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Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate

CAS #:

Linear Formula:

C30H24F12N6P2Ru

MDL Number:

MFCD11042502

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate
RU-OMX-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate
RU-OMX-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate
RU-OMX-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate
RU-OMX-05
Pricing > SDS > Data Sheet >

Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate Properties

Compound Formula

C30H24F12N6P2Ru

Molecular Weight

859.55

Appearance

Orange to red powder or crystals

Melting Point

>300 ?C

Boiling Point

N/A

Density

N/A

Exact Mass

884.189598

Monoisotopic Mass

884.189598

Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate Health & Safety Information

Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Statements N/A
Transport Information N/A

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 05/24/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate

Product Number: All applicable American Elements product codes, e.g. RU-OMX-02 , RU-OMX-03 , RU-OMX-04 , RU-OMX-05

CAS #: 60804-74-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Skin irritation (Category 2), H315
Eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
For the full text of the H-Statements mentioned in this Section, see Section 16.
GHS Label elements, including precautionary statements
Pictogram

Exclamation Mark - GHS07

Signal word Warning
Hazard statement(s)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
P321 Specific treatment (see supplemental first aid instructions on this label).
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS - none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms : Ru(bpy)3(PF6)2,Ruthenium-tris(2,2'-bipyridyl) dihexafluorophosphate
Formula : C30H24F12N6P2Ru
Molecular Weight : 859.55 g/mol
CAS-No. : 60804-74-2
Hazardous components
Component Tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate
Classification: Skin Irrit. 2; Eye Irrit. 2A; STOT SE 3; H315, H319, H335
Concentratin: N/A
For the full text of the H-Statements mentioned in this Section, see Section 16.


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
no data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
no data available
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Handle and store under inert gas. Light sensitive. Moisture sensitive.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form: solid
Odor: no data available
Odor Threshold: no data available
Melting point/freezing point: > 300 °C (> 572 °F)
Initial boiling point and boiling range: no data available
Flash point: no data available
Evapouration rate: no data available
Flammability (solid, gas): no data available
Upper/lower flammability or explosive limits: no data available
Vapour pressure: no data available
Vapour density: no data available
Relative density: no data available
Water solubility: no data available
Partition coefficient: noctanol/water: no data available
Auto-ignition temperature: no data available
Decomposition temperature: no data available
Viscosity: no data available
Explosive properties: no data available
Oxidizing properties: no data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx), Oxides of phosphorus, Hydrogen fluoride, Ruthenium oxide
Other decomposition products - no data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
no data available
Inhalation: no data available
Dermal: no data available
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
no data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
no data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate
CAS-No. 60804-74-2
Revision Date
New Jersey Right To Know Components
Tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate
CAS-No. 60804-74-2
Revision Date
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate

Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate is generally immediately available in most volumes, including bulk orders. American Elements can produce materials to custom specifications by request, in addition to custom compositions for commercial and research applications and new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar or plate form, as well as numerous other machined shapes, nanomaterials, and in the form of solutions and organometallic compounds. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate Synonyms

Ru(bpy)3(PF6)2, Ruthenium-tris(2, 2'-bipyridyl) dihexafluorophosphate; Ruthenium(2+) hexafluorophosphate 2, 2'-bipyridine (1:2:3)

Tris(2,2'-bipyridine)ruthenium(II) Hexafluorophosphate Chemical Identifiers

Linear Formula

C30H24F12N6P2Ru

Pubchem CID

15198703

MDL Number

MFCD11042502

EC No.

N/A

Beilstein Registry No.

N/A

IUPAC Name

2-pyridin-2-ylpyridine; ruthenium(2+); dihexafluorophosphate

SMILES

C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ru+2]

InchI Identifier

InChI=1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2

InchI Key

KLDYQWXVZLHTKT-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Ruthenium products. Ruthenium (atomic symbol: Ru, atomic number: 44) is a Block D, Group 8, Period 5 elemen with an atomic weight of 101.07. Ruthenium Bohr ModelThe number of electrons in each of ruthenium's shells is [2, 8, 18, 15, 1] and its electron configuration is [Kr] 4d7 5s1. The ruthenium atom has a radius of 134 pm and a Van der Waals radius of 207 pm. Ruthenium was discovered by J?drzej ?niadecki in 1807. It was first recognized as a distinct element by Karl Ernst Claus in 1844. Elemental RutheniumIn its elemental form, ruthenium has a silvery white metallic appearance. Ruthenium is a rare transition metal belonging to the platinum group of metals. It is found in pentlandite, pyroxenite, and platinum group metal ores. The name Ruthenium originates from the Latin word "Ruthenia," meaning Russia.

Recent Research

Lipophilicity-antiproliferative activity relationship study leads to the preparation of a ruthenium(II) arene complex with considerable in vitro cytotoxicity against cancer cells and a lower in vivo toxicity in zebrafish embryos than clinically approved, Haghdoost, MohammadMehdi, Golbaghi Golara, Létourneau Myriam, Patten Shunmoogum A., and Castonguay Annie , Eur J Med Chem, 2017 May 26, Volume 132, p.282-293, (2017)

Ruthenium(II)-Catalyzed Redox-Neutral [3+2] Annulation of Indoles with Internal Alkynes via C-H Bond Activation: Accessing a Pyrroloindolone Scaffold., Xie, Yanan, Wu Xiaowei, Li Chunpu, Wang Jiang, Li Jian, and Liu Hong , J Org Chem, 2017 May 19, Volume 82, Issue 10, p.5263-5273, (2017)

Synthesis of m-Alkylphenols via a Ruthenium-Catalyzed C-H Bond Functionalization of Phenol Derivatives., Li, Gang, Gao Panpan, Lv Xulu, Qu Chen, Yan Qingkai, Wang Ya, Yang Suling, and Wang Junjie , Org Lett, 2017 May 19, Volume 19, Issue 10, p.2682-2685, (2017)

Ruthenium-Catalyzed Oxidative Annulation and Hydroarylation of Chromene-3-carboxamides with Alkynes via Double C-H Functionalization., Tulichala, R N. Prasad, Shankar Mallepalli, and Swamy K C. Kumara , J Org Chem, 2017 May 19, Volume 82, Issue 10, p.5068-5079, (2017)

Ruthenium(II)-Catalyzed C-C Arylations and Alkylations: Decarbamoylative C-C Functionalizations., Moselage, Marc, Li Jie, Kramm Frederik, and Ackermann Lutz , Angew Chem Int Ed Engl, 2017 May 02, Volume 56, Issue 19, p.5341-5344, (2017)

Role of Mediator and Effects of Temperature on ortho-C-N Bond Fusion Reactions of Aniline Using Ruthenium Templates: Isolation and Characterization of New Ruthenium Complexes of the in-Situ-Generated Ligands., Roy, Suman K., Sengupta Debabrata, Rath Santi Prasad, Saha Tanushri, Samanta Subhas, and Goswami Sreebrata , Inorg Chem, 2017 May 01, Volume 56, Issue 9, p.4966-4977, (2017)

Stepwise Deoxygenation of Nitrite as a Route to Two Families of Ruthenium Corroles: Group 8 Periodic Trends and Relativistic Effects., Alemayehu, Abraham B., Vazquez-Lima Hugo, Gagnon Kevin J., and Ghosh Abhik , Inorg Chem, 2017 May 01, Volume 56, Issue 9, p.5285-5294, (2017)

Unique Ruthenium Bimetallic Supramolecular Cages From C4-Symmetric Tetrapyridyl Metalloligands., Ryu, Ji Yeon, Wi Eun Hye, Pait Moumita, Lee Sunwoo, Stang Peter J., and Lee Junseong , Inorg Chem, 2017 May 01, Volume 56, Issue 9, p.5471-5477, (2017)

Disaggregation of human islet amyloid polypeptide fibril formation by ruthenium polypyridyl complexes., Zhu, Dengsen, Gong Gehui, Wang Wenji, and Du Weihong , J Inorg Biochem, 2017 May, Volume 170, p.109-116, (2017)

Determination of pholcodine in syrups and human plasma using the chemiluminescence system of tris(1,10 phenanthroline)ruthenium(II) and acidic Ce(IV)., Delouei, Nastaran Jafari, Mokhtari Ali, and Jamali Mohammad Reza , Luminescence, 2017 May, Volume 32, Issue 3, p.387-393, (2017)

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