Palladium Chunk

High Purity Pd Chunks
CAS 7440-05-3


Product Product Code Order or Specifications
(2N) 99% Palladium Chunk PD-M-02-CK Contact American Elements
(3N) 99.9% Palladium Chunk PD-M-03-CK Contact American Elements
(4N) 99.99% Palladium Chunk PD-M-04-CK Contact American Elements
(5N) 99.999% Palladium Chunk PD-M-05-CK Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Pd 7440-05-3 24861601 23938 MFCD00011167 231-115-6 N/A [Pd] InChI=1S/Pd KDLHZDBZIXYQEI-UHFFFAOYSA-N

PROPERTIES Mol. Wt. Appearance Density Tensile Strength Melting Point Boiling Point Thermal Conductivity Electrical Resistivity Eletronegativity Specific Heat Heat of Vaporization Heat of Fusion MSDS
106.42 Gray Powder 12.02 gm/cc N/A 1554 °C 2970 °C

0.718 W/cm/K @ 298.2 K

10.54 microhm-cm @ 20°C

2.2 Paulings

0.0584 Cal/g/K @ 25°C 90 K-cal/gm atom at 2970°C

4.12 Cal/gm mole

Safety Data Sheet

High Purity ChunkAmerican Elements specializes in producing high purity Palladium Chunk using crystallization, solid state and other ultra high purification processes such as sublimation. Standard Chunk pieces are amorphous uniform pieces ranging in size from 5-15 mm. American Elements specializes in producing custom compositions for commercial and research applications and for new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into granules, rod, bar or plate form, as well as other machined shapes and through other processes such as nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and in the form of solutions and organometallics. See research below. We also produce Palladium as rod, pellets, powder, pieces, disc, ingot, wire, and in compound forms, such as oxide. Other shapes are available by request.

Palladium(Pd) atomic and molecular weight, atomic number and elemental symbolPalladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and its Van der Waals radius is 163.pm. Palladium is a member of the platinum group of metals. It is an excellent hydrogenation and dehydrogenationPalladium Bohr Model catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other platinum group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Elemental Palladium Researchers at the University of Delaware recently developed a chemical reaction that converts carbon-hydrogen bonds to carbon-silicon bonds using Palladium as a catalyst. The process is an important new tool for building molecules with potential industrial applications ranging from the manufacture of medicines to plastics. Palladium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Nickel-copper deposits are the main source of Palladium commercial production. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


Have a Question? Ask a Chemical Engineer or Material Scientist
Request an MSDS or Certificate of Analysis





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Recent Research & Development for Palladium

  • Synthesis of phenanthridines via palladium-catalyzed picolinamide-directed sequential C-H functionalization. Pearson R, Zhang S, He G, Edwards N, Chen G. Beilstein J Org Chem. 2013 May 8;9:891-9. doi: 10.3762/bjoc.9.102. Print 2013.
  • A ladder polysilane as a template for folding palladium nanosheets. Sunada Y, Haige R, Otsuka K, Kyushin S, Nagashima H. Nat Commun. 2013 Jun 14;4:2014. doi: 10.1038/ncomms3014.
  • Trinuclear palladium addition to unsaturated carbocycles. Murahashi T, Takase K, Usui K, Kimura S, Fujimoto M, Uemura T, Ogoshi S, Yamamoto K. Dalton Trans. 2013 Jun 13. [Epub ahead of print]
  • Electrooxidation of formaldehyde based on nickel-palladium modified ordered mesoporous silicon. Miao F, Tao B. J Nanosci Nanotechnol. 2013 Apr;13(4):3104-9.
  • Palladium-Catalyzed Direct Arylation of C-H Bond To Construct Quaternary Carbon Centers: The Synthesis of Diarylfluorene. Cao X, Yang W, Liu C, Wei F, Wu K, Sun W, Song J, Xie L, Huang W. Org Lett. 2013 Jun 12. [Epub ahead of print]
  • Palladium-Catalyzed Chemoselective Catellani ortho-Arylation of Iodopyrroles: Rapid Total Synthesis of Rhazinal. Sui X, Zhu R, Li G, Ma X, Gu Z. J Am Chem Soc. 2013 Jun 11. [Epub ahead of print]
  • Imidazolium-Salt-Functionalized Ionic-CNT-Supported Ru?Carbene/Palladium Nanoparticles for Recyclable Tandem Metathesis/Hydrogenation Reactions in Ionic Liquids. Lee S, Shin JY, Lee SG. Chem Asian J. 2013 Jun 11. doi: 10.1002/asia.201300360. [Epub ahead of print]
  • Influence of a surfactant and reducing agent on preparation of palladium. Kim SC, Jung SC, Park YK, Ahn HG, Seo SG. J Nanosci Nanotechnol. 2013 Mar;13(3):1961-5.
  • A Palladium-Catalyzed Enantioselective Addition of Arylboronic Acids to Cyclic Ketimines. Yang G, Zhang W. Angew Chem Int Ed Engl. 2013 Jun 10. doi: 10.1002/anie.201302861. [Epub ahead of print]
  • Palladium-Catalyzed Migratory Insertion of Isocyanides: An Emerging Platform in Cross-Coupling Chemistry. Vlaar T, Maes BU, Ruijter E, Orru RV. Angew Chem Int Ed Engl. 2013 Jun 10. doi: 10.1002/anie.201300942. [Epub ahead of print]
  • Promising anti-growth effects of palladium(II) saccharinate complex of terpyridine by inducing apoptosis on transformed fibroblasts in vitro. Coskun MD, Ari F, Oral AY, Sarimahmut M, Kutlu HM, Yilmaz VT, Ulukaya E. Bioorg Med Chem. 2013 May 23. doi:pii: S0968-0896(13)00458-6. 10.1016/j.bmc.2013.05.023. [Epub ahead of print]
  • Palladium-Catalyzed Direct C-H Arylation of Cyclic Enaminones with Aryl Iodides. Yu YY, Bi L, Georg GI. J Org Chem. 2013 Jun 10. [Epub ahead of print]
  • Correction to Palladium-Catalyzed Cascade Reactions of 1-(3-Arylprop-2-ynyloxy)-2-bromo Benzene Derivatives with Organoboron Compounds. Arcadi A, Blesi F, Cacchi S, Fabrizi G, Goggiamani A, Marinelli F. J Org Chem. 2013 Jun 10. [Epub ahead of print] No abstract available.
  • Synthesis and electrocatalytic activity of highly porous hollow palladium nanoshells for oxygen reduction in alkaline solution. Cho YB, Kim JE, Shim JH, Lee C, Lee Y. Phys Chem Chem Phys. 2013 Jun 7. [Epub ahead of print]
  • Palladium-Catalyzed Catellani Aminocyclopropanation Reactions with Vinyl Halides. Khanna A, Premachandra ID, Sung PD, Van Vranken DL. Org Lett. 2013 Jun 7. [Epub ahead of print]
  • Palladium-Catalyzed Oxidative Cross-Coupling of N-Tosylhydrazones with Indoles: Synthesis of N-Vinylindoles. Zeng X, Cheng G, Shen J, Cui X. Org Lett. 2013 Jun 4. [Epub ahead of print]
  • Synthesis, Characterization, and Cytotoxicity Studies of a Novel Palladium(II) Complex and Evaluation of DNA-Binding Aspects. Saeidifar M, Mansouri-Torshizi H, Palizdar Y, Divsalar A, Saboury AA. Nucleosides Nucleotides Nucleic Acids. 2013;32(7):366-88. doi: 10.1080/15257770.2013.790552.
  • Palladium-Catalyzed Regio-, Diastereo-, and Enantio-selective Allylation of Nitroalkanes with Monosubstituted Allylic Substrates. Yang XF, Yu WH, Ding CH, Ding QP, Wan SL, Hou XL, Dai LX, Wang PJ. J Org Chem. 2013 Jun 6. [Epub ahead of print]
  • Palladium-Catalyzed Arylic/Allylic Aminations: Permutable Domino Sequences for the Synthesis of Dihydroquinolines from Morita-Baylis-Hillman Adducts. Lorion MM, Gasperini D, Oble J, Poli G. Org Lett. 2013 Jun 4. [Epub ahead of print]
  • Palladium-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and the Influence of PhI(OAc)2 on Aminopalladation Stereoselectivity. Martínez C, Wu Y, Weinstein AB, Stahl SS, Liu G, Muñiz K.