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Bismuth(III) Molybdate

CAS #:

13595-85-2

Linear Formula:

Bi2(MoO4)3

MDL Number:

MFCD00064784

EC No.:

237-032-1

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Bismuth(III) Molybdate
BI3-MOAT-02-C Pricing > SDS > Data Sheet >
(3N) 99.9% Bismuth(III) Molybdate
BI3-MOAT-03-C Pricing > SDS > Data Sheet >
(4N) 99.99% Bismuth(III) Molybdate
BI3-MOAT-04-C Pricing > SDS > Data Sheet >
(5N) 99.999% Bismuth(III) Molybdate
BI3-MOAT-05-C Pricing > SDS > Data Sheet >
Question? Ask an American Elements EngineerWHOLESALE/SKU 0000-742-5550

Properties

Compound Formula

Bi2Mo3O12

Molecular Weight

897.77

Appearance

Gray crystals or yellow powder

Melting Point

643°C

Boiling Point

N/A

Density

5.9-6.07 g/cm3

Exact Mass

898.615703

Monoisotopic Mass

903.615967

Health & Safety Information

Signal Word Warning
Hazard Statements H373-H315-H319-H335
Hazard Codes Xn,Xi
Risk Codes 36/37/38
Safety Statements 22-25-26
RTECS Number N/A
Transport Information N/A
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/29/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Bismuth(III) Molybdate

Product Number: All applicable American Elements product codes, e.g. BI3-MOAT-02-C , BI3-MOAT-03-C , BI3-MOAT-04-C , BI3-MOAT-05-C

CAS #: 13595-85-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Not a hazardous substance or mixture.
GHS Label elements, including precautionary statements
Not a hazardous substance or mixture.
Hazards not otherwise classified (HNOC) or not covered by GHS-none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Formula: Bi2Mo3O12
Molecular Weight: 897.77 g/mol
CAS-No.: 13595-85-2
EC-No.: 237-032-1


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never
give anything by mouth to an unconscious person. Rinse mouth with water.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed: no data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Hydrogen iodide, Borane/boron oxides, Molybdenum oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing vapours, mist or gas.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures form preventive fire protection.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls
Appropriate engineering controls
General industrial hygiene practice.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: crystalline
Colour: grey
Odour
no data available
Odour Threshold
no data available
pH
no data available
Melting point/freezing point
Melting point/range: > 300 °C (> 572 °F)-lit.
Initial boiling point and boiling range
no data available
Flash point
not applicable
Evapouration rate
no data available
Flammability (solid, gas)
no data available
Upper/lower flammability or explosive limits
no data available
Vapour pressure
no data available
Vapour density
no data available
Relative density
5.950 g/cm3
Water solubility
insoluble
Partition coefficient: n-octanol/water
no data available
Auto-ignition temperature
no data available
Decomposition temperature
no data available
Viscosity
no data available
Explosive properties
no data available
Oxidizing properties
no data available
Other safety information
no data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products-no data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
no data available
Inhalation: no data available
Dermal:
no data available
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH:
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
no data available
Specific target organ toxicity -single exposure
no data available
Specific target organ toxicity -repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS:
Not available
Symptoms of chronic bismuth toxicity in humans consists of decreased appetite, weakness, rheumatic pain, diarrhea, fever, metal line on the gums, foul breathe, gingivitis, and dermatitis. Jaundice and conjunctival hemorrhage are rare, but have been reported. Bismuth nephropathy with proteinuria may occur. The kidney is the site of highest concentration with the liver being considerably lower. Bismuth does pass into the amniotic fluid and into the fetus., To
the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Stomach-Irregularities-Based on Human Evidence
Stomach-Irregularities-Based on Human Evidence


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
no data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302
Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312
Hazards
Chronic Health Hazard
Massachusetts Right To Know
Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know
Components
Dibismuth trimolybdenum dodecaoxide
CAS-No.13595-85-2
Revision Date
New Jersey Right To Know
Components
Dibismuth trimolybdenum dodecaoxide
CAS-No.13595-85-2
Revision Date
California Prop. 65
Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About

Molybdate IonBismuth Molybdate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Bismuth(3+) dioxido(dioxo)molybdenum (2:3), Bismuth molybdenum oxide, Molybdic acid bismuth(III) salt; dibismuth trimolybdenum dodecaoxide; dibismuth diketo(dioxido)molybdenum; dibismuth(3+) ion trimolybdate

Chemical Identifiers

Linear Formula

Bi2(MoO4)3

Pubchem CID

16213783

MDL Number

MFCD00064784

EC No.

237-032-1

Beilstein Registry No.

N/A

IUPAC Name

dibismuth; dioxido(dioxo) molybdenum

SMILES

[BiH3+3].[BiH3+3].[O-][Mo](=O)(=O)[O-].[O-][Mo]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O

InchI Identifier

InChI=1S/2Bi.3Mo.12O/q2*+3;;;;;;;;;;6*-1

InchI Key

DDGRELPQDWMXLU-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Bismuth products. Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental BismuthBismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass.

See more Molybdenum products. Molybdenum (atomic symbol: Mo, atomic number: 42) is a Block D, Group 6, Period 5 element with an atomic weight of 95.96. Molybdenum Bohr ModelThe number of electrons in each of molybdenum's shells is [2, 8, 18, 13, 1] and its electron configuration is [Kr] 4d5 5s1. The molybdenum atom has a radius of 139 pm and a Van der Waals radius of 209 pm. In its elemental form, molybdenum has a gray metallic appearance. Molybdenum was discovered by Carl Wilhelm in 1778 and first isolated by Peter Jacob Hjelm in 1781. Molybdenum is the 54th most abundant element in the earth's crust. Elemental MolybdenumIt has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum does not occur naturally as a free metal, it is found in various oxidation states in minerals. The primary commercial source of molybdenum is molybdenite, although it is also recovered as a byproduct of copper and tungsten mining. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead.

Recent Research

Sonochemical assisted hydrothermal synthesis of pseudo-flower shaped Bismuth vanadate (BiVO4) and their solar-driven water splitting application., Khan, Ibrahim, Ali Shahid, Mansha Muhammad, and Qurashi Ahsanulhaq , Ultrason Sonochem, 2017 May, Volume 36, p.386-392, (2017)

Functionally Graded Bismuth Oxide/Zirconia Bilayer Electrolytes for High-Performance Intermediate-Temperature Solid Oxide Fuel Cells (IT-SOFCs)., Joh, Dong Woo, Park Jeong Hwa, Kim Doyeub, Wachsman Eric D., and Lee Kang Taek , ACS Appl Mater Interfaces, 2017 Mar 15, Volume 9, Issue 10, p.8443-8449, (2017)

A novel bismuth oxychloride-graphene hybrid nanosheets based non-enzymatic photoelectrochemical glucose sensing platform for high performances., Gopalan, A I., Muthuchamy N, and Lee K P. , Biosens Bioelectron, 2017 Mar 15, Volume 89, Issue Pt 1, p.352-360, (2017)

Deep melting reveals liquid structural memory and anomalous ferromagnetism in bismuth., Shu, Yu, Yu Dongli, Hu Wentao, Wang Yanbin, Shen Guoyin, Kono Yoshio, Xu Bo, He Julong, Liu Zhongyuan, and Tian Yongjun , Proc Natl Acad Sci U S A, 2017 Mar 13, (2017)

Surface-active bismuth ferrite as superior peroxymonosulfate activator for aqueous sulfamethoxazole removal: Performance, mechanism and quantification of sulfate radical., Da Oh, Wen-, Dong ZhiLi, Ronn Goei, and Lim Teik-Thye , J Hazard Mater, 2017 Mar 05, Volume 325, p.71-81, (2017)

Bismuth nanoparticles-carbon nanotubes modified sensor for sulfasalazine analysis., Nigović, Biljana, Jurić Sandra, and Mitrović Iva , Talanta, 2017 Mar 01, Volume 164, p.201-208, (2017)

Potent anticancer activity of a new bismuth (III) complex against human lung cancer cells., Ouyang, Ruizhuo, Yang Yang, Tong Xiao, Feng Kai, Yang Yaoqin, Tao Huihong, Zhang Xiaoshen, Zong Tianyu, Cao Penghui, Xiong Fei, et al. , J Inorg Biochem, 2017 Mar, Volume 168, p.18-26, (2017)

The fabrication and thermal properties of bismuth-aluminum oxide nanothermometers., Wang, Chiu-Yen, Chen Shih-Hsun, Tsai Ping-Hsin, Chiou Chung-Han, and Hsieh Sheng-Jen , Nanotechnology, 2017 Jan 27, Volume 28, Issue 4, p.045705, (2017)

Synthesis and Characterisation of Reduced Graphene Oxide/Bismuth Composite for Electrodes in Electrochemical Energy Storage Devices., Wang, Jiabin, Zhang Han, Hunt Michael R. C., Charles Alasdair, Tang Jie, Bretcanu Oana, Walker David, Hassan Khalil T., Sun Yige, and Šiller Lidija , ChemSusChem, 2017 Jan 20, Volume 10, Issue 2, p.363-371, (2017)

Bismuth-catalyzed allylation of para-quinone methides., Zhang, Zhi-Pei, Dong Nan, and Li Xin , Chem Commun (Camb), 2017 Jan 19, Volume 53, Issue 7, p.1301-1304, (2017)

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March 29, 2017
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