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99% 2N 99.9% 3N     99.99% 4N   99.999% 5N     99.9999% 6N 

Organometallics
AE OrganoMetallics ™

32.4 (A)/00.022

Hydrogen                                 Helium
Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Cesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                   
    Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
    Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium      

(click on an element to view our products)



American Elements is a manufacturer and supplier specializing in organometallic compounds of Cerium, Lanthanum, Erbium, Ytterbium, Neodymium, Yttrium and other Rare Earth elements, Palladium, Hafnium, Scandium, Niobium, Tungsten, Ruthenium, Platinum as well as other advanced elements and more common catalytic metals, such as copper, tin and nickel in the form of acetylacetonates, cyclohexanebutyrates, 2-ethylhexanoates, trifluoroacetates, trifloromethanesulfonates, hexafloro- and trifloroacetylacetonates and Tris(2,2,6,6-tetramethyl-3,5-heptanedionate).

Organo-Metallic compounds are metallic cations bound to carbon-based anions making the compound soluble in organic rather than aqueous solvents so the elemental metal can serve as a catalyst in organic synthesis reactions.

For example, 2-Ethylhexanoates are carboxylates with many commercial applications They are commonly used in various catalysts for oxidation, hydrogenation and polymerization and as an adhesion promoter. The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring. Because of this property, Metallic Acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis such as hydrogenation and polymerization.


Organo-Metallics are marketed under the trade name and trademark AE OrganoMetallics™. American Elements can produce a variety of purities including 99%, 99.9%, 99.99%, 99.999% and 99.9999% which are sometimes referred to as 2N, 3N, 4N, 5N and 6N. Specific impurities, such as iron, calcium and silica can be reduced to customer specified levels.

Please select from the table an AE OrganoMetallics™ product:


Acetylacetonate
(A-N)		 2-Ethylhexanoate
(A-Z)		 Trifluoromethanesulfonate
(A-P)		 Other Other Other
Aluminum Acetylacetonate Aluminum 2-Ethylhexanoate Dysprosium Trifluoromethanesulfonate Tris[N,N-bis(trimethylsilyl)amide]cerium(III) Yttrium Trifluoroacetate Hydrate  
Barium Acetylacetonate Barium 2-Ethylhexanoate Erbium Trifluoromethanesulfonate Tris[N,N-bis(trimethylsilyl)amide]europium(III) Praseodymium(III) Tris[3-(trifluoromethylhydroxymethylene)-d-camphorate]  
Beryllium Acetylacetonate Bismuth 2-Ethylhexanoate Europium Trifluoromethanesulfonate Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) Praseodymium(III) Tris[3-(heptafluoropropylhdroxymethylene)-d-camphorate]  
Cadmium Acetylacetonate Calcium 2-Ethylhexanoate Gadolinium Trifluoromethanesulfonate Tris[N,N-bis(trimethylsilyl)amide]holmium(III) Neodymium(III) Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)  
Calcium Acetylacetonate Cerium 2-Ethylhexanoate Holmium Trifluoromethanesulfonate Tris[N,N-bis(trimethylsilyl)amide]lanthanum(III) Neodymium(III) Hexafluoro-2,4-pentanedionate  
Cerium Acetylacetonate Chromium 2-Ethylhexanoate Lanthanum Trifluoromethanesulfonate Tris[N,N-bis(trimethylsilyl)amide]neodymium(III)    
Chromium Acetylacetonate Cobalt 2-Ethylhexanoate Lutetium Trifluoromethanesulfonate Tris[N,N-bis(trimethylsilyl)amide]praseodymium(III)    
Cobalt Acetylacetonate Copper 2-Ethylhexanoate Neodymium Trifluoromethanesulfonate Tris[N,N-bis(trimethylsilyl)amide]samarium(III)    
Copper Acetylacetonate Europium 2-Ethylhexanoate Praseodymium Trifluoromethanesulfonate Tris[N,N-bis(trimethylsilyl)amide]terbium(III)    
Dysprosium Acetylacetonate Gadolinium 2-Ethylhexanoate Samarium Trifluoromethanesulfonate Tris[N,N-bis(trimethylsilyl)amide]yttrium    
Erbium Acetylacetonate Lead 2-Ethylhexanoate Terbium Trifluoromethanesulfonate Aluminum Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Europium Acetylacetonate Lithium 2-Ethylhexanoate Thulium Trifluoromethanesulfonate Copper Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Gadolinium Acetylacetonate Magnesium 2-Ethylhexanoate Ytterbium Trifluoromethanesulfonate Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Gallium Acetylacetonate Manganese 2-Ethylhexanoate Zinc Trifluoromethanesulfonate Cobalt Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Hafnium Acetylacetonate Molybdenum 2-Ethylhexanoate Yttrium Trifluoromethanesulfonate Iron Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Holmium Acetylacetonate Neodymium 2-Ethylhexanoate Tin Trifluoromethanesulfonate Chromium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Indium Acetylacetonate Nickel 2-Ethylhexanoate Calcium Trifluoromethanesulfonate Terbium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Iridium Acetylacetonate Niobium 2-Ethylhexanoate Hafnium Trifluoromethanesulfonate Thulium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Iron Acetylacetonate Potassium 2-Ethylhexanoate Copper Trifluoromethanesulfonate Scandium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) Hydrate    
Lanthanum Acetylacetonate Silicon 2-Ethylhexanoate Silver Trifluoromethanesulfonate Yttrium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Lead Acetylacetonate Silver 2-Ethylhexanoate Aluminum Trifluoromethanesulfonate Calcium Bis(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Lithium Acetylacetonate Sodium 2-Ethylhexanoate Cerium Trifluoromethanesulfonate Zirconium Diisopropoxidebis(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Lutetium Acetylacetonate Strontium 2-Ethylhexanoate   Zinc p-toluenesulfonate Hydrate    
Magnesium Acetylacetonate Thallium 2-Ethylhexanoate   Iron p-toluenesulfonate Hexahydrate    
Manganese Acetylacetonate Tin 2-Ethylhexanoate   Silver p-toluenesulfonate    
Neodymium Acetylacetonate Yttrium 2-Ethylhexanoate   Bis(cyclopentadienyl)nickel    
Nickel Acetylacetonate Zinc 2-Ethylhexanoate   Europium Tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate]    
Palladium Acetylacetonate     Tris(benzoylacetonato) mono(phenanthroline)europium    
Platinum Acetylacetonate     Tris(cyclopentadienyl)gadolinium    
Praseodymium Acetylacetonate     Tris(dibenzoylmethane) mono(1,10-phenanthroline)europium    
Rhodium Acetylacetonate     Tris(tetramethylcyclopentadienyl)europium(III)    
Ruthenium Acetylacetonate     Gadolinium Octanoate    
Samarium Acetylacetonate     Tris(tetramethylcyclopentadienyl)gadolinium(III)    
Scandium Acetylacetonate     Zinc Undecylenate    
Sodium Acetylacetonate     Zinc Trifluoroacetate Hydrate    
Strontium Acetylacetonate     Zinc p-toluenesulfonate Hydrate    
Terbium Acetylacetonate     Zinc Citrate Dihydrate    
Thallium Acetylacetonate     Zinc Acrylate    
Thorium Acetylacetonate     Zinc Stearate    
Thulium Acetylacetonate     Tris(cyclopentadienyl)yttrium    
Tin Acetylacetonate     Tris(tetramethylcyclopentadienyl)cerium(III)    
Vanadium Acetylacetonate     Tris(cyclopentadienyl)lanthanum    
Ytterbium Acetylacetonate     Tris(tetramethylcyclopentadienyl)lanthanum(III)    
Yttrium Acetylacetonate     Erbium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate)    
Zinc Acetylacetonate     Tris(cyclopentadienyl)erbium    
Zirconium Acetylacetonate     Tris(isopropylcyclopentadienyl)erbium    



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Recent Research & Development for Organometallics

  • Modular Synthesis of 5-Substituted Thiophen-2-yl C-2'-Deoxyribonucleosides. J Org Chem. 2008 Apr 17. [Epub ahead of print]


  • Current literature in mass spectrometry. J Mass Spectrom. 2008 Apr;43(4):547-58.


  • Current literature in mass spectrometry. J Mass Spectrom. 2008 Mar;43(3):409-18.


  • Ordered mesoporous materials at the beginning of the third millennium: new strategies to create hybrid and non-siliceous variants. Phys Chem Chem Phys. 2008 Jan 21;10(3):347-60. Epub 2007 Aug 9.


  • Heterogeneous catalysis with nickel-on-graphite (Ni/Cg). Org Biomol Chem. 2008 Jan 7;6(1):19-25. Epub 2007 Nov 5.


  • Methylgallium as a terminal ligand in [(Cp*Ga)4Rh(GaCH3)]+. Angew Chem Int Ed Engl. 2008;47(18):3438-41. No abstract available.


  • Substituted tertiary phosphine Ru(II) organometallics: Catalytic utility on the hydrolysis of etofibrate in pharmaceuticals. Spectrochim Acta A Mol Biomol Spectrosc. 2007 Nov 17. [Epub ahead of print]


  • Synthesis and structure of new compounds with Zn-Ga bonds: insertion of the gallium(I) bisimidinate Ga(DDP) into Zn-X (X = CH3, Cl) and the homoleptic complex cation [Zn(GaCp*)4]2+. Inorg Chem. 2007 Oct 29;46(22):9481-7. Epub 2007 Oct 5.


  • Facile access to pentavalent uranium organometallics: one-electron oxidation of uranium(IV) imido complexes with copper(I) salts. J Am Chem Soc. 2007 Oct 3;129(39):11914-5. Epub 2007 Sep 7. No abstract available.


  • The platinum-olefin binding energy in series of (PH3)2Pt(olefin) complexes--a theoretical study. J Mol Model. 2007 Sep;13(9):1009-16. Epub 2007 Jul 14.


  • Current literature in mass spectrometry. J Mass Spectrom. 2007 Aug 22;42(9):1251-1262. [Epub ahead of print]


  • Asymmetric synthesis of all eight seven-carbon dipropionate stereotetrads. J Am Chem Soc. 2007 Jul 25;129(29):9086-93. Epub 2007 Jun 14.


  • Cis double allylation of cyclopropenes using cyclopropylindium reagents. Org Biomol Chem. 2007 Jul 7;5(13):2154-8. Epub 2007 Jun 5.


  • Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface. Langmuir. 2007 Jul 3;23(14):7440-2. Epub 2007 Jun 2.


  • Applications of and alternatives to pi-electron-deficient azine organometallics in metal catalyzed cross-coupling reactions. Chem Soc Rev. 2007 Jul;36(7):1058-68. Epub 2007 Mar 2. Review.


  • Ultra-fast hydrothermal synthesis of diastereoselective pure ethenylene-bridged periodic mesoporous organosilicas. Chem Commun (Camb). 2007 Jun 14;(22):2261-3. Epub 2007 May 11.


  • Novel vapor phase reactions for the synthesis and modification of carbon nanotubes and inorganic nanowires. J Nanosci Nanotechnol. 2007 Jun;7(6):1695-702. Review.


  • Trapping metal-organic framework nanocrystals: an in-situ time-resolved light scattering study on the crystal growth of MOF-5 in solution. J Am Chem Soc. 2007 May 2;129(17):5324-5. Epub 2007 Apr 4. No abstract available.


  • The organic chemistry of silver acetylides. Chem Soc Rev. 2007 May;36(5):759-69. Epub 2007 Jan 23. Erratum in: Chem Soc Rev. 2007 Oct;36(10):1690.


  • Ab initio parametrized MM3 force field for the metal-organic framework MOF-5. J Comput Chem. 2007 May;28(7):1169-76.

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