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Bismuth Germanate
High Purity Bi4Ge3O12

Product Product Code Order or Specifications
(2N) 99% Bismuth Germanate BI-GE-02-C Contact American Elements
(3N) 99.9% Bismuth Germanate BI-GE-03-C Contact American Elements
(4N) 99.99% Bismuth Germanate BI-GE-04-C Contact American Elements
(5N) 99.999% Bismuth Germanate BI-GE-05-C Contact American Elements


Bismuth Germanate is a crystalline solid used in photo optic applications.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Bismuth(Bi) atomic and molecular weight, atomic number and elemental symbolBismuth is a Block P, Group 15, Period 6 element. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electronic configuration is [Xe] 4f14 5d10 6s2 6p3. In its elemental form bismuth's CAS number is 7440-69-9. The bismuth atom has a radius of 154.5.pm and it's Van der Waals radius is 200.pm. Bismuth is the most diamagnetic of all metals, and the thermal conductivity is lower than any metal, except mercury. Bismuth is not toxic. It has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth expands on solidification. This property makes bismuth alloys particularly suited to the making of sharp castings of objects subject to damage by high temperatures. With other metalsElemental Bismuth such as tin, cadmium , etc., bismuth forms low-melting alloys which Bismuth Bohr Modelare extensively used for safety devices in fire detection and extinguishing systems. Bismuth is used in producing malleable irons and is finding use as a catalyst for making acrylic fibers. When bismuth is heated in air it burns with a blue flame, forming yellow fumes of the oxide. The metal is also used as a thermocoupling material, and has found application as a carrier for 235 U or 233 U fuel in nuclear reactors. Its soluble salts are characterized by forming unsoluble basic salts on the addition of water, a property sometimes used in detection work. Bismuth oxychloride is used extensively in cosmetics. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth' meaning white mass. See Bismuth research below.  

Germanium(Ge) atomic and molecular weight, atomic number and elemental symbolGermanium(Ge) atomic and molecular weight, atomic number and elemental symbolGermanium is a Block P, Group 14, Period 4 element. The number of electrons in each of Germanium's shells is 2, 8, 18, 4 and its electronic configuration is [Ar] 3d10 4s2 4p2. In its elemental form germanium's CAS number is 7440-56-4. The germanium atom has a radius of 122.5.pm and it's Van der Waals radius is 200.pm. Germanium is not toxic. Germanium is a very important semiconductor. Zone-refining techniques have led to production of crystalline germanium for semiconductor use with extremely high purities. When germanium is doped with arsenic, gallium, or other elements, it is used as a transistor Elemental Germanium element in thousands of electronic Germanium Bohr Modelapplications. The most common use of germanium is as a semiconductor. Germanium is also finding many other applications including use as an alloying agent, as a phosphor in fluorescent lamps, and as a catalyst. Germanium and germanium oxide are transparent to the infrared and are used in infrared spectroscopes and other optical equipment, including extremely sensitive infrared detectors. The high refractive index and dispersion properties of its oxide's have made germanium useful as a component of wide-angle camera lenses and microscope objectives. The field of organo-germanium chemistry is becoming increasingly important. Germanium was first discovered by Clemens Winkler in 1886. See Germanium research below.  

American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:

  • Crystal "pulling" by the Czochaiski method for production of semiconductor materials
  • Flux growth and gradient freeze
  • Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
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Recent Research & Development for Bismuth

  • Helicobacter pylori antibiotic resistance in Brazil: clarithromycin is still a good option. Jaime Natan E, Silva FM, Barbuti RC, Navarro-Rodriguez T, Moraes-Filho JP, Pedrazzoli J Jr. Arq Gastroenterol. 2011 Dec;48(4):261-4. PMID: 22147131 [PubMed - in process]

  • Towards better photocatalysts: first-principles studies of the alloying effects on the photocatalytic activities of bismuth oxyhalides under visible light. Zhang H, Liu L, Zhou Z. Phys Chem Chem Phys. 2011 Dec 7. [Epub ahead of print] PMID: 22146949 [PubMed - as supplied by publisher]

  • A stannum-bismuth composite film electrode for simultaneous determination of zinc(ii) and cadmium(ii) using differential pulse anodic stripping voltammetry. Li NB, Zhu WW, Luo JH, Luo HQ. Analyst. 2011 Dec 6. [Epub ahead of print] PMID: 22145153 [PubMed - as supplied by publisher]

  • Conductive scanning probe microscopy of nanostructured Bi(2)Te(3). Souier T, Li G, Santos S, Stefancich M, Chiesa M. Nanoscale. 2011 Dec 6. [Epub ahead of print] PMID: 22143255 [PubMed - as supplied by publisher]

  • Near-infrared ultrabroadband luminescence spectra properties of subvalent bismuth in CsI halide crystals. Su L, Zhao H, Li H, Zheng L, Ren G, Xu J, Ryba-Romanowski W, Lisiecki R, Solarz P. Opt Lett. 2011 Dec 1;36(23):4551-3. doi: 10.1364/OL.36.004551. PMID: 22139239 [PubMed - in process]

  • Bismuth Shields for CT Dose Reduction: Do They Help or Hurt? McCollough CH, Wang J, Berland LL. J Am Coll Radiol. 2011 Dec;8(12):878-9. No abstract available. PMID: 22137008 [PubMed - in process]

  • Treatment and diagnostic accuracy of neurosyphilis at Boston City Hospital's Neurological Unit, 1930-1979. Patterson D, Vilensky JA, Robertson WM, Berger J. J Neurol Sci. 2011 Nov 29. [Epub ahead of print] PMID: 22129939 [PubMed - as supplied by publisher]

  • Three novel Bi(iii) complexes with in situ generated anilate ligands: unusual oxidation of cyclohexanedione to dihydroxy benzoquinone. Gao H, Zhang XM. Dalton Trans. 2011 Nov 29. [Epub ahead of print] PMID: 22124341 [PubMed - as supplied by publisher]

  • Microfabricated disposable lab-on-a-chip sensors with integrated bismuth microelectrode arrays for voltammetric determination of trace metals. Kokkinos C, Economou A, Raptis I. Anal Chim Acta. 2012 Jan 13;710:1-8. Epub 2011 Nov 3. PMID: 22123106 [PubMed - in process]

  • Novel in situ N-Doped (BiO)2CO3 Hierarchical Microspheres Self-Assembled by Nanosheets as Efficient and Durable Visible Light Driven Photocatalyst. Dong F, Sun Y, Fu M, Ho WK, Lee SC, Wu Z. Langmuir. 2011 Nov 28. [Epub ahead of print] PMID: 22122119 [PubMed - as supplied by publisher]

  • From {Bi(22) O(26) } to Chiral Ligand-Protected {Bi(38) O(45) }-Based Bismuth Oxido Clusters. Mansfeld D, Miersch L, Rüffer T, Schaarschmidt D, Lang H, Böhle T, Troff RW, Schalley CA, Müller J, Mehring M. Chemistry. 2011 Nov 25. doi: 10.1002/chem.201102437. [Epub ahead of print] PMID: 22120957 [PubMed - as supplied by publisher]

  • Status of development of gamma-ray detector response function code or GAMDRF. Li F, Han X. Appl Radiat Isot. 2011 Nov 18. [Epub ahead of print] PMID: 22118837 [PubMed - as supplied by publisher]

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  • Characteristics of rational harmonic mode-locked short-cavity fiber ring laser using a bismuth-oxide-based erbium-doped fiber and a bismuth-oxide-based highly nonlinear fiber. Fukuchi Y, Maeda J. Opt Express. 2011 Nov 7;19(23):22502-9. doi: 10.1364/OE.19.022502. PMID: 22109128 [PubMed - in process]

  • Fabrication and supercontinuum generation in dispersion flattened bismuth microstructured optical fiber. Zhang WQ, Ebendorff-Heidepriem H, Monro TM, Afshar V S. Opt Express. 2011 Oct 24;19(22):21135-44. doi: 10.1364/OE.19.021135. PMID: 22108964 [PubMed - in process]

  • Structural motifs in phenylbismuth heterocyclic carboxylates - secondary interactions leading to oligomers. Anjaneyulu O, Maddileti D, Kumara Swamy KC. Dalton Trans. 2011 Nov 21. [Epub ahead of print] PMID: 22105914 [PubMed - as supplied by publisher]

  • Influences of Oxygen Pressure on Optical Properties and Interband Electronic Transitions in Multiferroic Bismuth Ferrite Nanocrystalline Films Grown by Pulsed Laser Deposition. Jiang K, Zhu J, Wu J, Sun J, Hu Z, Chu J. ACS Appl Mater Interfaces. 2011 Nov 21. [Epub ahead of print] PMID: 22103473 [PubMed - as supplied by publisher]

  • Hydride generation in-atomizer collection atomic absorption spectrometry for the determination of antimony in acetic acid leachates from pewter cups. Dessuy MB, Kratzer J, Vale MG, Welz B, Dedina J. Talanta. 2011 Dec 15;87:255-61. Epub 2011 Oct 17. PMID: 22099676 [PubMed - in process]

  • Preparation and characterization of bismuth oxide nanoparticles-multiwalled carbon nanotube composite for the development of horseradish peroxidase based H(2)O(2) biosensor. Periasamy AP, Yang S, Chen SM. Talanta. 2011 Dec 15;87:15-23. Epub 2011 Oct 5. PMID: 22099642 [PubMed - in process]

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Recent Research & Development for Germanium

  • Facile central-element exchange in neutral hexacoordinate germanium and silicon complexes; synthesis and characterization of germanium complexes. Yakubovich S, Kalikhman I, Kost D. Dalton Trans. 2010 Oct 21;39(39):9241-4. Epub 2010 Aug 18. PubMed PMID: 20717626.

  • Ionic nature of Ge(II)-centered dications: a germanium K-edge X-ray absorption near edge structures study. Ward MJ, Rupar PA, Murphy MW, Yiu YM, Baines KM, Sham TK. Chem Commun (Camb). 2010 Oct 7;46(37):7016-8. Epub 2010 Aug 25. PubMed PMID: 20740225.

  • Seedless Growth of Sub-10 nm Germanium Nanowires. Hobbs RG, Barth S, Petkov N, Zirngast M, Marschner C, Morris MA, Holmes JD. J Am Chem Soc. 2010 Oct 6;132(39):13742-9. PubMed PMID: 20836555.

  • Group IV nanoparticles: synthesis, properties, and biological applications. Fan J, Chu PK. Small. 2010 Oct 4;6(19):2080-98. PubMed PMID: 20730824.

  • Broadband spectral modification from visible light to near-infrared radiation using Ce(3+)-Er(3+) codoped yttrium aluminium garnet. Zhou J, Teng Y, Liu X, Ye S, Ma Z, Qiu J. Phys Chem Chem Phys. 2010 Sep 27. [Epub ahead of print] PubMed PMID: 20871892.

  • Scanning Probe Direct-Write of Germanium Nanostructures. Torrey JD, Vasko SE, Kapetanovic A, Zhu Z, Scholl A, Rolandi M. Adv Mater. 2010 Sep 24. [Epub ahead of print] PubMed PMID: 20872407.

  • Bone densitometry using x-ray spectra. Krmar M, Shukla S, Ganezer K. Phys Med Biol. 2010 Sep 24;55(20):6105-6123. [Epub ahead of print] PubMed PMID: 20871137.

  • The effect of air mass origin on the ambient concentrations of (7)Be and (210)Pb in Islamabad, Pakistan. Ali N, Khan EU, Akhter P, Khattak NU, Khan F, Rana MA. J Environ Radioact. 2010 Sep 23. [Epub ahead of print] PubMed PMID: 20869795.

  • Metal-Assisted Chemical Etching of Silicon: A Review. Huang Z, Geyer N, Werner P, de Boor J, Gösele U. Adv Mater. 2010 Sep 21. [Epub ahead of print] PubMed PMID: 20859941.

  • ASSESSMENT OF RADIOLOGICAL HAZARDS OF CLAY BRICKS FABRICATED IN THE PUNJAB PROVINCE OF PAKISTAN. Asghar M, Tufail M, Khan K, Mahmood A. Radiat Prot Dosimetry. 2010 Sep 21. [Epub ahead of print] PubMed PMID: 20858678.

  • Toward a photoconducting semiconductor RF optical fiber antenna array. Davis R, Rice R, Ballato A, Hawkins T, Foy P, Ballato J. Appl Opt. 2010 Sep 20;49(27):5163-8. doi: 10.1364/AO.49.005163. PubMed PMID: 20856292.

  • Enhanced Raman Scattering from Nanoparticle-Decorated Nanocone Substrates: A Practical Approach to Harness In-Plane Excitation. Hu YS, Jeon J, Seok TJ, Lee S, Hafner JH, Drezek RA, Choo H. ACS Nano. 2010 Sep 13. [Epub ahead of print] PubMed PMID: 20836500.

  • Indium Flux-Growth of Eu(2)AuGe(3): A New Germanide with an AlB(2) Superstructure. Sebastian CP, Malliakas CD, Chondroudi M, Schellenberg I, Rayaprol S, Hoffmann RD, Po¨ttgen R, Kanatzidis MG. Inorg Chem. 2010 Sep 13. [Epub ahead of print] PubMed PMID: 20836517.

  • Germanium(ii) hydride mediated reduction of carbon dioxide to formic acid and methanol with ammonia borane as the hydrogen source. Jana A, Tavcar G, Roesky HW, John M. Dalton Trans. 2010 Sep 7. [Epub ahead of print] PubMed PMID: 20830405.

  • Survey of materials for nanoskiving and influence of the cutting process on the nanostructures produced. Lipomi DJ, Martinez RV, Rioux RM, Cademartiri L, Reus WF, Whitesides GM. ACS Appl Mater Interfaces. 2010 Sep;2(9):2503-14. PubMed PMID: 20815347.

  • Dual energy CT at the synchrotron: A piglet model for neurovascular research. Schültke E, Kelly ME, Nemoz C, Fiedler S, Ogieglo L, Crawford P, Paterson J, Beavis C, Esteve F, Brochard T, Renier M, Requardt H, Dallery D, Le Duc G, Meguro K. Eur J Radiol. 2010 Aug 21. [Epub ahead of print] PubMed PMID: 20732772.

  • Impact of source-production revision on the dose-rate constant of 131Cs interstitial brachytherapy sources. Chen Z, Bongiorni P, Nath R. Med Phys. 2010 Jul;37(7):3607-10. PubMed PMID: 20831068; PubMed Central PMCID: PMC2902542.

  • Synchrotron-based scattered radiation from phantom materials used in X-ray CT. Rao DV, Swapna M, Cesareo R, Brunetti A, Akatsuka T, Yuasa T, Takeda T, Gigante GE. J Xray Sci Technol. 2010;18(3):327-37. PubMed PMID: 20714090.

  • Methylated Metal(loid) Species in Humans. Met Ions Life Sci. 2010;7:465-521. Hirner AV, Rettenmeier AW. Epub 2010 Jan 30. PubMed PMID: 20877816.

  • Determination method for total arsenic and partial-digestion method with nitric acid for inorganic arsenic speciation in several varieties of rice. Nishimura T, Hamano-Nagaoka M, Sakakibara N, Abe T, Maekawa Y, Maitani T. Shokuhin Eiseigaku Zasshi. 2010;51(4):178-81. PubMed PMID: 20827054.

 

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