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(Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III)
[(C6H5)3P]2Re(CH3CN)Cl3
34387-57-0
Product Product Code Order or Specifications
(2N) 99% (Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III)      RE-OM-02 Contact American Elements
(3N) 99.9% (Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III) RE-OM-03 Contact American Elements
(4N) 99.99% (Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III) RE-OM-04 Contact American Elements
(5N) 99.999% (Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III) RE-OM-05 Contact American Elements
(Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III) is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Rhenium(Re) atomic and molecular weight, atomic number and elemental symbol Rhenium is a Block D, Group 7, Period 6 element. The number of electrons in each of Rhodium's shells is 2, 8, 18, 32, 13, 2 and its electronic configuration is [Xe] 4f14 5d5 6s2. In its Rhenium Bohr Model elemental form rhenium's CAS number is 7440-15-5. The rhenium atom has a radius of 137.1.pm and it's Van der Waals radius is 200.pm. The toxicity of Rhenium has not yet been established . Rhenium is the fourth densestelementexceeded only by that of platinum, iridium, and osmium . It has the second highest melting point exceeded only by tungsten and carbon . Rhenium is available as metal and Elemental Rheniumcompounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Because of this, thermocouples made of Tungsten/Rhenium alloy is are used when temperatures will rise to 2000 C and rhenium wire is used in photoflash lamps for photography. It is widely used as filaments for mass spectrographs and ion gauges. Rhenium was first discovered by Walter Noddack in 1925 in the Rhine region of Germany. The name Rhenium originates from the Latin word 'Rhenus' meaning "Rhine" after the place of discovery. See Rhenium research below.

Formula CAS No. Appearance Molecular Weight
[(C6H5)3P]2Re(CH3CN)Cl3 34387-57-0   858.19
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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

 

 

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Recent Research & Development for Rhenium

  • An Unsupported Uranium-Rhenium Complex Prepared by Alkane Elimination. Gardner BM, McMaster J, Moro F, Lewis W, Blake AJ, Liddle ST. Chemistry. 2011 May 6. doi: 10.1002/chem.201100682. [Epub ahead of print] No abstract available. PMID: 21557365 [PubMed - as supplied by publisher]

  • Rhenium-Catalyzed Regio- and Stereoselective Addition of Two Carbon Units to Terminal Alkynes via Carbon-Carbon Bond Cleavage of ß-Keto Sulfones. Kuninobu Y, Matsuzaki H, Nishi M, Takai K. Org Lett. 2011 May 9. [Epub ahead of print] PMID: 21553820 [PubMed - as supplied by publisher]

  • Novel rhenium(i) catalysts for the isomerization of propargylic alcohols into a,ß-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids. García-Álvarez J, Díez J, Gimeno J, Seifried CM. Chem Commun (Camb). 2011 May 9. [Epub ahead of print] PMID: 21552615 [PubMed - as supplied by publisher]

  • Investigation on the removal of Mo(VI) from Mo-Re containing wastewater by chemically modified persimmon residua. Xiong Y, Chen C, Gu X, Biswas BK, Shan W, Lou Z, Fang D, Zang S. Bioresour Technol. 2011 Apr 21. [Epub ahead of print] PMID: 21550234 [PubMed - as supplied by publisher]

  • Diammonium hexakis(thiocyanato-?N)rhenate(IV) dimethyl sulfone tetrasolvate. Kochel A, Holynska M. Acta Crystallogr C. 2011 May;67(Pt 5):m134-6. Epub 2011 Apr 14. PMID: 21540528 [PubMed - in process]

  • The tolerance and therapeutic efficacy of rhenium-188 hydroxyethylidene diphosphonate in advanced cancer patients with painful osseous metastases. Cheng A, Chen S, Zhang Y, Yin D, Dong M. Cancer Biother Radiopharm. 2011 Apr;26(2):237-44. PMID: 21539455 [PubMed - in process]

  • Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene. Azhakar R, Sarish SP, Roesky HW, Hey J, Stalke D. Inorg Chem. 2011 May 3. [Epub ahead of print] PMID: 21539353 [PubMed - as supplied by publisher]

  • (1)H and (13)C solution- and solid-state NMR investigation into wax products from the Fischer-Tropsch process. Speight RJ, Rourke JP, Wong A, Barrow NS, Ellis PR, Bishop PT, Smith ME. Solid State Nucl Magn Reson. 2011 Apr 14. [Epub ahead of print] PMID: 21536414 [PubMed - as supplied by publisher]

  • What patient, joint and isotope characteristics influence the response to radiosynovectomy in patients with haemophilia? DE LA Corte-Rodriguez H, Rodriguez-Merchan EC, Jimenez-Yuste V. Haemophilia. 2011 Apr 27. doi: 10.1111/j.1365-2516.2011.02546.x. [Epub ahead of print] PMID: 21535325 [PubMed - as supplied by publisher]

  • Investigation of Mixed Oxidation State Cyanide-Bridged Re(V)Oxo (acac(2)en/pn) and Re(I)(bipy)(CO)(3) Complexes. Moore AL, Twamley B, Barnes CL, Benny PD. Inorg Chem. 2011 May 2. [Epub ahead of print] PMID: 21534538 [PubMed - as supplied by publisher]

  • Direct intratumoral infusion of liposome encapsulated rhenium radionuclides for cancer therapy: effects of nonuniform intratumoral dose distribution. Hrycushko BA, Li S, Goins B, Otto RA, Bao A. Med Phys. 2011 Mar;38(3):1339-47. PMID: 21520844 [PubMed - in process]

  • Rhenium in Homogeneous Catalysis: [ReBrH(NO)(labile ligand)(large-bite-angle diphosphine)] Complexes as Highly Active Catalysts in Olefin Hydrogenations. Dudle B, Rajesh K, Blacque O, Berke H. J Am Chem Soc. 2011 May 11. [Epub ahead of print] PMID: 21517108 [PubMed - as supplied by publisher]

  • Synthesis, Functionalization, Characterization, and Photophysical Study of Carbonyl-Containing Isocyano Rhenium(I) Diimine Complexes. Cheung AW, Lo LT, Ko CC, Yiu SM. Inorg Chem. 2011 Apr 25. [Epub ahead of print] PMID: 21517013 [PubMed - as supplied by publisher]

  • Photoswitching tetranuclear rhenium(i) tricarbonyl diimine complexes with a stilbene-like bridging ligand. Lin JL, Chen CW, Sun SS, Lees AJ. Chem Commun (Camb). 2011 Apr 21. [Epub ahead of print] PMID: 21509379 [PubMed - as supplied by publisher]

  • Covalent Attachment of a Rhenium Bipyridyl CO(2) Reduction Catalyst to Rutile TiO(2). Anfuso CL, Snoeberger RC, Ricks AM, Liu W, Xiao D, Batista VS, Lian T. J Am Chem Soc. 2011 May 11;133(18):6922-5. Epub 2011 Apr 19. PMID: 21504161 [PubMed - in process]

  • Influence of MIL-101 Doping by Ionic Clusters on Hydrogen Storage Performance up to 1900 Bar. Klyamkin SN, Berdonosova EA, Kogan EV, Kovalenko KA, Dybtsev DN, Fedin VP. Chem Asian J. 2011 Apr 15. doi: 10.1002/asia.201000871. [Epub ahead of print] PMID: 21500356 [PubMed - as supplied by publisher]

  • Synthesis, structure, photophysical and electrochemiluminescence properties of Re(i) tricarbonyl complexes incorporating pyrazolyl-pyridyl-based ligands. Wei QH, Xiao FN, Han LJ, Zeng SL, Duan YN, Chen GN. Dalton Trans. 2011 May 14;40(18):5078-85. Epub 2011 Mar 31. PMID: 21451882 [PubMed - in process]

  • Rhenium(iv) compounds inducing apoptosis in cancer cells. Martínez-Lillo J, Mastropietro TF, Lappano R, Madeo A, Alberto ME, Russo N, Maggiolini M, De Munno G. Chem Commun (Camb). 2011 May 14;47(18):5283-5. Epub 2011 Mar 29. PMID: 21448489 [PubMed - in process]

  • Reactivity of 17 e(-) Complex [Re(II)Br(4)(CO)(2)](2-) with Bridging Aromatic Ligands. Characterization and CO-Releasing Properties. Zobi F, Blacque O. Dalton Trans. 2011 May 14;40(18):4994-5001. Epub 2011 Mar 28. PMID: 21442117 [PubMed - in process]

  • Preparation, Characterization, and Screening of a High Affinity Organometallic Probe for a-Adrenergic Receptors. Louie AS, Vasdev N, Valliant JF. J Med Chem. 2011 May 12;54(9):3360-7. Epub 2011 Apr 13. PMID: 21428421 [PubMed - in process]

     

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