General Synthetic Route toward Highly Dispersed Ultrafine Pd-Au Alloy Nanoparticles Enabled by Imidazolium-based Organic Polymers.

Title General Synthetic Route toward Highly Dispersed Ultrafine Pd-Au Alloy Nanoparticles Enabled by Imidazolium-based Organic Polymers.
Authors Y. Gong; H. Zhong; W. Liu; B. Zhang; S. Hu; R. Wang
Journal ACS Appl Mater Interfaces
DOI 10.1021/acsami.7b16794
Abstract

Bimetallic Pd-Au nanoparticles (NPs) usually show superior catalytic performances over their single component counterparts, the general and facile synthesis of subnanometer-scaled Pd-Au NPs still remains a great challenge, especially for electronegative ultra?ne bimetallic NPs. Here, we develop an anion-exchange strategy for the preparation of ultrafine Pd-Au alloy NPs. Simple treatment of main-chain imidazolium-based organic polymer (IOP) with HAuCl4 and Na2PdCl4, and followed by reduction with NaBH4 generated Pd-Au alloy NPs (Pd-Au/IOP). These NPs possess an unprecedented tiny size of 1.50±0.20 nm, and are uniformly dispersed over IOP. The electronic structure of surface Pd and Au atoms is optimized via electron exchange during alloying, a net charge ?owing resutling from counter anions is injected into Au and Pd to form a strong ensemble effect, which is responsible for remarkably higher catalytic activity of Pd-Au/IOP in hydrolysis dehydrogenation of ammonia borane than those of monometallic counterparts.

Citation Y. Gong; H. Zhong; W. Liu; B. Zhang; S. Hu; R. Wang.General Synthetic Route toward Highly Dispersed Ultrafine Pd-Au Alloy Nanoparticles Enabled by Imidazolium-based Organic Polymers.. ACS Appl Mater Interfaces. 2017. doi:10.1021/acsami.7b16794

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