Creation of bismuth-tungsten oxide nanoclusters using lacunary polyoxometalates.

Title Creation of bismuth-tungsten oxide nanoclusters using lacunary polyoxometalates.
Authors T. Hanaya; K. Suzuki; R. Sato; K. Yamaguchi; N. Mizuno
Journal Dalton Trans
DOI 10.1039/c7dt01587a
Abstract

Three types of heterometallic bismuth-tungsten oxide nanoclusters were successfully synthesized by the reactions of lacunary silicotungstates (trivacant [A-?-SiW9O34](10-) and divacant [?-SiW10O36](8-)) and Bi(3+) in organic solvents. Lone pairs on Bi(3+) acted as structure-directing groups in these nanoclusters.

Citation T. Hanaya; K. Suzuki; R. Sato; K. Yamaguchi; N. Mizuno.Creation of bismuth-tungsten oxide nanoclusters using lacunary polyoxometalates.. Dalton Trans. 2017. doi:10.1039/c7dt01587a

Related Elements

Bismuth

See more Bismuth products. Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental BismuthBismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite. It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass.

Tungsten

See more Tungsten products. Tungsten (atomic symbol: W, atomic number: 74) is a Block D, Group 6, Period 6 element with an atomic weight of 183.84. The number of electrons in each of tungsten's shells is [2, 8, 18, 32, 12, 2] and its electron configuration is [Xe] 4f14 5d4 6s2. Tungsten Bohr ModelThe tungsten atom has a radius of 139 pm and a Van der Waals radius of 210 pm. Tungsten was discovered by Torbern Bergman in 1781 and first isolated by Juan José Elhuyar and Fausto Elhuyar in 1783. In its elemental form, tungsten has a grayish white, lustrous appearance. Elemental TungstenTungsten has the highest melting point of all the metallic elements and a density comparable to that or uranium or gold and about 1.7 times that of lead. Tungsten alloys are often used to make filaments and targets of x-ray tubes. It is found in the minerals scheelite (CaWO4) and wolframite [(Fe,Mn)WO4]. In reference to its density, Tungsten gets its name from the Swedish words tung and sten, meaning heavy stone.

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