SECTION 2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS05 corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
GHS07
STOT SE 3
H335 May cause respiratory irritation.
Other hazards that do not result in classification
No data available
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
Hazard pictograms
GHS05 GHS07
Signal word
Danger
Hazard statements
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
Precautionary statements
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
CAS# Designation:
Lithium lanthanum zirconium oxide
SECTION 4. FIRST AID MEASURES
4.1 Description of first aid measures
General information
Instantly remove any clothing soiled by the product.
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
In case of skin contact:
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Then consult doctor.
If swallowed:
Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayed
Causes severe skin burns.
Causes serious eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5. FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
5.2 Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Lithium oxide
Zirconium oxide
Lanthanum oxide
5.3 Advice for firefighters
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
6.2 Environmental precautions:
Do not allow product to enter drains, sewage systems, or other water courses system or water bodies.
6.3 Methods and materials for containment and cleanup:
Use neutralizing agent.
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
6.4 Reference to other sections
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
SECTION 7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Handle under dry protective gas.
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
No data available
7.2 Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and containers:
No special requirements.
Information about storage in one common storage facility:
Store away from air.
Store away from water.
Store away from oxidising agents.
Further information about storage conditions:
Store under dry inert gas.
This product is moisture sensitive.
This product is air sensitive.
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Protect from humidity and keep away from water.
Store in a locked cabinet or with access restricted to technical experts or their assistants.
7.3 Specific end use(s)
No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
8.1 Control parameters
Components with critical values that require monitoring at the workplace:
None.
Additional information:
No data
8.2 Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use breathing protection with high concentrations.
Protection of hands:
Inspect gloves prior to use.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Material of gloves
Impervious gloves
Eye protection:
Tightly sealed safety glasses.
Full face protection
Body protection:
Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance:
Form: Solid in various forms:
Colour: Pale grey
Smell: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: No data available
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Inflammability (solid, gas)
No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Self-inflammability: No data available.
Danger of explosion: No data available.
Critical values for explosion:
Lower: No data available
Upper: No data available
Steam pressure: N/A
Density No data available
Relative density
No data available.
Vapor density
N/A
Evaporation rate
N/A
Solubility in Water (H2O): No data available
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
9.2 Other information
No data available
SECTION 10. STABILITY AND REACTIVITY
10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
10.3 Possibility of hazardous reactions
Reacts with strong oxidising agents
10.4 Conditions to avoid
No data available
10.5 Incompatible materials:
Air
Water/moisture
Oxidising agents
10.6 Hazardous decomposition products:
Lithium oxide
Zirconium oxide
Lanthanum oxide
SECTION 11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity:
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
Causes severe skin burns.
Eye irritation or corrosion:
Causes serious eye damage.
Sensitization:
No sensitizing effect known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
May cause respiratory irritation.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
12.1 Toxicity
Aquatic toxicity:
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
Additional ecological information:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage systems.
Avoid transfer into the environment.
12.5 Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
12.6 Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Recommendation
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Consult official regulations for proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
ADR, IMDG, IATA
UN3262
14.2 UN proper shipping name
ADR
3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (Lithium lanthanum zirconium oxide )
IMDG, IATA
CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (Lithium lanthanum zirconium oxide )
14.3 Transport hazard class(es)
ADR
Class
8 (C6) Corrosive substances.
Label
8
IMDG, IATA
Class
8 Corrosive substances.
Label
8
Packing group
ADR, IMDG, IATA
III
14.5 Environmental hazards:
N/A
14.6 Special precautions for user
Warning: Corrosive substances.
Kemler Number: 80
EMS Number: F-A,S-B
Segregation groups
Alkalis
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC
Code
N/A
Transport/Additional information:
ADR
Excepted quantities (EQ):
E1
Limited quantities (LQ)
5 kg
Transport category
3
Tunnel restriction code
E
UN "Model Regulation":
UN3262, CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (Lithium lanthanum zirconium oxide ), 8, III
SECTION 15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Australian Inventory of Chemical Substances
Substance is not listed.
Standard for the Uniform Scheduling of Drugs and Poisons
Substance is not listed.
National regulations
Information about limitation of use:
For use only by technically qualified individuals.
Employment restrictions concerning young persons must be observed.
Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Other regulations, limitations and prohibitive regulations
ELINCS (European List of Notified Chemical Substances)
Substance is not listed.
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
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