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Bismuth Germanate |
| High Purity Bi4Ge3O12
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| Product |
Product Code | Order or Specifications |
| (2N) 99% Bismuth Germanate |
BI-GE-02-C |
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| (3N) 99.9% Bismuth Germanate |
BI-GE-03-C |
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| (4N) 99.99% Bismuth Germanate |
BI-GE-04-C |
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| (5N) 99.999% Bismuth Germanate |
BI-GE-05-C |
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Bismuth Germanate is a crystalline solid used in photo optic applications.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Bismuth is a Block P, Group 15, Period 6 element. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electronic configuration is [Xe] 4f14 5d10 6s2 6p3. In its elemental form bismuth's CAS number is 7440-69-9. The bismuth atom has a radius of 154.5.pm and it's Van der Waals radius is 200.pm. Bismuth is the most diamagnetic of all metals, and the thermal conductivity is lower than any metal, except mercury. Bismuth is not toxic. It has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth expands on solidification. This property makes bismuth alloys particularly suited to the making of sharp castings of objects subject to damage by high temperatures. With other metals such as tin, cadmium , etc., bismuth forms low-melting alloys which are extensively used for safety devices in fire detection and extinguishing systems. Bismuth is used in producing malleable irons and is finding use as a catalyst for making acrylic fibers. When bismuth is heated in air it burns with a blue flame, forming yellow fumes of the oxide. The metal is also used as a thermocoupling material, and has found application as a carrier for 235 U or 233 U fuel in nuclear reactors. Its soluble salts are characterized by forming unsoluble basic salts on the addition of water, a property sometimes used in detection work. Bismuth oxychloride is used extensively in cosmetics. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth' meaning white mass. See Bismuth research below.
 Germanium is a Block P, Group 14, Period 4 element. The number of electrons in each of Germanium's shells is 2, 8, 18, 4 and its electronic configuration is [Ar] 3d10 4s2 4p2. In its elemental form germanium's CAS number is 7440-56-4. The germanium atom has a radius of 122.5.pm and it's Van der Waals radius is 200.pm. Germanium is not toxic. Germanium is a very important semiconductor. Zone-refining techniques have led to production of crystalline germanium for semiconductor use with extremely high purities. When germanium is doped with arsenic, gallium, or other elements, it is used as a transistor element in thousands of electronic applications. The most common use of germanium is as a semiconductor. Germanium is also finding many other applications including use as an alloying agent, as a phosphor in fluorescent lamps, and as a catalyst. Germanium and germanium oxide are transparent to the infrared and are used in infrared spectroscopes and other optical equipment, including extremely sensitive infrared detectors. The high refractive index and dispersion properties of its oxide's have made germanium useful as a component of wide-angle camera lenses and microscope objectives. The field of organo-germanium chemistry is becoming increasingly important. Germanium was first discovered by Clemens Winkler in 1886. See Germanium research below.
American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:
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Crystal "pulling" by the Czochaiski method for production of semiconductor materials
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Flux growth and gradient freeze
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Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
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Recent Research & Development for Bismuth - Helicobacter pylori antibiotic resistance in Brazil: clarithromycin is still a good option.
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Su L, Zhao H, Li H, Zheng L, Ren G, Xu J, Ryba-Romanowski W, Lisiecki R, Solarz P.
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Langmuir. 2011 Nov 28. [Epub ahead of print]
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Mansfeld D, Miersch L, Rüffer T, Schaarschmidt D, Lang H, Böhle T, Troff RW, Schalley CA, Müller J, Mehring M.
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Dalton Trans. 2011 Nov 21. [Epub ahead of print]
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ACS Appl Mater Interfaces. 2011 Nov 21. [Epub ahead of print]
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Recent Research & Development for Germanium
- Facile central-element exchange in neutral
hexacoordinate germanium and silicon complexes; synthesis and characterization of
germanium complexes. Yakubovich S, Kalikhman I, Kost D. Dalton Trans. 2010 Oct 21;39(39):9241-4. Epub 2010 Aug 18.
PubMed PMID: 20717626.
- Ionic nature of
Ge(II)-centered dications: a germanium K-edge X-ray absorption near edge
structures study. Ward MJ, Rupar PA, Murphy MW, Yiu YM, Baines KM, Sham TK. Chem Commun (Camb). 2010 Oct 7;46(37):7016-8. Epub 2010 Aug 25.
PubMed PMID: 20740225.
- Seedless Growth of Sub-10 nm Germanium Nanowires. Hobbs RG, Barth S, Petkov N, Zirngast M, Marschner C, Morris MA, Holmes JD. J Am Chem Soc. 2010 Oct
6;132(39):13742-9. PubMed PMID: 20836555.
- Group IV nanoparticles: synthesis, properties, and biological
applications. Fan J, Chu PK. Small. 2010 Oct 4;6(19):2080-98. PubMed PMID: 20730824.
- Broadband spectral modification from
visible light to near-infrared radiation using Ce(3+)-Er(3+) codoped yttrium
aluminium garnet. Zhou J, Teng Y, Liu X, Ye S, Ma Z, Qiu J. Phys Chem Chem Phys. 2010 Sep 27. [Epub ahead of print] PubMed
PMID: 20871892.
- Scanning Probe
Direct-Write of Germanium Nanostructures. Torrey JD, Vasko SE, Kapetanovic A, Zhu Z, Scholl A, Rolandi M. Adv Mater. 2010 Sep 24. [Epub ahead of
print] PubMed PMID: 20872407.
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