Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]palladium(II) Chloride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Palladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the palladium group of metals. It is an excellent hydrogenation and dehydrogenation catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other palladium group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Palladium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Coking- and sintering-resistant palladium catalysts achieved through
atomic layer deposition.
Lu J, Fu B, Kung MC, Xiao G, Elam JW, Kung HH, Stair PC.
Science. 2012 Mar 9;335(6073):1205-8.
PMID:
22403386
[PubMed - in process]
Palladium-catalyzed S-benzylation of unprotected mercaptobenzoic acid with
benzyl alcohols in water.
Hikawa H, Yokoyama Y.
Org Biomol Chem. 2012 Mar 8. [Epub ahead of print]
PMID:
22402746
[PubMed - as supplied by publisher]
Kinetics of the sulfur oxidation on palladium: A combined in situ x-ray
photoelectron spectroscopy and density-functional study.
Gotterbarm K, Luckas N, Ho?fert O, Lorenz MP, Streber R, Papp C, Vin~es F,
Steinru?ck HP, Go?rling A.
J Chem Phys. 2012 Mar 7;136(9):094702.
PMID:
22401463
[PubMed - as supplied by publisher]
Structure and magnetic properties of nanostructured Pd-Fe thin films
produced by pulse electrodeposition.
Strukova GK, Strukov GV, Bozhko SI, Kabanov YP, Shmytko IM, Mazilkin AA,
Sobolev NA, Zhiteytsev ER, Sukhanov AA, Voronkova VK, Tagirov LR.
J Nanosci Nanotechnol. 2011 Oct;11(10):8907-11.
PMID:
22400279
[PubMed - in process]
Microbial synthesis of core/shell gold/palladium nanoparticles for
applications in green chemistry.
Deplanche K, Merroun ML, Casadesus M, Tran DT, Mikheenko IP, Bennett JA, Zhu
J, Jones IP, Attard GA, Wood J, Selenska-Pobell S, Macaskie LE.
J R Soc Interface. 2012 Mar 7. [Epub ahead of print]
PMID:
22399790
[PubMed - as supplied by publisher]
Pd(ii)-catalyzed direct C5-arylation of azole-4-carboxylates through
double C-H bond cleavage.
Li Z, Ma L, Xu J, Kong L, Wu X, Yao H.
Chem Commun (Camb). 2012 Mar 8. [Epub ahead of print]
PMID:
22399150
[PubMed - as supplied by publisher]
Palladium(ii) thiocarboxamide complexes: synthesis, characterisation and
application to catalytic Suzuki coupling reactions.
Sindhuja E, Ramesh R, Liu Y.
Dalton Trans. 2012 Mar 8. [Epub ahead of print]
PMID:
22399145
[PubMed - as supplied by publisher]
Effects of a catalytic converter on PCDD/F, chlorophenol and PAH emissions
in residential wood combustion.
Kaivosoja T, Virén A, Tissari J, Ruuskanen J, Tarhanen J, Sippula O, Jokiniemi
J.
Chemosphere. 2012 Mar 5. [Epub ahead of print]
PMID:
22397840
[PubMed - as supplied by publisher]
Engineering Biogenic Magnetite for Sustained Cr(VI) Remediation in Flow-
through Systems.
Crean DE, Coker VS, van der Laan G, Lloyd JR.
Environ Sci Technol. 2012 Mar 7. [Epub ahead of print]
PMID:
22397548
[PubMed - as supplied by publisher]
Palladium-Catalyzed N-Arylation of 2-Aminothiazoles.
McGowan MA, Henderson JL, Buchwald SL.
Org Lett. 2012 Mar 6. [Epub ahead of print]
PMID:
22394197
[PubMed - as supplied by publisher]
Generation of Indeno[1,2-c]pyrroles via a Pd-Catalyzed Reaction of 2-
Alkynylbromobenzene with Propargylic Sulfonamide.
Luo Y, Wu J.
Org Lett. 2012 Mar 5. [Epub ahead of print]
PMID:
22390224
[PubMed - as supplied by publisher]
Heck-Type Cross-Dehydrogenative Coupling Reactions of Indolizines at the
3-Position with Electron-Deficient Alkenes through Palladium-Catalyzed C?H
Activation.
Hu H, Liu Y, Zhong H, Zhu Y, Wang C, Ji M.
Chem Asian J. 2012 Mar 2. doi: 10.1002/asia.201101050. [Epub ahead of print]
PMID:
22389289
[PubMed - as supplied by publisher]
Preparation of Allyl and Vinyl Silanes by the Palladium-Catalyzed
Silylation of Terminal Olefins: A Silyl-Heck Reaction.
McAtee JR, Martin SE, Ahneman DT, Johnson KA, Watson DA.
Angew Chem Int Ed Engl. 2012 Mar 1. doi: 10.1002/anie.201200060. [Epub ahead
of print]
PMID:
22383447
[PubMed - as supplied by publisher]
Synthesis and Unexpected Coordination of a Silicon(II)-Based SiCSi
Pincerlike Arene to Palladium.
Wang W, Inoue S, Irran E, Driess M.
Angew Chem Int Ed Engl. 2012 Mar 1. doi: 10.1002/anie.201200632. [Epub ahead
of print]
PMID:
22383113
[PubMed - as supplied by publisher]
MOFs as multifunctional catalysts: One-pot synthesis of menthol from
citronellal over a bifunctional MIL-101 catalyst.
Cirujano FG, Llabrés I Xamena FX, Corma A.
Dalton Trans. 2012 Mar 2. [Epub ahead of print]
PMID:
22382815
[PubMed - as supplied by publisher]
A facile route for preparing a mesoporous palladium coordination polymer
as a recyclable heterogeneous catalyst.
Zhang S, Liu Q, Shen M, Hu B, Chen Q, Li H, Amoureux JP.
Dalton Trans. 2012 Mar 1. [Epub ahead of print]
PMID:
22382505
[PubMed - as supplied by publisher]
Development of palladium-catalyzed transformations using propargylic
compounds.
Yoshida M.
Chem Pharm Bull (Tokyo). 2012;60(3):285-99.
PMID:
22382407
[PubMed - in process]
Palladium-Catalyzed Decarboxylative Coupling of Quinolinone-3-Carboxylic
Acids and Related Heterocyclic Carboxylic Acids with (Hetero)aryl Halides.
Messaoudi S, Brion JD, Alami M.
Org Lett. 2012 Mar 1. [Epub ahead of print]
PMID:
22381127
[PubMed - as supplied by publisher]
Elemental Release from CoCr and NiCr Alloys Containing Palladium.
Beck KA, Sarantopoulos DM, Kawashima I, Berzins DW.
J Prosthodont. 2012 Feb;21(2):88-93. doi: 10.1111/j.1532-849X.2011.00800.x.
PMID:
22380645
[PubMed - in process]
Proud sponsors of Aeromat 2012. Please join us and our customers & co-sponsors Boeing and ATI on
June 18-20, 2012
in Charlotte, North Carolina
Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]palladium(II) Chloride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Palladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the palladium group of metals. It is an excellent hydrogenation and 
dehydrogenation
catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other palladium group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Palladium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.
