10; [Epub ahead of print]

  • Liver Metal Concentrations in Greater Sage-grouse (Centrocercus urophasianus). J Wildl Dis. 2008 Apr;44(2):494-8.

  • Hepatic minerals of white-tailed and mule deer in the southern black hills, South dakota. J Wildl Dis. 2008 Apr;44(2):341-50.

  • Efficient and Selective Peracetic Acid Epoxidation Catalyzed by a Robust Manganese Catalyst. Org Lett. 2008 Apr 25; [Epub ahead of print]

  • Shear Stress Influences Spatial Variations in Vascular Mn-SOD Expression: Implication for LDL Nitration. Am J Physiol Cell Physiol. 2008 Apr 23; [Epub ahead of print]

  • Evaluation of trace metal contents of some wild edible mushrooms from Black sea region, Turkey. J Hazard Mater. 2008 Mar 13; [Epub ahead of print]

  • Observed and modeled seasonal trends in dissolved and particulate Cu, Fe, Mn, and Zn in a mining-impacted stream. Water Res. 2008 Mar 18; [Epub ahead of print]

  • A zinc-resistant human epithelial cell line is impaired in cadmium and manganese import. Toxicol Appl Pharmacol. 2008 Mar 6; [Epub ahead of print]

  • Control of molecular fragmentation using shaped femtosecond pulses. J Phys Chem A. 2008 May 1;112(17):3789-812.

  • Numbers, biomass and cultivable diversity of microbial populations relate to depth and borehole-specific conditions in groundwater from depths of 4-450 m in Olkiluoto, Finland. ISME J. 2008 Apr 24; [Epub ahead of print]

  • Metal Levels in Tissues of the European Anchovy, Engraulis encrasicolus L., 1758, and Picarel, Spicara smaris L., 1758, from Black, Marmara and Aegean Seas. Bull Environ Contam Toxicol. 2008 Apr 23; [Epub ahead of print]

  • Spatial correlation between the prevalence of transmissible spongiform diseases and British soil geochemistry. Environ Geochem Health. 2008 Apr 22; [Epub ahead of print]

  • Metal binding specificity of the MntABC permease of Neisseria gonorrhoeae and its influence on bacterial growth and interaction with cervical epithelial cells. Infect Immun. 2008 Apr 21; [Epub ahead of print]

  • Manganese Enhanced Magnetic Resonance Imaging in a Contusion Model of Spinal Cord Injury in Rats: Correlation With Motor Function. Invest Radiol. 2008 May;43(5):277-283.

  • (-)-Epigallocatechin gallate induces Nrf2-mediated-antioxidant enzyme expression via activation of PI3K and ERK in human mammary epithelial cells. Arch Biochem Biophys. 2008 Apr 6; [Epub ahead of print]

  • [Analysis and study of total flavone and trace element in carthmus tinctorius L] Guang Pu Xue Yu Guang Pu Fen Xi. 2008 Jan;28(1):225-7. Chinese.

  • [Effect of dizocilpine maleate and taurine on the circuitry of glutamate and glutamine in rat striatum exposed by manganese] Wei Sheng Yan Jiu. 2008 Jan;37(1):8-10. Chinese.

  • Manganese-enhanced MRI detection of neurodegeneration in neonatal hypoxic-ischemic cerebral injury. Magn Reson Med. 2008 Apr 17; [Epub ahead of print]

 

 

 

 

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