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Palladium Nanoparticles

CAS #:

Linear Formula:

Pd

MDL Number:

MFCD00011167

EC No.:

231-115-6

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Palladium Nanoparticles
PD-M-02-NP
Pricing > SDS > Data Sheet >
(3N) 99.9% Palladium Nanoparticles
PD-M-03-NP
Pricing > SDS > Data Sheet >
(4N) 99.99% Palladium Nanoparticles
PD-M-04-NP
Pricing > SDS > Data Sheet >
(5N) 99.999% Palladium Nanoparticles
PD-M-05-NP
Pricing > SDS > Data Sheet >

Palladium Nanoparticles Properties

Molecular Weight

106.42

Appearance

Gray

Melting Point

1555 °C

Boiling Point

2963 °C

Crystal Phase / Structure

N/A

Thermal Expansion

N/A

Young's Modulus

N/A

Vickers Hardness

N/A

Poisson's Ratio

N/A

True Density

12.02 g/cm3

Bulk Density

N/A

Average Particle Size

N/A

Size Range

N/A

Specific Surface Area

N/A

Morphology

N/A

Palladium Nanoparticles Health & Safety Information

Signal Word Danger
Hazard Statements H228
Hazard Codes N/A
Precautionary Statements P210-P280-P240-P241-P370+P378
Risk Codes N/A
Safety Statements N/A
RTECS Number RT3480500
Transport Information UN 3089 4.1 / PGII
WGK Germany nwg
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 06/23/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Palladium Nanoparticles

Product Number: All applicable American Elements product codes, e.g. PD-M-02-NP , PD-M-03-NP , PD-M-04-NP , PD-M-05-NP

CAS #: 7440-05-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 Flame
Flam. Sol. 1 H228 Flammable solid.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
F; Highly flammable
R11: Highly flammable.
Information concerning particular hazards for human and environment:
Not applicable
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms

Flame - GHS02

GHS02
Signal word
Danger
Hazard statements
H228 Flammable solid.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
WHMIS classification
B4 - Flammable solid
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
1
3
1
Health (acute effects) = 1
Flammability = 3
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
7440-05-3 Palladium
Identification number(s):
EC number:
231-115-6


SECTION 4. FIRST AID MEASURES

Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing agents
Water
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Palladium oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow product to reach sewage system or any water course.
Do not allow to penetrate the ground/soil.
Methods and material for containment and cleaning up:
Keep away from ignition sources.
Ensure adequate ventilation.
Prevention of secondary hazards:
Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Information about storage in one common storage facility:
Do not store together with oxidizing and acidic materials.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes)
>480
Glove thickness
0.11 mm
Eye protection:
Safety glasses
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder
Color: Grey to silver
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 1555 °C (2831 °F)
Boiling point/Boiling range: 3167 °C (5733 °F)
Sublimation temperature / start: Not determined
Flammability (solid, gaseous)
Highly flammable.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure at 1400 °C (2552 °F): 0.0013 hPa
Density at 20 °C (68 °F): 12.02 g/cm³ (100.307 lbs/gal)
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Not determined
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No further relevant information available.
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Palladium oxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity
data for this substance.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity
data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN3089
UN proper shipping name
DOT
Metal powders, flammable, n.o.s. (Palladium powder)
IMDG, IATA
METAL POWDER, FLAMMABLE, N.O.S. (Palladium powder)
Transport hazard class(es)
DOT
Class
4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
Label
4.1
Class
4.1 (F3) Flammable solids, self-reactive substances and solid desensitised explosives
Label
4.1
IMDG, IATA
Class
4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
Label
4.1
Packing group
DOT, IMDG, IATA
II
Environmental hazards: Not applicable.
Special precautions for user
Warning: Flammable solids, self-reactive substances and solid desensitised explosives
EMS Number: F-G,S-G
Segregation groups
Heavy metals and their salts (including their organometallic compounds), powdered metals
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information: DOT
Marine Pollutant (DOT): No
UN "Model Regulation":
UN3089, Metal powders, flammable, n.o.s. (Palladium powder), 4.1, Il


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
REACH - Pre-registered substances
Substance is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Palladium Nanoparticles

High Purity, D50 = +10 nanometer (nm) by SEMPalladium (Pd) Nanoparticles, nanodots or nanopowder are black spherical high surface area metal particles. Nanoscale Palladium Particles are typically 20 - 100 nanometers (nm) with specific surface area (SSA) in the 1 - 3 m2/g range. Nano Palladium Particles are also available in Ultra high purity and high purity and coated and dispersed forms. They are also available as a dispersion through the AE Nanofluid production group. Nanofluids are generally defined as suspended nanoparticles in solution either using surfactant or surface charge technology. Nanofluid dispersion and coating selection technical guidance is also available. Other nanostructures include nanorods, nanowhiskers, nanohorns, nanopyramids and other nanocomposites. Surface functionalized nanoparticles allow for the particles to be preferentially adsorbed at the surface interface using chemically bound polymers.

Palladium Nanoparticles Synonyms

Palladium nanopowder, Palladium nanocrystals, Palladium nano-particles, Palladium nano-powder, nanopalladium, nano-palladium, 686468

Palladium Nanoparticles Chemical Identifiers

Linear Formula

Pd

Pubchem CID

23938

MDL Number

MFCD00011167

EC No.

231-115-6

Beilstein Registry No.

N/A

SMILES

[Pd]

InchI Identifier

InChI=1S/Pd

InchI Key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Palladium Bohr ModelSee more Palladium products. Palladium (atomic symbol: Pd, atomic number: 46) is a Block D, Group 10, Period 5 element with an atomic weight of 106.42. The number of electrons in each of palladium's shells is 2, 8, 18, 18 and its electron configuration is [Kr] 4d10. The palladium atom has a radius of 137 pm and a Van der Waals radius of 202 pm. In its elemental form, palladium has a silvery white appearance. Palladium is a member of the platinum group of metals (along with platinum, rhodium, ruthenium, iridium and osmium). Elemental PalladiumPalladium has the lowest melting point and is the least dense of the group. Palladium can be found as a free metal and alloyed with other platinum-group metals. Nickel-copper deposits are the main commercial source of palladium. Palladium was discovered and first isolated by William Hyde Wollaston in 1803. Its name is derived from the asteroid Pallas.

Recent Research

Probing the oxidative etching induced dissolution of palladium nanocrystals in solution by liquid cell transmission electron microscopy., Jiang, Yingying, Zhu Guomin, Dong Ganxing, Lin Fang, Zhang Hui, Yuan Jun, Zhang Ze, and Jin Chuanhong , Micron, 2017 Jun, Volume 97, p.22-28, (2017)

Cobalt nanoparticles supported on N-doped mesoporous carbon as a highly efficient catalyst for the synthesis of aromatic amines., Cui, Xueliang, Liang Kun, Tian Meng, Zhu Yangyang, Ma Jiantai, and Dong Zhengping , J Colloid Interface Sci, 2017 Sep 01, Volume 501, p.231-240, (2017)

PLLA microcapsules combined with silver nanoparticles and chlorhexidine acetate showing improved antibacterial effect., Zhou, Yuwei, Hu Ke, Guo Zhaobin, Fang Kun, Wang Xing, Yang Fang, and Gu Ning , Mater Sci Eng C Mater Biol Appl, 2017 Sep 01, Volume 78, p.349-353, (2017)

Nanomolar electrochemical detection of caffeic acid in fortified wine samples based on gold/palladium nanoparticles decorated graphene flakes., Thangavelu, Kokulnathan, Raja Nehru, Chen Shen-Ming, and Liao Wei-Cheng , J Colloid Interface Sci, 2017 Sep 01, Volume 501, p.77-85, (2017)

Using reduced graphene oxide-Ca:CdSe nanocomposite to enhance photoelectrochemical activity of gold nanoparticles functionalized tungsten oxide for highly sensitive prostate specific antigen detection., Wang, Xueping, Xu Rui, Sun Xu, Wang Yaoguang, Ren Xiang, Du Bin, Wu Dan, and Wei Qin , Biosens Bioelectron, 2017 Oct 15, Volume 96, p.239-245, (2017)

Antitumor activity of intratracheal inhalation of temozolomide (TMZ) loaded into gold nanoparticles and/or liposomes against urethane-induced lung cancer in BALB/c mice., Hamzawy, Mohamed A., Abo-Youssef Amira M., Salem Heba F., and Mohammed Sameh A. , Drug Deliv, 2017 Nov, Volume 24, Issue 1, p.599-607, (2017)

Influence of PEG coating on the oral bioavailability of gold nanoparticles in rats., Alalaiwe, Ahmed, Roberts Georgia, Carpinone Paul, Munson John, and Roberts Stephen , Drug Deliv, 2017 Nov, Volume 24, Issue 1, p.591-598, (2017)

Enantioselective Synthesis of gem-Diaryl Benzofuran-3(2H)-ones via One-Pot Asymmetric Rhodium/Palladium Relay Catalysis., Zhang, Zong-Feng, Zhu Dong-Xing, Chen Wen-Wen, Xu Bin, and Xu Ming-Hua , Org Lett, 2017 May 19, Volume 19, Issue 10, p.2726-2729, (2017)

Mesoporous metallic rhodium nanoparticles., Jiang, Bo, Li Cuiling, Dag Ömer, Abe Hideki, Takei Toshiaki, Imai Tsubasa, Hossain Md Shahriar A., Islam Md Tofazzal, Wood Kathleen, Henzie Joel, et al. , Nat Commun, 2017 May 19, Volume 8, p.15581, (2017)

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