99% 2N
99.9% 3N 99.99% 4N 99.999% 5N 99.9999% 6N
ORGANOMETALLICS INFORMATION CENTER
AE OrganoMetallics ™
32.4 (A)/00.022
(click on an element to view our products)
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American Elements is a manufacturer and supplier specializing in organometallic compounds of Cerium, Lanthanum, Erbium, Ytterbium, Neodymium, Yttrium and other Rare Earth elements, Palladium, Hafnium, Scandium, Niobium, Tungsten, Ruthenium, Platinum as well as other advanced elements and more common catalytic metals, such as copper, tin and nickel in the form of acetylacetonates, cyclohexanebutyrates, 2-ethylhexanoates, trifluoroacetates, trifloromethanesulfonates, hexafloro- and trifloroacetylacetonates and Tris(2,2,6,6-tetramethyl-3,5-heptanedionate).
Organo-Metallic compounds are metallic cations bound to carbon-based anions making the compound soluble in organic rather than aqueous solvents so the elemental metal can serve as a catalyst in organic synthesis reactions.
For example, 2-Ethylhexanoates are carboxylates with many commercial applications They are commonly used in various catalysts for oxidation, hydrogenation and polymerization and as an adhesion promoter. The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring. Because of this property, Metallic Acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis such as hydrogenation and polymerization.
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Organo-Metallics are marketed under the trade name and trademark AE OrganoMetallics™. American Elements can produce a variety of purities including 99%, 99.9%, 99.99%, 99.999% and 99.9999% which are sometimes referred to as 2N, 3N, 4N, 5N and 6N. Specific impurities, such as iron, calcium and silica can be reduced to customer specified levels.
Please select from the table an AE OrganoMetallics™ product: |
Acetylacetonate
(A-N) |
2-Ethylhexanoate
(A-Z) |
Trifluoromethanesulfonate
(A-P) |
Other |
Other |
| Aluminum Acetylacetonate |
Aluminum 2-Ethylhexanoate |
Dysprosium Trifluoromethanesulfonate |
Tris[N,N-bis(trimethylsilyl)amide]cerium(III) |
Yttrium Trifluoroacetate Hydrate |
| Barium Acetylacetonate |
Barium 2-Ethylhexanoate |
Erbium Trifluoromethanesulfonate |
Tris[N,N-bis(trimethylsilyl)amide]europium(III) |
Praseodymium(III) Tris[3-(trifluoromethylhydroxymethylene)-d-camphorate] |
| Beryllium Acetylacetonate |
Bismuth 2-Ethylhexanoate |
Europium Trifluoromethanesulfonate |
Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) |
Praseodymium(III) Tris[3-(heptafluoropropylhdroxymethylene)-d-camphorate] |
| Cadmium Acetylacetonate |
Calcium 2-Ethylhexanoate |
Gadolinium Trifluoromethanesulfonate |
Tris[N,N-bis(trimethylsilyl)amide]holmium(III) |
Neodymium(III) Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) |
| Calcium Acetylacetonate |
Cerium 2-Ethylhexanoate |
Holmium Trifluoromethanesulfonate |
Tris[N,N-bis(trimethylsilyl)amide]lanthanum(III) |
Neodymium(III) Hexafluoro-2,4-pentanedionate |
| Cerium Acetylacetonate |
Chromium 2-Ethylhexanoate |
Lanthanum Trifluoromethanesulfonate |
Tris[N,N-bis(trimethylsilyl)amide]neodymium(III) |
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| Chromium Acetylacetonate |
Cobalt 2-Ethylhexanoate |
Lutetium Trifluoromethanesulfonate |
Tris[N,N-bis(trimethylsilyl)amide]praseodymium(III) |
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| Cobalt Acetylacetonate |
Copper 2-Ethylhexanoate |
Neodymium Trifluoromethanesulfonate |
Tris[N,N-bis(trimethylsilyl)amide]samarium(III) |
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| Copper Acetylacetonate |
Europium 2-Ethylhexanoate |
Praseodymium Trifluoromethanesulfonate |
Tris[N,N-bis(trimethylsilyl)amide]terbium(III) |
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| Dysprosium Acetylacetonate |
Gadolinium 2-Ethylhexanoate |
Samarium Trifluoromethanesulfonate |
Tris[N,N-bis(trimethylsilyl)amide]yttrium |
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| Erbium Acetylacetonate |
Lead 2-Ethylhexanoate |
Terbium Trifluoromethanesulfonate |
Aluminum Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Europium Acetylacetonate |
Lithium 2-Ethylhexanoate |
Thulium Trifluoromethanesulfonate |
Copper Bis(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Gadolinium Acetylacetonate |
Magnesium 2-Ethylhexanoate |
Ytterbium Trifluoromethanesulfonate |
Nickel Bis(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Gallium Acetylacetonate |
Manganese 2-Ethylhexanoate |
Zinc Trifluoromethanesulfonate |
Cobalt Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Hafnium Acetylacetonate |
Molybdenum 2-Ethylhexanoate |
Yttrium Trifluoromethanesulfonate |
Iron Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Holmium Acetylacetonate |
Neodymium 2-Ethylhexanoate |
Tin Trifluoromethanesulfonate |
Chromium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Indium Acetylacetonate |
Nickel 2-Ethylhexanoate |
Calcium Trifluoromethanesulfonate |
Terbium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Iridium Acetylacetonate |
Niobium 2-Ethylhexanoate |
Hafnium Trifluoromethanesulfonate |
Thulium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Iron Acetylacetonate |
Potassium 2-Ethylhexanoate |
Copper Trifluoromethanesulfonate |
Scandium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) Hydrate |
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| Lanthanum Acetylacetonate |
Silicon 2-Ethylhexanoate |
Silver Trifluoromethanesulfonate |
Yttrium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Lead Acetylacetonate |
Silver 2-Ethylhexanoate |
Aluminum Trifluoromethanesulfonate |
Calcium Bis(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Lithium Acetylacetonate |
Sodium 2-Ethylhexanoate |
Cerium Trifluoromethanesulfonate |
Zirconium Diisopropoxidebis(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Lutetium Acetylacetonate |
Strontium 2-Ethylhexanoate |
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Zinc p-toluenesulfonate Hydrate |
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| Magnesium Acetylacetonate |
Thallium 2-Ethylhexanoate |
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Iron p-toluenesulfonate Hexahydrate |
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| Manganese Acetylacetonate |
Tin 2-Ethylhexanoate |
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Silver p-toluenesulfonate |
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| Neodymium Acetylacetonate |
Yttrium 2-Ethylhexanoate |
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Bis(cyclopentadienyl)nickel |
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| Nickel Acetylacetonate |
Zinc 2-Ethylhexanoate |
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Europium Tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate] |
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| Palladium Acetylacetonate |
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Tris(benzoylacetonato) mono(phenanthroline)europium |
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| Platinum Acetylacetonate |
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Tris(cyclopentadienyl)gadolinium |
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| Praseodymium Acetylacetonate |
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Tris(dibenzoylmethane) mono(1,10-phenanthroline)europium |
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| Rhodium Acetylacetonate |
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Tris(tetramethylcyclopentadienyl)europium(III) |
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| Ruthenium Acetylacetonate |
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Gadolinium Octanoate |
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| Samarium Acetylacetonate |
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Tris(tetramethylcyclopentadienyl)gadolinium(III) |
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| Scandium Acetylacetonate |
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Zinc Undecylenate |
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| Sodium Acetylacetonate |
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Zinc Trifluoroacetate Hydrate |
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| Strontium Acetylacetonate |
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Zinc p-toluenesulfonate Hydrate |
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| Terbium Acetylacetonate |
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Zinc Citrate Dihydrate |
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| Thallium Acetylacetonate |
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Zinc Acrylate |
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| Thorium Acetylacetonate |
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Zinc Stearate |
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| Thulium Acetylacetonate |
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Tris(cyclopentadienyl)yttrium |
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| Tin Acetylacetonate |
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Tris(tetramethylcyclopentadienyl)cerium(III) |
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| Vanadium Acetylacetonate |
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Tris(cyclopentadienyl)lanthanum |
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| Ytterbium Acetylacetonate |
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Tris(tetramethylcyclopentadienyl)lanthanum(III) |
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| Yttrium Acetylacetonate |
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Erbium Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Zinc Acetylacetonate |
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Tris(cyclopentadienyl)erbium |
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| Zirconium Acetylacetonate |
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Tris(isopropylcyclopentadienyl)erbium |
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Recent Research & Development for Organometallics
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Substituent-Free Gallium by Hydrogenolysis of Coordinated GaCp*: Synthesis and Structure of Highly Fluxional [Ru(2)(Ga)(GaCp*)(7)(H)(3)].
Cadenbach T, Gemel C, Schmid R, Halbherr M, Yusenko K, Cokoja M, Fischer RA.
Angew Chem Int Ed Engl. 2009 Feb 13. [Epub ahead of print] No abstract available.
PMID: 19219882 [PubMed - as supplied by publisher]
- Current literature in mass spectrometry.
John Wiley & Sons, Ltd.
J Mass Spectrom. 2009 Feb;44(2):288-99.
PMID: 19180566 [PubMed - in process]
- New ventures in the chemistry of avermectins.
Pitterna T, Cassayre J, Hüter OF, Jung PM, Maienfisch P, Kessabi FM, Quaranta L, Tobler H.
Bioorg Med Chem. 2009 Jan 6. [Epub ahead of print]
PMID: 19168364 [PubMed - as supplied by publisher]
- Systematic First Principles Parameterization of Force Fields for Metal-Organic Frameworks using a Genetic Algorithm Approach.
Tafipolsky M, Schmid R.
J Phys Chem B. 2009 Feb 5;113(5):1341-52.
PMID: 19133795 [PubMed - in process]
- Synthesis and structure of electron rich ruthenium polyhydride complexes and clusters containing AlCp* and GaCp*.
Cadenbach T, Bollermann T, Gemel C, Fischer RA.
Dalton Trans. 2009 Jan 14;(2):322-9. Epub 2008 Nov 6.
PMID: 19089014 [PubMed - in process]
- Large static first and second hyperpolarizabilities dominated by excess electron transition for radical ion pair salts M2*+TCNQ*- (M=Li, Na, K).
Li ZJ, Wang FF, Li ZR, Xu HL, Huang XR, Wu D, Chen W, Yu GT, Gu FL, Aoki Y.
Phys Chem Chem Phys. 2009 Jan 14;11(2):402-8. Epub 2008 Nov 4.
PMID: 19088997 [PubMed - in process]
- Triple-Decker Complexes Formed via the Weak Link Approach.
Jeon YM, Heo J, Brown AM, Mirkin CA.
Organometallics. 2006 May 22;25(11):2729-2732.
PMID: 19060957 [PubMed]
- Redox-active organometallics: magnetic and electronic couplings through carbon-silicon hybrid molecular connectors.
Hamon P, Justaud F, Cador O, Hapiot P, Rigaut S, Toupet L, Ouahab L, Stueger H, Hamon JR, Lapinte C.
J Am Chem Soc. 2008 Dec 24;130(51):17372-83.
PMID: 19053464 [PubMed - in process]
- Cannabinoids inhibit zebra mussel (Dreissena polymorpha) byssal attachment: a potentially green antifouling technology.
Angarano MB, McMahon RF, Schetz JA.
Biofouling. 2009;25(2):127-38.
PMID: 19037826 [PubMed - in process]
- Well-defined polynuclear heterobimetallic complexes as precursors for ceramic and magnetic materials.
Szafert S, John L, Sobota P.
Dalton Trans. 2008 Dec 14;(46):6509-20. Epub 2008 Oct 14.
PMID: 19030610 [PubMed - in process]
- Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts.
Sinha A, Schrock RR, Müller P, Hoveyda AH.
Organometallics. 2006 Nov;25(19):4621-4626.
PMID: 19030118 [PubMed]
- Organometallic chemistry of Ga(+): formation of an unusual gallium dimer in the coordination sphere of ruthenium.
Cadenbach T, Gemel C, Bollermann T, Fernandez I, Frenking G, Fischer RA.
Chemistry. 2008;14(34):10789-96.
PMID: 18956398 [PubMed]
- Molybdenum Imido Alkylidene Metathesis Catalysts that Contain Electron Withdrawing Biphenolates or Binaphtholates.
Singh R, Czekelius C, Schrock RR, Müller P, Hoveyda AH.
Organometallics. 2007;26(10):2528-2539.
PMID: 18953421 [PubMed]
- The Development of Versatile Methods for Palladium-Catalyzed Coupling Reactions of Aryl Electrophiles through the Use of P(t-Bu)3 and PCy3 as Ligands.
Fu GC.
Acc Chem Res. 2008 Oct 24. [Epub ahead of print]
PMID: 18947239 [PubMed - as supplied by publisher]
- Molecular cut-outs of Mo/Zn Hume-Rothery phases: synthesis and structure of [{Mo(CO)4}4(Zn)6(mu-ZnCp*)4].
Cadenbach T, Gemel C, Fischer RA.
Angew Chem Int Ed Engl. 2008;47(47):9146-9. No abstract available.
PMID: 18846528 [PubMed]
- Twelve one-electron ligands coordinating one metal center: structure and bonding of [Mo(ZnCH3)9(ZnCp*)3].
Cadenbach T, Bollermann T, Gemel C, Fernandez I, von Hopffgarten M, Frenking G, Fischer RA.
Angew Chem Int Ed Engl. 2008;47(47):9150-4. No abstract available.
PMID: 18846517 [PubMed]
- Electrophilic Activation of Lewis Base Complexes of Borane with Trityl Tetrakis(pentafluorophenyl)borate.
De Vries TS, Vedejs E.
Organometallics. 2007;26(13):3079-3081. No abstract available.
PMID: 18806887 [PubMed]
- Determination of Hg and organomercury species following SPME: a review.
Díez S, Bayona JM.
Talanta. 2008 Oct 19;77(1):21-7. Epub 2008 Jun 27. Review.
PMID: 18804593 [PubMed - indexed for MEDLINE]
- Functionalized coordination space in metal-organic frameworks.
Fischer RA, Wöll C.
Angew Chem Int Ed Engl. 2008;47(43):8164-8. No abstract available.
PMID: 18803195 [PubMed]
- Ultra stable ordered mesoporous phenol/formaldehyde polymers as a heterogeneous support for vanadium oxide.
Muylaert I, Borgers M, Bruneel E, Schaubroeck J, Verpoort F, Van Der Voort P.
Chem Commun (Camb). 2008 Oct 7;(37):4475-7. Epub 2008 Jul 29.
PMID: 18802595 [PubMed]
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PRODUCT LIST
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