Rhodium Telluride (RhTe) is a crystal grown product generally immediately available in most volumes. Technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Rhodium is a Block D, Group 9, Period 5 element. The number of electrons in each of Rhodium's shells is 2, 8, 18, 16, 1 and its electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm. Rhodium is not toxic. Rhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density.
It is alloyed with platinum and palladium in electrodes for spark plugs, advanced laboratory equipment and in thermocouples. Rhodium compounds also have catalytic uses in automotive catalytic converters. Rhodium is used as a plating metal in jewelry production to enhance the whiteness of white gold. Rhodium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Rhodium was first discovered by William Wollaston in 1803. The name Rhodium, originates from the Greek word 'Rhodon' which means rose. See Rhodium research below.
Tellurium is a Block P, Group 16, Period 5 element. The number of electrons in each of Tellurium's shells is 2, 8, 18, 18, 6 and its electronic configuration is [Kr] 4d10 5s2 5p4. In its elemental form tellurium's CAS number is 13494-80-9. The tellurium atom has a radius of 143.2.pm and it's Van der Waals radius is 206.pm. Tellurium is a p-type semiconductor, and shows greater conductivity in certain directions, depending on alignment of the atoms. It is grown in crystalline form with other elements such as indium telluride. Its conductivity increases slightly with exposure to light which makes many tellurides candidates for solar energyapplications. Tellurium improves the machinability of copper and stainless steel, and its addition to lead decreases the corrosive action of sulfuric acid on lead and improves its strength and hardness. Tellurium is used as a basic ingredient in blasting caps, and is added to cast iron for chill control. Tellurium is used in ceramics. Bismuth telluride has been used in thermoelectric devices. Iron is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Tellurium was first discovered by Franz Muller von Reichenstein in 1782. The name Tellurium originates from the Greek word 'Tellus' meaning Earth. See Tellurium research below.
American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:
Crystal "pulling" by the Czochaiski method for production of semiconductor materials
Flux growth and gradient freeze
Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Intramolecular Aromatic Carbenoid Insertion of Biaryldiazoacetates for the Regioselective Synthesis of Fluorenes.
Kim J, Ohk Y, Park SH, Jung Y, Chang S.
Chem Asian J. 2011 May 12. doi: 10.1002/asia.201100142. [Epub ahead of print]
PMID:
21567971
[PubMed - as supplied by publisher]
Rhodium-Catalyzed Cycloisomerization Involving Cyclopropenes: Efficient Stereoselective Synthesis of Medium-Sized Heterocyclic Scaffolds.
Miege F, Meyer C, Cossy J.
Angew Chem Int Ed Engl. 2011 May 12. doi: 10.1002/anie.201101220. [Epub ahead of print] No abstract available.
PMID:
21567678
[PubMed - as supplied by publisher]
Allylic C-H bond activation and functionalization mediated by tris(oxazolinyl)borato rhodium(i) and iridium(i) compounds.
Ho HA, Gray TS, Baird B, Ellern A, Sadow AD.
Dalton Trans. 2011 May 12. [Epub ahead of print]
PMID:
21566811
[PubMed - as supplied by publisher]
Inter- and intramolecular hydroacylation of alkenes employing a bifunctional catalyst system.
Vautravers NR, Regent DD, Breit B.
Chem Commun (Camb). 2011 May 12. [Epub ahead of print]
PMID:
21566809
[PubMed - as supplied by publisher]
Carbon Chain Growth by Formyl Insertion on Rhodium and Cobalt Catalysts in Syngas Conversion.
Zhao YH, Sun K, Ma X, Liu J, Sun D, Su HY, Li WX.
Angew Chem Int Ed Engl. 2011 May 6. doi: 10.1002/anie.201100735. [Epub ahead of print] No abstract available.
PMID:
21557417
[PubMed - as supplied by publisher]
Synthesis, Characterisation and Application of Iridium(III) Photosensitisers for Catalytic Water Reduction.
Gärtner F, Cozzula D, Losse S, Boddien A, Anilkumar G, Junge H, Schulz T, Marquet N, Spannenberg A, Gladiali S, Beller M.
Chemistry. 2011 May 6. doi: 10.1002/chem.201100235. [Epub ahead of print]
PMID:
21557356
[PubMed - as supplied by publisher]
Analysis of Tertiary Phosphanes, Arsanes, and Stibanes as Bridging Ligands in Dinuclear Group 9 Complexes.
Schinzel S, Müller R, Riedel S, Werner H, Kaupp M.
Chemistry. 2011 May 9. doi: 10.1002/chem.201003438. [Epub ahead of print]
PMID:
21557345
[PubMed - as supplied by publisher]
Asymmetric hydrogenation of alkenes lacking coordinating groups.
Woodmansee DH, Pfaltz A.
Chem Commun (Camb). 2011 May 10. [Epub ahead of print]
PMID:
21556431
[PubMed - as supplied by publisher]
Ionic Diamine Rhodium Complex Catalyzed Reductive N-Heterocyclization of 2-Nitrovinylarenes.
Alper H, Okuro K, Gurnham J.
J Org Chem. 2011 May 4. [Epub ahead of print]
PMID:
21542601
[PubMed - as supplied by publisher]
trans-Carbonylchloridobis(ferrocenyldiphenylphosphane-?P)rhodium(I) dichloromethane monosolvate and trans-carbonylchloridobis(ferrocenyldiphenylphosphane-?P)iridium(I) dichloromethane monosolvate.
Muller A, Otto S.
Acta Crystallogr C. 2011 May;67(Pt 5):m165-8. Epub 2011 Apr 28.
PMID:
21540536
[PubMed - in process]
A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides.
Serna P, Gates BC.
Angew Chem Int Ed Engl. 2011 Apr 29. doi: 10.1002/anie.201008086. [Epub ahead of print] No abstract available.
PMID:
21538737
[PubMed - as supplied by publisher]
Asymmetric polymerizations of chiral 4-benzyl-2-ethynyloxazoline with rhodium catalyst and chiroptical properties of the polymers.
Onimura K, Shintaku K, Rattanatraicharoen P, Yamabuki K, Oishi T.
Chirality. 2011 Apr 28. doi: 10.1002/chir.20959. [Epub ahead of print]
PMID:
21538572
[PubMed - as supplied by publisher]
Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines.
Shintani R, Narui R, Tsutsumi Y, Hayashi S, Hayashi T.
Chem Commun (Camb). 2011 May 3. [Epub ahead of print]
PMID:
21537505
[PubMed - as supplied by publisher]
Synthesis and characterisation of group nine transition metal complexes containing new mesityl and naphthyl based azaindole scorpionate ligands.
Owen GR, Tsoureas N, Hope RF, Kuo YY, Haddow MF.
Dalton Trans. 2011 Apr 28. [Epub ahead of print]
PMID:
21528139
[PubMed - as supplied by publisher]
Screen-printed carbon electrodes modified by rhodium dioxide and glucose dehydrogenase.
Polan V, Soukup J, Vytras K.
Enzyme Res. 2011 Mar 3;2010:324184.
PMID:
21528113
[PubMed - in process]
Computationally Designed and Experimentally Confirmed Diastereoselective Rhodium-Catalyzed Pauson-Khand Reaction at Room Temperature.
Baik MH, Mazumder S, Ricci P, Sawyer JR, Song YG, Wang H, Evans PA.
J Am Chem Soc. 2011 Apr 27. [Epub ahead of print]
PMID:
21524123
[PubMed - as supplied by publisher]
An Atom-Economic Synthesis of Bicyclo[3.1.0]hexanes by Rhodium N-Heterocyclic Carbene-Catalyzed Diastereoselective Tandem Hetero-[5 + 2] Cycloaddition/Claisen Rearrangement Reaction of Vinylic Oxiranes with Alkynes.
Feng JJ, Zhang J.
J Am Chem Soc. 2011 May 18;133(19):7304-7. Epub 2011 Apr 27.
PMID:
21524076
[PubMed - in process]
Supported Rhodium Oxide Nanoparticles as Highly Active CO Oxidation Catalysts.
Ligthart DA, van Santen RA, Hensen EJ.
Angew Chem Int Ed Engl. 2011 Apr 20. doi: 10.1002/anie.201100190. [Epub ahead of print] No abstract available.
PMID:
21509919
[PubMed - as supplied by publisher]
Thermal diffusion of (57)Co into rhodium matrix as a second step in preparing Mössbauer sources.
Cieszykowska I, Zóltowska M, Zachariasz P, Piasecki A, Janiak T, Mielcarski M.
Appl Radiat Isot. 2011 Apr 8. [Epub ahead of print]
PMID:
21507667
[PubMed - as supplied by publisher]
Rhodium-Catalyzed Branched-Selective Alkyne Hydroacylation: A Ligand-Controlled Regioselectivity Switch.
González-Rodríguez C, Pawley RJ, Chaplin AB, Thompson AL, Weller AS, Willis MC.
Angew Chem Int Ed Engl. 2011 Apr 19. doi: 10.1002/anie.201100956. [Epub ahead of print] No abstract available.
PMID:
21506226
[PubMed - as supplied by publisher]
Bulk and Surface Structure and High-Temperature Thermoelectric Properties of Inverse Clathrate-III in the Si-P-Te System.
Zaikina JV, Mori T, Kovnir K, Teschner D, Senyshyn A, Schwarz U, Grin Y, Shevelkov AV.
Chemistry. 2010 Oct 13. [Epub ahead of print]PMID: 20945448 [PubMed - as supplied by publisher]Related citations
Tellurium dioxide Erbium doped planar rib waveguide amplifiers with net gain and 2.8 dB/cm internal gain.
Vu K, Madden S.
Opt Express. 2010 Aug 30;18(18):19192-200. doi: 10.1364/OE.18.019192.PMID: 20940815 [PubMed - in process]Related citations
Water-Processable Polymer-Nanocrystal Hybrids for Thermoelectrics.
See KC, Feser JP, Chen CE, Majumdar A, Urban JJ, Segalman RA.
Nano Lett. 2010 Oct 5. [Epub ahead of print]PMID: 20923178 [PubMed - as supplied by publisher]Related citations
Methylated Metal(loid) Species in Humans.
Hirner AV, Rettenmeier AW.
Met Ions Life Sci. 2010;7:465-521. Epub 2010 Jan 30.PMID: 20877816 [PubMed - in process]Free ArticleRelated citations
Formation, occurrence, significance, and analysis of organoselenium and organotellurium compounds in the environment.
Wallschläger D, Feldmann J.
Met Ions Life Sci. 2010;7:319-64. Epub 2010 Jan 30.PMID: 20877812 [PubMed - in process]Free ArticleRelated citations
Dicationic Tellurium Analogues of the Classic N-Heterocyclic Carbene.
Dutton JL, Ragogna PJ.
Chemistry. 2010 Sep 16. [Epub ahead of print]PMID: 20848623 [PubMed - as supplied by publisher]Related citations
Tellurite-induced carbonylation of the Escherichia coli pyruvate dehydrogenase multienzyme complex.
Contreras Ndel P, Vásquez CC.
Arch Microbiol. 2010 Nov;192(11):969-73. Epub 2010 Sep 7.PMID: 20821193 [PubMed - in process]Related citations
Seebeck tuning in chalcogenide nanoplate assemblies by nanoscale heterostructuring.
Mehta RJ, Karthik C, Singh B, Teki R, Borca-Tasciuc T, Ramanath G.
ACS Nano. 2010 Sep 28;4(9):5055-60.PMID: 20812700 [PubMed - in process]Related citations
Inhibition of creatine kinase activity by 3-butyl-1-phenyl-2-(phenyltelluro)oct-en-1-one in the cerebral cortex and cerebellum of young rats.
de Andrade RB, Gemelli T, Guerra RB, Funchal C, Wannmacher CM.
J Appl Toxicol. 2010 Aug;30(6):611-6.PMID: 20809551 [PubMed - in process]Related citations
Tellurium: an element with great biological potency and potential.
Ba LA, Döring M, Jamier V, Jacob C.
Org Biomol Chem. 2010 Oct 7;8(19):4203-16. Epub 2010 Aug 17.PMID: 20714663 [PubMed - in process]Related citations
Hypervalent adducts of chalcogen-containing peri-substituted naphthalenes; reactions of sulfur, selenium, and tellurium with dihalogens.
Knight FR, Fuller AL, Bühl M, Slawin AM, Woollins JD.
Inorg Chem. 2010 Aug 16;49(16):7577-96.PMID: 20690768 [PubMed - in process]Related citations
Speciation and determination of ultra trace amounts of inorganic tellurium in environmental water samples by dispersive liquid-liquid microextraction and electrothermal atomic absorption spectrometry.
Najafi NM, Tavakoli H, Alizadeh R, Seidi S.
Anal Chim Acta. 2010 Jun 18;670(1-2):18-23. Epub 2010 May 2.PMID: 20685411 [PubMed - in process]Related citations
Selenium- and tellurium-containing multifunctional redox agents as biochemical redox modulators with selective cytotoxicity.
Jamier V, Ba LA, Jacob C.
Chemistry. 2010 Sep 24;16(36):10920-8.PMID: 20677196 [PubMed - in process]Related citations
Sulfate assimilation mediates tellurite reduction and toxicity in Saccharomyces cerevisiae.
Ottosson LG, Logg K, Ibstedt S, Sunnerhagen P, Käll M, Blomberg A, Warringer J.
Eukaryot Cell. 2010 Oct;9(10):1635-47. Epub 2010 Jul 30.PMID: 20675578 [PubMed - in process]Related citations
Metalloids, soil chemistry and the environment.
Lombi E, Holm PE.
Adv Exp Med Biol. 2010;679:33-44. Review.PMID: 20666222 [PubMed - indexed for MEDLINE]Related citations
Na(+), K (+) and Tl(+) hydration from QM/MM computations and MD simulations with a polarizable force field.
Lev BB, Salahub DR, Noskov SY.
Interdiscip Sci. 2010 Mar;2(1):12-20. Epub 2010 Jan 28.PMID: 20640793 [PubMed - indexed for MEDLINE]Related citations
Immunocompetence and alterations in hepatic gene expression in rainbow trout exposed to CdS/CdTe quantum dots.
Gagné F, Fortier M, Yu L, Osachoff HL, Skirrow RC, van Aggelen G, Gagnon C, Fournier M.
J Environ Monit. 2010 Aug 5;12(8):1556-65. Epub 2010 Jul 1.PMID: 20596552 [PubMed - in process]Related citations
Chalcogen chemistry of group(IV) closo-dodecaborates, synthesis, theory and coordination chemistry.
Dimmer JA, Hornung M, Weigend F, Wesemann L.
Dalton Trans. 2010 Aug 28;39(32):7504-12. Epub 2010 Jul 1.PMID: 20593101 [PubMed - in process]Related citations
New noncentrosymmetric tellurite phosphate material: synthesis, characterization, and calculations of Te2O(PO4)2.
Kim MK, Kim SH, Chang HY, Halasyamani PS, Ok KM.
Inorg Chem. 2010 Aug 2;49(15):7028-34.PMID: 20586470 [PubMed - in process]Related citations
An efficient one-pot synthesis of symmetrical diselenides or ditellurides from halides with CuO nanopowder/Se0 or Te0/base.
Singh D, Deobald AM, Camargo LR, Tabarelli G, Rodrigues OE, Braga AL.
Org Lett. 2010 Aug 6;12(15):3288-91.PMID: 20586442 [PubMed - in process]Related citations