Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)

Bi(TMHD)3

CAS #:

Linear Formula:

C33H57BiO6

MDL Number:

MFCD00064763

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
BI-TMHD3-02
Pricing > SDS > Data Sheet >
(2N5) 99.5% Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
BI-TMHD3-025
Pricing > SDS > Data Sheet >
(3N) 99.9% Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
BI-TMHD3-03
Pricing > SDS > Data Sheet >
(3N5) 99.95% Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
BI-TMHD3-035
Pricing > SDS > Data Sheet >
(4N) 99.99% Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
BI-TMHD3-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
BI-TMHD3-05
Pricing > SDS > Data Sheet >

Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) Properties (Theoretical)

Compound Formula C33H57BiO6
Molecular Weight 758.78
Appearance White Solid
Melting Point 89-116 °C
Boiling Point 150°C
Density N/A
Solubility in H2O N/A
Exact Mass 758.395913
Monoisotopic Mass 758.395913

Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) Health & Safety Information

Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes Xi
Risk Codes 36/37/38
Safety Statements 26-37
RTECS Number N/A
Transport Information N/A
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 06/15/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)

Product Number: All applicable American Elements product codes, e.g. BI-TMHD3-02 , BI-TMHD3-025 , BI-TMHD3-03 , BI-TMHD3-035 , BI-TMHD3-04 , BI-TMHD3-05

CAS #: 142617-53-6

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute oral toxicity Category 4
Acute dermal toxicity Category 4
Acute Inhalation Toxicity - Dusts and Mists Category 4
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system.
Label Elements
Signal Word
Warning
Hazard Statements
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
Harmful if swallowed, in contact with skin or if inhaled

Exclamation Mark - GHS07

Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
Skin
IF ON SKIN: Wash with plenty of soap and water
Call a POISON CENTER or doctor/physician if you feel unwell
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Storage
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component
Bismuth tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
CAS-No: 142617-53-6
Weight %: 97


SECTION 4. FIRST AID MEASURES

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Get medical attention.
Inhalation Remove from exposure, lie down. Remove to fresh air. If not breathing, give artificial
respiration. Get medical attention.
Ingestion Clean mouth with water. Get medical attention.
Most important symptoms and effects
No information available.
Notes to Physician Treat symptomatically


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media Water spray. Carbon dioxide (CO 2). Dry chemical. Chemical foam.
Unsuitable Extinguishing Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Keep product and empty container away from heat and sources of ignition.
Hazardous Combustion Products
Carbon monoxide (CO). Carbon dioxide (CO2).
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
NFPA
Health
2
Flammability
0
Instability
0
Physical hazards
N/A


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required.
Environmental Precautions See Section 12 for additional Ecological Information.
Methods for Containment and Clean Up
Sweep up and shovel into suitable containers for disposal.


SECTION 7. HANDLING AND STORAGE

Handling Avoid contact with skin and eyes. Do not breathe dust.
Storage Keep in a dry, cool and well-ventilated place. Refer product specification and/or product
label for specific storage temperature requirement. Keep container tightly closed. Keep
under nitrogen.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies.
Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Powder Solid
Appearance Off-white
Odor No information available
Odor Threshold No information available
pH No information available
Melting Point/Range 114 - 116 °C / 237.2 - 240.8 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula C33 H57 Bi O6
Molecular Weight 758.79


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard None known, based on information available
Stability Moisture sensitive. Air sensitive.
Conditions to Avoid Exposure to air. Incompatible products. Exposure to moist air or water.
Incompatible Materials Strong oxidizing agents
Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2)
Hazardous Polymerization No information available.
Hazardous Reactions None under normal processing.


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and
delayed
No information available
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Do not empty into drains.
Persistence and Degradability No information available
Bioaccumulation/ Accumulation No information available.
Mobility No information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT Not regulated
TDG Not regulated
IATA Not regulated
IMDG/IMO Not regulated


SECTION 15. REGULATORY INFORMATION

U.S. Federal Regulations
SARA 313 Not applicable
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
Clean Air Act Not applicable
OSHA - Occupational Safety and
Health Administration
Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know
Regulations
Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland
Security
This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)

Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) is one of numerous organo-metallic compounds (also known Organo-Metallic Packaging, Lab Quantity as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the trade name AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.

Bismuth Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) Synonyms

Bismuth(III)-DPM; Bi(TMHD)2; Bi(TMHD)3; (4Z, 4'Z, 4''Z)-5, 5', 5''-[Bismuthinetriyltris(oxy)]tris(2, 2, 6, 6-tetramethyl-4-hepten-3-one); Bismuth(III) tris(2, 2, 6, 6-tetramethyl-3, 5-heptanedionate); Tris(2, 2, 6, 6-tetramethyl-3, 5-heptanedionato)bismut

Chemical Identifiers

Linear Formula C33H57BiO6
MDL Number MFCD00064763
EC No. N/A
Pubchem CID 16717622
IUPAC Name (Z)-5-bis[[(Z)-2,2,6, 6-tetramethyl-5-oxohept-3-en-3-yl]oxy]bismuthanyloxy-2,2,6, 6-tetramethylhept-4-en-3-one
SMILES CC(C)(C)C(=CC(=O)C(C)(C)C)O[Bi](OC(=CC(=O)C(C)(C)C)C(C)(C)C)OC(=CC(=O)C(C)(C)C)zC(C)(C)C
InchI Identifier InChI=1S/3C11H20O2.Bi/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
InchI Key ZNHBPQSSVCRFST-LWTKGLMZSA-K

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Bismuth

See more Bismuth products. Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental BismuthBismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite. It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass.

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