Bismuth(III) Oxyiodide

CAS #:

Linear Formula:

BiOI

MDL Number:

MFCD00015969

EC No.:

232-126-9

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Bismuth(III) Oxyiodide
BI3-OXI-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Bismuth(III) Oxyiodide
BI3-OXI-03
Pricing > SDS > Data Sheet >
98% Bismuth(III) Oxyiodide
BI3-OXI-018
Pricing > SDS > Data Sheet >

Bismuth(III) Oxyiodide Properties (Theoretical)

Compound Formula BiOI
Molecular Weight 351.88
Appearance Reddish-brown powder
Melting Point N/A
Boiling Point N/A
Density 7.92 g/cm3
Solubility in H2O N/A
Exact Mass 351.880005 Da
Monoisotopic Mass 351.880005 Da
Charge N/A

Bismuth(III) Oxyiodide Health & Safety Information

Signal Word Warning
Hazard Statements H302-H312-H315-H319-H332-H335
Hazard Codes Xi
Precautionary Statements P261-P280-P305 + P351 + P338
Risk Codes 20/21/22-36/37/38
Safety Statements 26-37/39
RTECS Number N/A
Transport Information N/A
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 06/13/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Bismuth(III) Oxyiodide

Product Number: All applicable American Elements product codes, e.g. BI3-OXI-02 , BI3-OXI-03 , BI3-OXI-018

CAS #: 7787-63-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements
Signal Word: Warning
Hazard Statements
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
Harmful if swallowed, in contact with skin or if inhaled

Exclamation Mark - GHS07

Precautionary Statements
Prevention
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
Skin
IF ON SKIN: Wash with plenty of soap and water
Call a POISON CENTER or doctor/physician if you feel unwell
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Storage
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component
Bismuth iodide oxide
CAS-No 7787-63-5
Weight % >95


SECTION 4. FIRST AID MEASURES

General Advice If symptoms persist, call a physician.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.
Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if
symptoms occur.
Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if
symptoms occur.
Most important symptoms and effects
None reasonably foreseeable.
Notes to Physician Treat symptomatically


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
Unsuitable Extinguishing Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature Not applicable
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Keep product and empty container away from heat and sources of ignition.
Hazardous Combustion Products
None known.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA
Health
2
Flammability
0
Instability
0
Physical hazards
N/A


SECTION 6. ACCIDENTAL RELEASE MEASURES

Accidental release measures
Personal Precautions Use personal protective equipment as required. Ensure adequate ventilation. Avoid dust formation.
Environmental Precautions Should not be released into the environment. See Section 12 for additional Ecological Information.
Methods for Containment and Clean Up
Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed
containers for disposal.


SECTION 7. HANDLING AND STORAGE

Handling and storage
Handling Do not get in eyes, on skin, or on clothing. Ensure adequate ventilation. Wear personal
protective equipment/face protection. Avoid dust formation. Avoid ingestion and inhalation.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls / personal protection
Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location.
Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Powder Solid
Appearance No information available
Odor No information available
Odor Threshold No information available
pH No information available
Melting Point/Range No data available
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature Not applicable
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula Bi I O
Molecular Weight 351.88


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard None known, based on information available
Stability No information available.
Conditions to Avoid Incompatible products.
Incompatible Materials Strong oxidizing agents
Hazardous Decomposition Products None under normal use conditions
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation Irritating to eyes, respiratory system and skin
Sensitization No information available
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and
delayed
No information available
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Do not empty into drains.
Persistence and Degradability Insoluble in water
Bioaccumulation/ Accumulation No information available.
Mobility Is not likely mobile in the environment due its low water solubility.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT Not regulated
TDG Not regulated
IATA Not regulated
IMDG/IMO Not regulated


SECTION 15. REGULATORY INFORMATION

U.S. Federal Regulations
SARA 313 Not applicable
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
Clean Air Act Not applicable
OSHA - Occupational Safety and
Health Administration
Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know
Regulations
Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland
Security
This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Bismuth(III) Oxyiodide

Iodide IonBismuth(III) Oxyiodide (Bismuth Subiodide) is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Iodide compounds are used in internal medicine. Treating an iodide with manganese dioxide and sulfuric acid sublimes the iodine. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Bismuth(III) Oxyiodide Synonyms

Bismuth subiodide; Bismuth(III) iodide oxide; Iodo(oxo)bismuthine

Chemical Identifiers

Linear Formula BiOI
MDL Number MFCD00015969
EC No. 232-126-9
Beilstein/Reaxys No. N/A
Pubchem CID 21863085
IUPAC Name iodobismuthanone
SMILES I[Bi]=O
InchI Identifier InChI=1S/Bi.HI.O/h;1H;/q+1;;/p-1
InchI Key YPMZHGJQYGMKBQ-UHFFFAOYSA-M

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Bismuth

See more Bismuth products. Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental BismuthBismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite. It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass.

Iodine

See more Iodine products. Iodine (atomic symbol: I, atomic number: 53) is a Block P, Group 17, Period 5 element with an atomic radius of 126.90447. The number of electrons in each of Iodine's shells is 2, 8, 18, 18, 7 and its electron configuration is [Kr] 4d10 5s2 5p5. The iodine atom has a radius of 140 pm and a Van der Waals radius of 198 pm. In its elemental form, iodine has a lustrous metallic gray appearance as a solid and a violet appearance as a gas or liquid solution. Elemental IodineIodine forms compounds with many elements, but is less active than the other halogens. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Iodine compounds are important in organic chemistry and very useful in the field of medicine. Iodine was discovered and first isolated by Bernard Courtois in 1811. The name Iodine is derived from the Greek word "iodes" meaning violet.

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