Samarium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.
Samarium is primarily utilized in the production of samarium-cobalt (Sm2Co17) permanent magnets. Samarium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is also used in laser applications and for its dielectric properties. Samarium-cobalt magnets replaced the more expensive platinum-cobalt magnets in the early 1970s. While now overshadowed by the less expensive neodymium-iron-boron magnet, they are still valued for their ability to function at high temperatures. They are utilized in lightweight electronic equipment where size or space is a limiting factor and where functionality at high temperature is a concern. Applications include electronic watches, aeospace equipment, microwave technology and servomotors. Because of its weak spectral absorption band samarium is used in the filter glass on Nd:YAG solid state lasers to surround the laser rod to improve efficiency by absorbing stray emissions. Samarium forms stable titanate compounds with useful dielectric properties suitable for coatings and in capacitors at microwave frequencies.
Samarium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.
Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Samarium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.
Samarium is a Block F, Group 3, Period 6 element. The number of electrons in each of Samarium's shells is 2, 8, 18, 24, 8, 2 and its electronic configuration is [Xe]4f6 6s2. In its elemental form samarium's CAS number is 7440-19-9. The samarium atom has a radius of 180.4.pm and it's Van der Waals radius is unknown. Samarium is somewhat toxic. Samarium is primarily utilized in the production of samarium-cobalt (Sm2Co17) permanent magnets. Samarium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is also used in laser applications and for its dielectric properties. Samarium-cobalt magnets replaced the more expensive platinum-cobalt magnets in the early 1970s. While now overshadowed by the less expensive neodymium-iron-boron magnet, they are still valued for their ability to function at high temperatures. They are utilized in lightweight electronic equipment where size or space is a limiting factor and where functionality at high temperature is a concern. Applications include electronic watches, aeospace equipment, microwave technology and servomotors. Samarium was first discovered by Paul Emile Lecoq de Boisbaudran in 1879. Samarium is named aftssssser the mineral samarskite. See Samarium research below.
All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, thin fillm deposition using sputtering targets and evaporation materials, metallurgy and optical materials and other high technology applications. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Samarium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.
Samarium was first discovered by Paul Emile Lecoq de Boisbaudran in 1879.
Samarium is named after the
mineral samarskite.
samarium |
Samarium |
samario |
Samário |
samario |
Samarium |
Samarium Abundance. The following table shows the abundance of Samarium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.
| Isotope |
Atomic Mass |
% Abundance on Earth |
| Sm-144 |
143.912 |
3.1 |
| Sm-147 |
146.915 |
15.0 |
| Sm-148 |
147.915 |
11.3 |
| Sm-149 |
148.917 |
13.8 |
| Sm-150 |
149.917 |
7.4 |
| Sm-152 |
151.920 |
26.7 |
| Sm-154 |
153.922 |
22.7 |
The following table shows the abundance of Samarium present in the human body and in the universe scaled to parts per billion (ppb) by weight and by atom:
| |
Typical Human Body |
Universe |
| by Weight |
no data |
5 ppb |
| by Atom |
no data |
0.04 ppb |
Samarium Safety Data and Biological Role. The safety data for Samarium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin. Samarium compounds have no biological role.
Ionization Energy. The ionization energy for Samarium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:
| 1st Ionization Energy |
544.53 kJ mol-1 |
| 2nd Ionization Energy |
1068.10 kJ mol-1 |
| 3rd Ionization Energy |
2257.77 kJ mol-1 |
Conductivity. As to Samarium's electrical and thermal conductivity, the electrical conductivity measured in terms of electrical resistivity @ 20 ºC is 88 µOcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.17. The thermal conductivity of Samarium is 13.3 W m-1 K-1.
Thermal Properties of Samarium. The melting point and boiling point for Samarium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.
| Heat of Fusion |
10.9 kJ mol-1 |
| Heat of Vaporization |
164.8 kJ mol-1 |
| Heat of Atomization |
206.1 kJ mol-1 |
Recent Research & Development for SamariumSelective separation of samarium(III) by synergistic extraction with ß-diketone and methylphenylphenanthroline carboxamide.
Hasegawa Y, Tamaki S, Yajima H, Hashimoto B, Yaita T.
Talanta. 2011 Sep 15;85(3):1543-8. Epub 2011 Jun 21.
PMID:
21807220
[PubMed - in process]
Integral Stereocontrolled Synthesis of a Spiro-norlignan, Sequosempervirin A: Revision of Absolute Configuration.
Ito Y, Takahashi K, Nagase H, Honda T.
Org Lett. 2011 Aug 1. [Epub ahead of print]
PMID:
21805972
[PubMed - as supplied by publisher]
Interactions between metal ions and carbohydrates. Syntheses and spectroscopic studies of several lanthanide nitrate-d-galactitol complexes.
Yu L, Hua X, Pan Q, Yang L, Xu Y, Zhao G, Wang H, Wang H, Wu J, Liu K, Chen J.
Carbohydr Res. 2011 Jun 30. [Epub ahead of print]
PMID:
21784418
[PubMed - as supplied by publisher]
Chemical synthesis and evaluation of 17a-alkylated derivatives of estradiol as inhibitors of steroid sulfatase.
Fournier D, Poirier D.
Eur J Med Chem. 2011 Jun 28. [Epub ahead of print]
PMID:
21782294
[PubMed - as supplied by publisher]
Concise Syntheses of Strychnine and Englerin A: the Power of Reductive Cyclizations Triggered by Samarium Iodide.
Szostak M, Procter DJ.
Angew Chem Int Ed Engl. 2011 Jul 20. doi: 10.1002/anie.201103128. [Epub ahead of print] No abstract available.
PMID:
21780264
[PubMed - as supplied by publisher]
Preparation and Quality Control of the [Sm]-Samarium Maltolate Complex as a Lanthanide Mobilization Product in Rats.
Naseri Z, Hakimi A, Jalilian AR, Nemati Kharat A, Bahrami-Samani A, Ghannadi-Maragheh M.
Sci Pharm. 2011 Jun;79(2):265-275. Epub 2011 Feb 24.
PMID:
21773065
[PubMed - as supplied by publisher]
Synthesis and characterization of heterobimetallic oxo-bridged aluminum-rare Earth metal complexes.
Hao J, Li J, Cui C, Roesky HW.
Inorg Chem. 2011 Aug 15;50(16):7453-9. Epub 2011 Jul 15.
PMID:
21761836
[PubMed - in process]
Novel Supramolecular Assemblies Based on Coordination of Samarium Cation to Cucurbit[5]uril.
Chen K, Liang LL, Zhang YQ, Zhu QJ, Xue SF, Tao Z.
Inorg Chem. 2011 Aug 15;50(16):7754-60. Epub 2011 Jul 15.
PMID:
21761833
[PubMed - in process]
Total Synthesis of 10-Isocyano-4-cadinene and Its Stereoisomers and Evaluations of Antifouling Activities.
Nishikawa K, Nakahara H, Shirokura Y, Nogata Y, Yoshimura E, Umezawa T, Okino T, Matsuda F.
J Org Chem. 2011 Jul 26. [Epub ahead of print]
PMID:
21755975
[PubMed - as supplied by publisher]
Tris[6-meth-oxy-2-(phenyl-iminiometh-yl)phenolato]-?O,O';?O-tris-(thio-cyanato-?N)samarium(III).
Ge GD, Shen JB, Zhao GL.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m706-7. Epub 2011 May 7.
PMID:
21754608
[PubMed]
{µ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methanylyl-idene)]di-phenolato}dimethano-ltrinitrato-samarium(III)zinc(II) methanol disolvate.
Liu F, Zhang F.
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m525. Epub 2011 Apr 7.
PMID:
21754267
[PubMed]
Samarium Diiodide Induced Cyclizations of ?-, d- and e-Indolyl Ketones: Reductive Coupling, Intermolecular Trapping, and Subsequent Transformations of Indolines.
Beemelmanns C, Lentz D, Reissig HU.
Chemistry. 2011 Jul 8. doi: 10.1002/chem.201100981. [Epub ahead of print]
PMID:
21744405
[PubMed - as supplied by publisher]
177Lu-Labeled methylene diphosphonate.
Chopra A.
Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2011.
2011 May 24 [updated 2011 Jun 30].
PMID:
21735586
[PubMed]
Radioisotopes for metastatic bone pain.
Roqué I Figuls M, Martinez-Zapata MJ, Scott-Brown M, Alonso-Coello P.
Cochrane Database Syst Rev. 2011 Jul 6;(7):CD003347. Review.
PMID:
21735393
[PubMed - indexed for MEDLINE]
Cubic and doubly-fused cubic samarium clusters from Sm(ii)-mediated reduction of organic azides and azobenzenes.
Pan CL, Chen W, Su S, Pan YS, Wang J.
Dalton Trans. 2011 Aug 21;40(31):7941-5. Epub 2011 Jun 30.
PMID:
21717024
[PubMed - in process]
ACR-ASTRO Practice Guideline for the Performance of Therapy With Unsealed Radiopharmaceutical Sources.
Henkin RE, Del Rowe JD, Grigsby PW, Hartford AC, Jadvar H, Macklis RM, Parker JA, Wong JY, Rosenthal SA.
Clin Nucl Med. 2011 Aug;36(8):e72-e80.
PMID:
21716005
[PubMed - as supplied by publisher]
Synthesis and molecular structure of piperazidine-bridged bis(phenolate) samarium(ii) complex and its reactivity to carbodiimides.
Du Z, Zhang Y, Yao Y, Shen Q.
Dalton Trans. 2011 Aug 7;40(29):7639-44. Epub 2011 Jun 24.
PMID:
21701733
[PubMed - in process]
Theoretical Treatment of Redox Processes Involving Lanthanide(II) Compounds: Reactivity of Organosamarium(II) and Organothulium(II) Complexes with CO(2) and Pyridine.
Labouille S, Nief F, Maron L.
J Phys Chem A. 2011 Jul 28;115(29):8295-8301. Epub 2011 Jul 6.
PMID:
21675778
[PubMed - as supplied by publisher]
177Lu-Labeled ethylenediamine tetramethylene phosphonic acid.
Chopra A.
Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2011.
2011 Apr 28 [updated 2011 May 26].
PMID:
21656987
[PubMed]
[170Tm]-Labeled ethylenediamine tetramethylene phosphonic acid.
Chopra A.
Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2011.
2011 Apr 27 [updated 2011 May 26].
PMID:
21656985
[PubMed] |
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