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Antimony
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Antimony
Antimony information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Antimony is finding use in semiconductor technology for making infrared detectors, diodes and Hall-effect devices in crystalline structures, such as antimony telluride and gallium antimonide . Antimony is however a poor conductor of heat and electricity. It greatly increases the hardness and mechanical strength of lead. This has found applications in batteries, antifriction alloys, small arms and tracer bullets and cable sheathing. Antimony compounds are used in manufacturing flame-proofing compounds, paints, ceramic enamels, glass, and pottery glazes. Antimony is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Antimony facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Antimony is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Antimony is a Block P, Group 15, Period 5 element. The electronic configuration is [Kr] 4d10 5s2 5p3. In its elemental form antimony's CAS number is 7440-36-0. The antimony atom has a radius of 145.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Antimony compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Antimony was first discovered by Early Man.

French Antimoine German Antimon Italian Antimonio Portuguese Antimônio Spanish Antimonio Swedish Antimon

Abundance. The following table shows the abundance of antimony and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Sb-121
120.903818
57.36
Sb-123
122.904216
42.64

Safety Data. The safety data for antimony metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for antimony (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
830.59 kJ mol-1
2nd Ionization Energy
1594.96 kJ mol-1
3rd Ionization Energy
2441.10 kJ mol-1

Conductivity. As to antimony's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 şC is 39 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.05. The thermal conductivity of antimony is 24.3 W m-1 K-1.

Thermal Properties. The melting point and boiling point for antimony are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
20.9 kJ mol-1
Heat of Vaporization
165.8 kJ mol-1
Heat of Atomization
262.04 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Sb 51 121.75 g.mol -1 1.9 6.684 g.cm-3 at 20 °C 631 °C 1380 °C 200.pm 0.245 nm (-3) ; 0.062 (+5) ; 0.076 (+3) 830.59 kJ.mol-1

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Recent Research & Development for Antimony

  • Antimony: A modular model definition language. Smith LP, Bergmann FT, Chandran D, Sauro HM. Bioinformatics. 2009 Jul 3. [Epub ahead of print] PMID: 19578039 [PubMed - as supplied by publisher]

  • Synthesis of bismuth and antimony complexes of the "larger" calix[n]arenes (n = 6-8); from mononuclear to tetranuclear complexes. Mendoza-Espinosa D, Rheingold AL, Hanna TA. Dalton Trans. 2009 Jul 14;(26):5226-38. Epub 2009 May 26. PMID: 19562184 [PubMed - in process]

  • Synthesis, X-ray structures and reactivity of calix[5]arene bismuth(iii) and antimony(iii) complexes. Mendoza-Espinosa D, Hanna TA. Dalton Trans. 2009 Jul 14;(26):5211-25. Epub 2009 May 26. PMID: 19562183 [PubMed - in process]

  • Polynuclear titanocene complexes with antimony ligands: [(Cp(2)Ti)(2)(SbR(2))(2)] (R = Et), [(Cp(2)Ti)(3)(SbR)(3)Sb] [R = 2-(Me(2)NCH(2))C(6)H(4)] and [(Cp(2)Ti)(5)(SbR)(2)Sb(7)] (R = Me(3)SiCH(2)). Breunig HJ, Lork E, Moldovan O, Rat CI, Rosenthal U, Silvestru C. Dalton Trans. 2009 Jul 14;(26):5065-7. Epub 2009 May 13. PMID: 19562162 [PubMed - in process]

  • [Mechanisms of action for metallic elements and their species classified as R40 by EU] Apostoli P, Catalani S. G Ital Med Lav Ergon. 2009 Jan-Mar;31(1):54-60. Italian. PMID: 19558041 [PubMed - in process]

  • Heterobimetallic Bismuth(III)/Molybdenum(VI) and Antimony(III)/Molybdenum(VI) Calix[5]arene Complexes. Progress toward Modeling the SOHIO Catalyst. Mendoza-Espinosa D, Hanna TA. Inorg Chem. 2009 Jun 24. [Epub ahead of print] PMID: 19552450 [PubMed - as supplied by publisher]

  • The geometric effect and programming current reduction in cylindrical-shaped phase change memory. Li Y, Hwang CH, Li TY, Cheng HW. Nanotechnology. 2009 Jul 15;20(28):285701. Epub 2009 Jun 24. PMID: 19550022 [PubMed - in process]

  • Host peroxisomal properties are not restored to normal after treatment with sodium antimony gluconate. Gupta S, Raychaudhury B, Datta SC. Exp Parasitol. 2009 Jun 21. [Epub ahead of print] PMID: 19545565 [PubMed - as supplied by publisher]

  • Sub-optimal Dose of Sodium Antimony Gluconate (SAG)-Diperoxovanadate Combination Clears Organ Parasites from BALB/c Mice Infected with Antimony Resistant Leishmania donovani by Expanding Antileishmanial T-cell Repertoire and Increasing IFN-gamma to IL-10 Ratio. Haldar AK, Banerjee S, Naskar K, Kalita D, Islam NS, Roy S. Exp Parasitol. 2009 Feb 10. [Epub ahead of print] PMID: 19545517 [PubMed - as supplied by publisher]

  • Molecular Nitrides with Titanium and Group 13-15 Elements. García-Castro M, Martín A, Mena M, Yélamos C. Chemistry. 2009 Jun 19. [Epub ahead of print] PMID: 19544507 [PubMed - as supplied by publisher]

  • Elemental and iron isotopic composition of aerosols collected in a parking structure. Majestic BJ, Anbar AD, Herckes P. Sci Total Environ. 2009 Jun 18. [Epub ahead of print] PMID: 19540567 [PubMed - as supplied by publisher]

  • Sonochemical preparation of antimony subiodide. Nowak M, Szperlich P, Talik E, Szala J, Rzychon T, Stróz D, Nowrot A, Solecka B. Ultrason Sonochem. 2009 May 28. [Epub ahead of print] PMID: 19540144 [PubMed - as supplied by publisher]

  • The Antimony-Based Type I Clathrate Compounds Cs(8)Cd(18)Sb(28) and Cs(8)Zn(18)Sb(28). Liu Y, Wu LM, Li LH, Du SW, Corbett JD, Chen L. Angew Chem Int Ed Engl. 2009 Jun 17;48(29):5305-5308. [Epub ahead of print] PMID: 19536797 [PubMed - as supplied by publisher]

  • Severe adverse reactions to meglumine antimoniate in the treatment of visceral leishmaniasis: a report of 13 cases in the southwestern region of Brazil. de Oliveira AL, Brustoloni YM, Fernandes TD, Dorval ME, da Cunha RV, Bóia MN. Trop Doct. 2009 Jul;39(3):180-2. PMID: 19535762 [PubMed - in process]

  • Resonant oscillation of misch-metal atoms in filled skutterudites. Wang Y, Xu X, Yang J. Phys Rev Lett. 2009 May 1;102(17):175508. Epub 2009 May 1. PMID: 19518798 [PubMed]

  • Episodic discharge of lead, copper and antimony from a Norwegian small arm shooting range. Strřmseng AE, Ljřnes M, Bakka L, Mariussen E. J Environ Monit. 2009 Jun;11(6):1259-67. Epub 2009 Apr 15. PMID: 19513458 [PubMed - in process]

  • The effects of antimony doping on the surface structure of rutile TiO2(110). Bechstein R, Kitta M, Schütte J, Onishi H, Kühnle A. Nanotechnology. 2009 Jul 1;20(26):264003. Epub 2009 Jun 10. PMID: 19509451 [PubMed - in process]

  • Spectrophotometric determination of Sb(III) and Sb(V) in biological samples after micelle-mediated extraction. Madrakian T, Bozorgzadeh E. J Hazard Mater. 2009 May 15. [Epub ahead of print] PMID: 19501466 [PubMed - as supplied by publisher]

  • Down regulation of KMP-11 in Leishmania infantum axenic antimony resistant amastigotes as revealed by a proteomic screen. El Fadili K, Drummelsmith J, Roy G, Jardim A, Ouellette M. Exp Parasitol. 2009 Jun 3. [Epub ahead of print] PMID: 19500579 [PubMed - as supplied by publisher]

  • Metabolism of tellurium, antimony and germanium simultaneously administered to rats. Kobayashi A, Ogra Y. J Toxicol Sci. 2009 Jun;34(3):295-303. PMID: 19483383 [PubMed - in process]

 

 

 

 

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