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Antimony
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Antimony
Antimony information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Antimony is finding use in semiconductor technology for making infrared detectors, diodes and Hall-effect devices in crystalline structures, such as antimony telluride and gallium antimonide . Antimony is however a poor conductor of heat and electricity. It greatly increases the hardness and mechanical strength of lead. This has found applications in batteries, antifriction alloys, small arms and tracer bullets and cable sheathing. Antimony compounds are used in manufacturing flame-proofing compounds, paints, ceramic enamels, glass, and pottery glazes. Antimony is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Antimony facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

  Hydrogen                                 Helium
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  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Antimony is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Antimony is a Block P, Group 15, Period 5 element. The electronic configuration is [Kr] 4d10 5s2 5p3. In its elemental form antimony's CAS number is 7440-36-0. The antimony atom has a radius of 145.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Antimony compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Antimony was first discovered by Early Man.

French Antimoine German Antimon Italian Antimonio Portuguese Antimônio Spanish Antimonio Swedish Antimon

Abundance. The following table shows the abundance of antimony and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Sb-121
120.903818
57.36
Sb-123
122.904216
42.64

Safety Data. The safety data for antimony metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for antimony (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
830.59 kJ mol-1
2nd Ionization Energy
1594.96 kJ mol-1
3rd Ionization Energy
2441.10 kJ mol-1

Conductivity. As to antimony's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 39 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.05. The thermal conductivity of antimony is 24.3 W m-1 K-1.

Thermal Properties. The melting point and boiling point for antimony are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
20.9 kJ mol-1
Heat of Vaporization
165.8 kJ mol-1
Heat of Atomization
262.04 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Sb 51 121.75 g.mol -1 1.9 6.684 g.cm-3 at 20 °C 631 °C 1380 °C 200.pm 0.245 nm (-3) ; 0.062 (+5) ; 0.076 (+3) 830.59 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Antimony

  • Crucial role of cytosolic tryparedoxin peroxidase in Leishmania donovani survival, drug response and virulence. Mol Microbiol. 2008 Feb 26; [Epub ahead of print]

  • Synthesis, structural characterization and biological study of new organotin(IV), silver(I) and antimony(III) complexes with thioamides. J Inorg Biochem. 2008 Jan 8; [Epub ahead of print]

  • An Unusual Asymmetric Polyoxomolybdate Containing Mixed-Valence Antimony and Its Derivatives: [Sb4(V)Sb2(III)Mo18O73(H2O)2](12-) and {M(H2O)2[Sb4(V)Sb2(III)Mo18O73(H2O)2]2}(22-) (M = Mn(II), Fe(II), Cu(II) or Co(II)). Inorg Chem. 2008 Feb 16; [Epub ahead of print]

  • In vitro evaluation of the effectiveness and cytotoxicity of meglumine antimoniate microspheres produced by spray drying against Leishmania infantum. Parasitol Res. 2008 Feb 17; [Epub ahead of print]

  • Absorbed radiation dose of the female breast during diagnostic multidetector chest CT and dose reduction with a tungsten-antimony composite breast shield: preliminary results. Clin Radiol. 2008 Mar;63(3):278-88. Epub 2007 Dec 4.

  • Visual Colorimetry for Trace Antimony(V) by Ion-Pair Solid-Phase Extraction with Bis[2-(5-chloro-2-pyridylazo)-5-diethylaminophenolato]cobalt(III) on a PTFE Type Membrane Filter. Anal Sci. 2008 Feb;24(2):219-23.

  • Efficacy of miltefosine for bolivian cutaneous leishmaniasis. Am J Trop Med Hyg. 2008 Feb;78(2):210-1.

  • Thermal stability and spectroscopic properties of Er(3+)-doped antimony-borosilicate glasses. Spectrochim Acta A Mol Biomol Spectrosc. 2007 Dec 28; [Epub ahead of print]

  • Antimony uptake by Zea mays (L.) and Helianthus annuus (L.) from nutrient solution. Environ Geochem Health. 2008 Feb 6; [Epub ahead of print]

  • Roles of trypanothione S-transferase and tryparedoxin peroxidase in resistance to antimonials. Antimicrob Agents Chemother. 2008 Feb 4; [Epub ahead of print]

  • Wound Fragments from Cutaneous Sites of U.S. Military Personnel Deployed in Operation Iraqi Freedom: Clinical Aspects and Pathologic Characterizations. Dermatol Surg. 2008 Jan 31; [Epub ahead of print]

  • Dissolved antimony concentrations in contrasted watersheds: the importance of lithogenic origin. J Environ Monit. 2008 Feb;10(2):256-260. Epub 2007 Dec 5.

  • Effect of Sb dopant amount on the structure and electrocatalytic capability of Ti/Sb-SnO2 electrodes in the oxidation of 4-chlorophenol. J Environ Sci (China). 2007;19(11):1380-6.

  • Mutilating lupoid leishmaniasis: twelve years to make the diagnosis! Dermatology. 2008;216(2):187-9. Epub 2008 Jan 23. No abstract available.

  • Tris[2-(morpholin-4-ylmethyl)phenyl-kappa2C1,N]antimony(III). Acta Crystallogr C. 2008 Jan;64(Pt 1):m37-9. Epub 2007 Dec 14.

  • Human placental extract offers protection against experimental visceral leishmaniasis: a pilot study for a phase-I clinical trial. Ann Trop Med Parasitol. 2008 Jan;102(1):21-38.

  • Measurement of total antimony and antimony species in mine contaminated soils by ICPMS and HPLC-ICPMS. J Environ Monit. 2008 Jan;10(1):136-40. Epub 2007 Dec 7.

  • Indigenous leishmaniasis in Taiwan: report of a case. Int J Dermatol. 2008 Jan;47(1):40-3.

  • Confirmation of sentinel lymph node identity by analysis of fine-needle biopsy samples using inductively coupled plasma-mass spectrometry. Ann Surg Oncol. 2008 Mar;15(3):934-40. Epub 2008 Jan 3.

  • Clinical and parasite species risk factors for pentavalent antimonial treatment failure in cutaneous leishmaniasis in Peru. Clin Infect Dis. 2008 Jan 15;46(2):223-31.

 

 

 

 

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