Palladium Acetate is a moderately water soluble crystalline Palladium source that decomposes to Palladium oxide on heating. It is generally immediately available in most volumes. Acetates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic acetates are inorganic salts of a metal cation and the acetate anion. The acetate anion is a univalent (-1 charge) polyatomic ion composed of two carbon atoms ionically bound to three hydrogen and two oxygen atoms (Symbol: CH3COO) for a total formula weight of 59.05. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Palladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the platinum group of metals. It is an excellent hydrogenation and dehydrogenation catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other platinum group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Platinum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.
Acetate is an anion used as a ligand in metal complexes. The formula is CH3CO2-, C2H3O2-, or CH3COO-. Metal acetates are used in biology, printing, vinyl acetate in plastic production, volatile organic esters as solvents and cellulose acetate in photographic films and textiles. Cellulose acetate, one of the first synthetic fibers, is often called acetate.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
PET study using [(11)C]FTIMD with ultra-high specific activity to evaluate I(2)-imidazoline receptors binding in rat brains.
Kawamura K, Kimura Y, Yui J, Wakizaka H, Yamasaki T, Hatori A, Kumata K, Fujinaga M, Yoshida Y, Ogawa M, Nengaki N, Fukumura T, Zhang MR.
Nucl Med Biol. 2011 Sep 27. [Epub ahead of print]
PMID:
21958848
[PubMed - as supplied by publisher]
Titanocene-Phosphine Derivatives as Precursors to Cytotoxic Heterometallic TiAu(2) and TiM (M = Pd, Pt) Compounds. Studies of Their Interactions with DNA.
González-Pantoja JF, Stern M, Jarzecki AA, Royo E, Robles-Escajeda E, Varela-Ramírez A, Aguilera RJ, Contel M.
Inorg Chem. 2011 Sep 29. [Epub ahead of print]
PMID:
21958150
[PubMed - as supplied by publisher]
Convenient and General Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Amines.
Wu XF, Neumann H, Beller M.
Angew Chem Int Ed Engl. 2011 Sep 28. doi: 10.1002/anie.201104653. [Epub ahead of print] No abstract available.
PMID:
21957031
[PubMed - as supplied by publisher]
A Convenient and General Palladium-Catalyzed Carbonylative Coupling for the Synthesis of 2-Arylbenzoxazinones.
Wu XF, Schranck J, Neumann H, Beller M.
Chemistry. 2011 Sep 28. doi: 10.1002/chem.201102254. [Epub ahead of print] No abstract available.
PMID:
21956858
[PubMed - as supplied by publisher]
Palladium Nanoparticles Encapsulated in Metal-Organic Framework as Efficient Heterogeneous Catalysts for Direct C2 Arylation of Indoles.
Huang Y, Lin Z, Cao R.
Chemistry. 2011 Sep 28. doi: 10.1002/chem.201101705. [Epub ahead of print]
PMID:
21956646
[PubMed - as supplied by publisher]
Palladium-Catalyzed Pentannulation of Polycyclic Aromatic Hydrocarbons.
Lütke Eversloh C, Avlasevich Y, Li C, Müllen K.
Chemistry. 2011 Sep 28. doi: 10.1002/chem.201101126. [Epub ahead of print]
PMID:
21956345
[PubMed - as supplied by publisher]
Curious Results with Palladium- and Platinum-Carrying Polymers in Mass Cytometry Bioassays and an Unexpected Application as a Dead Cell Stain.
Majonis D, Ornatsky O, Kinach R, Winnik MA.
Biomacromolecules. 2011 Sep 28. [Epub ahead of print]
PMID:
21955116
[PubMed - as supplied by publisher]
Palladium Catalyzed Stereoselective C-Glycosylation of Glycals with Enol Triflates.
Bai Y, Leow M, Zeng J, Liu XW.
Org Lett. 2011 Sep 28. [Epub ahead of print]
PMID:
21954934
[PubMed - as supplied by publisher]
Palladium-Catalyzed Mono-N-allylation of Unprotected Anthranilic Acids with Allylic Alcohols in Aqueous Media.
Hikawa H, Yokoyama Y.
J Org Chem. 2011 Sep 29. [Epub ahead of print]
PMID:
21919524
[PubMed - as supplied by publisher]
Twin Plane Decoration of Silver Nanorods with Palladium by Galvanic Exchange at a Controlled Rate.
Slawinski GW, Ivanova OS, Zamborini FP.
Langmuir. 2011 Sep 28. [Epub ahead of print]
PMID:
21916478
[PubMed - as supplied by publisher]
Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via ?(3)-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization.
Peng B, Zhang S, Yu X, Feng X, Bao M.
Org Lett. 2011 Oct 7;13(19):5402-5. Epub 2011 Sep 13.
PMID:
21910509
[PubMed - in process]
Azadipyrromethene-Based Conjugated Oligomers with Near-IR Absorption and High Electron Affinity.
Gao L, Senevirathna W, Sauvé G.
Org Lett. 2011 Oct 7;13(19):5354-7. Epub 2011 Sep 12.
PMID:
21910458
[PubMed - in process]
Palladium-catalyzed approach to stereodefined ten-membered cycles from 1,5-bisallenes.
Cheng J, Jiang X, Ma S.
Org Lett. 2011 Oct 7;13(19):5200-3. Epub 2011 Sep 12.
PMID:
21910412
[PubMed - in process]
New Heteroannulation Reactions of N-Alkoxybenzamides by Pd(II) Catalyzed C-H Activation.
Wrigglesworth JW, Cox B, Lloyd-Jones GC, Booker-Milburn KI.
Org Lett. 2011 Oct 7;13(19):5326-9. Epub 2011 Sep 12.
PMID:
21910404
[PubMed - in process]
Pd(0)-catalyzed iodoalkynation of norbornene scaffolds: the remarkable solvent effect on reaction pathway.
Liu H, Chen C, Wang L, Tong X.
Org Lett. 2011 Oct 7;13(19):5072-5. Epub 2011 Sep 12.
PMID:
21910403
[PubMed - in process]
Palladium Catalyzed 1,8-Conjugate Addition to Heptafulvene via Bis-?-allyl Palladium Complexes.
George SC, Thulasi S, Anas S, Radhakrishnan KV, Yamamoto Y.
Org Lett. 2011 Oct 7;13(19):4984-7. Epub 2011 Sep 7.
PMID:
21899322
[PubMed - in process]
Hydride formation in single palladium and magnesium nanoparticles studied by nanoplasmonic dark-field scattering spectroscopy.
Shegai T, Langhammer C.
Adv Mater. 2011 Oct 11;23(38):4409-14. doi: 10.1002/adma.201101976. Epub 2011 Sep 5. No abstract available.
PMID:
21898608
[PubMed - in process]
Cross-coupling of mesylated phenol derivatives with potassium cyclopropyltrifluoroborate.
Molander GA, Beaumard F, Niethamer TK.
J Org Chem. 2011 Oct 7;76(19):8126-30. Epub 2011 Sep 2.
PMID:
21888362
[PubMed - in process]
Palladium-catalyzed regioselective C-s bond cleavage of thiophenes.
Huang H, Li J, Lescop C, Duan Z.
Org Lett. 2011 Oct 7;13(19):5252-5. Epub 2011 Sep 2.
PMID:
21888338
[PubMed - in process]
Substrate-Directable Heck Reactions with Arenediazonium Salts. The Regio- and Stereoselective Arylation of Allylamine Derivatives and Applications in the Synthesis of Naftifine and Abamines.
Prediger P, Barbosa LF, Ge?nisson Y, Correia CR.
J Org Chem. 2011 Oct 7;76(19):7737-7749. Epub 2011 Sep 15.
PMID:
21877731
[PubMed - as supplied by publisher]
Palladium Acetate is a moderately water soluble crystalline Palladium source that decomposes to Palladium oxide on heating. It is generally immediately available in most volumes. Acetates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic acetates are inorganic salts of a metal cation and the acetate anion. The acetate anion is a univalent (-1 charge) polyatomic ion composed of two carbon atoms ionically bound to three hydrogen and two oxygen atoms (Symbol: CH3COO) for a total formula weight of 59.05. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Palladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the platinum group of metals. It is an excellent hydrogenation and 
dehydrogenation
catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other platinum group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Platinum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.
